File name: Pandora247s1_WhittierCA_20240529_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20241125T192010.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20240529_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240529T174158.7Z 8915.737485 320 1 54.18 2 30.58 105.15 81.16 242.46 0.00 1 0.00 1 0 17 1.112e-02 8.126e-03 4.343e-03 2.562e-03 1.783014e-01 1.374222e-03 2.025753e-03 -6.000000e+00 6.739410e-03 231.76 -2.00 3.36 -2.00 315.61 0.00e+00 3.860846e-04 1.352212e-04 5.792489e-05 -6.000000e+00 3.015400e-04 288.50 -2.00 20.00 -2.00 314.87 0.00e+00 1.161 0.000 302.00 328.00 3 6.0848e+00 3.5692e-03 1.4558e-02 -6.0000e+00 1.6859e-02 5.5823e-03 3.9586e-03 8.8328e-03 -6.0000e+00 1.8177e-02 3.8987e-03 2.2654e-03 4.2690e-03 -6.0000e+00 1.0831e-02 -4.4787e-03 1.0098e-03 1.2230e-03 -6.0000e+00 4.5916e-03 3.1879e-04 6.1778e-04 7.9244e-05 1.6303e-05 -6.0000e+00 3.3644e-04 -2.6713e-03 -8.6518e-05 11 9 0 11 8 0 99.95 25.27 0.32 -0.00267 0.00197 17 2 1 5 0 3186.797 33.25 20.00 25.27 27.69 35.2 1002.79 -583 -1839 170 -4078 -493 1548 1463 595 -901 -1768 -588 -501 1950 1396 2285 -252 416 923 980 1569 -644 1176 126 2331 2398 -1430 784 1034 116 -775 1937 20 1087 -2012 -3196 -775 -2293 -712 430 -1512 -979 -1089 -4040 -511 851 -637 -1196 532 -1483 617 404 974 1064 615 965 1645 823 571 1597 938 1188 1486 -500 1467 -519 3 -785 -370 1232 -149 950 658 151 835 -222 -849 -1284 -1641 -273 -1347 -723 -1351 -1830 -997 -439 -351 111 769 1284 519 426 185 -416 416 606 125 666 828 431 -61 -901 -894 -692 -136 -567 -270 -338 -914 21 332 883 -51 -47 -187 -729 -1081 261 352 267 -395 -221 334 397 795 236 -137 79 971 263 182 -581 -126 -262 202 289 516 -8 791 -15 116 -488 -1213 -160 -527 46 -1046 -113 347 356 162 -263 -524 -172 -154 649 474 838 -99 167 378 412 670 -282 506 56 1067 1135 -703 361 444 48 -323 823 9 508 -941 -1457 -358 -1218 -439 279 -1108 -756 -866 -3348 -408 667 -496 -907 383 -1071 445 307 777 884 530 778 1337 675 464 1382 768 1022 1366 -494 1434 -489 3 -696 -333 1106 -150 996 703 159 826 -203 -762 -1069 -1365 -241 -1237 -725 -1465 -1951 -1118 -524 -444 136 945 1645 631 474 201 -428 429 669 141 822 1015 535 -78 -1080 -1014 -788 -164 -733 -342 -445 -1264 31 497 1252 -76 -65 -239 -931 -1348 329 472 359 -558 -314 462 528 1074 305 -169 95 1195 345 250 -773 -170 -363 292 440 760 -12 1206 -23 172 -750 -1833 SS 20240529T182705.2Z 8915.768811 333 1 21.26 2 21.88 118.53 89.30 249.07 0.00 1 0.00 1 0 17 9.358e-03 7.076e-03 3.372e-03 2.388e-03 1.670743e-01 1.292969e-03 1.918284e-03 -6.000000e+00 5.671761e-03 231.76 -2.00 3.36 -2.00 314.80 0.00e+00 4.331205e-04 1.088105e-04 1.687761e-05 -6.000000e+00 2.537695e-04 288.50 -2.00 20.00 -2.00 314.15 0.00e+00 1.077 0.000 302.00 328.00 3 5.1918e+00 3.3284e-03 1.3572e-02 -6.0000e+00 1.4188e-02 9.8016e-03 3.6744e-03 8.2896e-03 -6.0000e+00 1.5298e-02 -3.0152e-03 2.1015e-03 4.0114e-03 -6.0000e+00 9.1148e-03 -2.4852e-03 9.1739e-04 1.1348e-03 -6.0000e+00 3.8642e-03 8.6548e-04 5.2022e-04 7.3324e-05 1.5957e-05 -6.0000e+00 2.8314e-04 -2.6185e-03 -8.3482e-05 12 9 1 12 1 1 99.77 25.38 0.22 -0.00262 0.00129 6 2 1 5 0 3036.981 33.25 20.00 25.38 30.10 35.5 1003.19 91 -613 -2267 -4450 -1237 771 978 1757 424 -1194 -1912 -314 -87 137 507 -425 1018 1192 898 1607 -296 804 1180 306 2404 -615 -780 -385 637 310 1180 371 943 -1283 -3035 -1044 -1667 -583 270 -728 -1026 -468 -1705 -277 115 -795 -150 386 -618 742 729 215 1173 732 477 907 500 626 1171 399 1041 1362 399 1212 -443 -312 -531 -391 1138 614 324 345 15 595 28 -443 -931 -885 -522 -1395 -1163 -1634 -2017 -1293 -969 -179 123 560 358 509 205 -437 200 785 469 189 447 607 379 -406 -793 -879 -126 75 -1013 -849 -542 -639 293 425 609 413 193 -187 -73 -593 342 264 656 14 -115 696 119 553 650 26 232 1130 525 166 -77 -218 -441 325 -54 -93 154 164 -348 102 -482 -1068 33 -226 -817 -1489 -403 246 309 607 157 -451 -723 -123 -38 60 242 -214 516 618 479 868 -163 439 658 167 1326 -349 -424 -210 326 159 626 209 543 -733 -1698 -594 -1001 -381 203 -573 -856 -400 -1402 -238 98 -668 -121 299 -473 570 589 184 1035 628 418 802 444 549 1014 355 967 1274 397 1205 -422 -288 -463 -346 1088 613 343 371 16 593 27 -389 -806 -760 -481 -1355 -1169 -1771 -2189 -1477 -1123 -218 155 680 447 597 232 -476 203 799 513 216 529 765 483 -498 -956 -1004 -144 87 -1262 -1056 -700 -859 391 591 859 567 260 -243 -88 -699 410 336 851 19 -158 933 155 714 797 32 279 1389 651 216 -98 -283 -590 452 -75 -135 228 236 -523 148 -683 -1488 SS 20240529T183119.9Z 8915.771758 336 1 54.56 2 21.12 120.22 90.09 249.66 0.00 1 0.00 1 0 17 7.941e-03 6.607e-03 1.253e-04 9.683e-05 1.641401e-01 5.264536e-05 1.902230e-03 -6.000000e+00 4.812280e-03 231.76 -2.00 3.36 -2.00 314.36 0.00e+00 3.075016e-04 4.061720e-06 1.359140e-05 -6.000000e+00 2.153943e-04 288.50 -2.00 20.00 -2.00 313.74 0.00e+00 1.072 0.000 302.00 328.00 3 5.9981e-02 1.3506e-04 1.3447e-02 -6.0000e+00 1.2038e-02 -3.1813e-02 1.4868e-04 8.1592e-03 -6.0000e+00 1.2980e-02 -7.7078e-04 8.5307e-05 3.9566e-03 -6.0000e+00 7.7339e-03 -2.5484e-03 3.6746e-05 1.0980e-03 -6.0000e+00 3.2782e-03 1.5057e-01 2.4657e-04 2.9655e-06 1.6679e-05 -6.0000e+00 2.4029e-04 -2.2801e-03 -1.2489e-04 11 8 0 10 0 0 72.52 25.40 0.30 -0.00228 -0.00043 3213 318 1 5 0 16.978 33.25 20.01 25.40 30.52 35.6 1004.26 -418 -604 -1286 -2514 -700 -372 919 1291 454 -1328 -1205 98 -179 260 428 -609 199 706 766 1205 388 830 960 671 845 425 -564 0 492 1185 1288 1512 938 -2249 -1997 -1406 -1466 -213 -352 -1108 -1146 -694 -850 -748 -38 -552 -594 -399 -427 500 967 611 1082 607 549 1045 576 265 436 585 1153 1280 1286 837 -545 -275 -577 -50 1406 283 187 223 171 478 -70 -262 -663 -711 -242 -1135 -1407 -1732 -2154 -1130 -798 -446 65 125 368 328 579 -27 87 671 556 341 574 548 -156 -290 -695 -820 -47 215 -1058 -804 -595 -592 294 464 441 208 206 49 33 345 304 346 378 -41 -58 125 304 255 834 33 444 958 379 289 -143 -401 -178 134 -4 -209 135 68 -203 -112 -303 -849 -176 -262 -538 -1018 -270 -143 378 555 199 -594 -535 45 -87 134 229 -344 109 395 439 702 228 487 557 407 530 268 -343 0 284 677 738 913 562 -1350 -1198 -870 -950 -150 -269 -887 -943 -584 -726 -637 -32 -471 -489 -326 -342 404 793 514 946 533 492 944 524 239 391 532 1069 1234 1272 838 -536 -254 -518 -46 1344 285 195 230 178 482 -66 -238 -575 -631 -224 -1109 -1435 -1808 -2322 -1249 -920 -532 78 153 440 385 652 -29 90 698 590 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