File name: Pandora247s1_WhittierCA_20240601_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20240602T075434.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20240601_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240601T200344.8Z 8918.835935 347 1 54.62 2 12.15 195.14 67.93 258.16 0.00 1 0.00 1 0 17 7.931e-03 6.585e-03 4.791e-04 3.724e-04 1.553514e-01 2.043359e-04 1.799884e-03 -6.000000e+00 4.861403e-03 231.87 -2.00 3.36 -2.00 314.21 0.00e+00 2.158555e-04 1.554452e-05 1.604642e-05 -6.000000e+00 2.180173e-04 288.78 -2.00 20.00 -2.00 313.62 0.00e+00 1.023 0.000 302.00 328.00 3 3.5609e+00 5.2364e-04 1.2791e-02 -6.0000e+00 1.2161e-02 -9.9492e-03 5.7596e-04 7.7198e-03 -6.0000e+00 1.3099e-02 -2.9471e-03 3.3074e-04 3.7513e-03 -6.0000e+00 7.8142e-03 -1.8632e-03 1.4083e-04 1.0364e-03 -6.0000e+00 3.2867e-03 4.7966e-03 2.8211e-04 1.1642e-05 1.6284e-05 -6.0000e+00 2.4603e-04 -6.5879e-03 1.9521e-04 11 8 0 10 0 0 99.99 25.83 0.32 -0.00659 -0.00447 386 38 1 5 0 141.493 33.50 20.01 25.83 32.76 35.4 999.71 781 -733 -1335 -1718 -2433 -18 360 1247 1445 166 -1367 -724 645 133 462 256 -804 188 765 511 1075 358 937 958 634 580 -52 -875 152 870 1374 1325 1217 540 -2543 -1562 -728 -916 -65 -359 -1313 -1276 -711 -1073 -903 -221 -822 -684 -424 -355 706 940 508 964 556 618 998 505 326 666 732 1252 1267 984 518 -716 -21 -75 384 1620 173 -5 53 -15 305 -126 -81 -343 -313 113 -1103 -1379 -1791 -2005 -1000 -777 -483 -11 -21 173 202 574 153 442 992 664 320 466 264 -357 -429 -595 -591 166 165 -1162 -869 -651 -556 169 355 263 125 220 184 298 533 412 303 273 -176 -111 105 321 282 885 166 570 1007 344 187 -199 -360 -129 187 -91 -280 111 44 -245 -89 -257 -762 316 -326 -611 -756 -986 -7 140 518 617 76 -637 -335 308 66 238 143 -447 106 437 300 639 215 560 587 386 364 -33 -532 90 512 800 760 734 335 -1582 -932 -447 -604 -47 -277 -1084 -1070 -610 -934 -783 -189 -690 -577 -344 -294 588 784 447 845 503 569 927 454 302 612 685 1178 1224 1001 532 -703 -19 -68 354 1548 177 -5 56 -16 312 -123 -74 -304 -275 102 -1069 -1415 -1910 -2181 -1104 -917 -584 -13 -26 207 235 651 164 459 1030 712 363 541 327 -435 -518 -693 -676 190 194 -1430 -1085 -820 -727 223 487 355 170 288 227 353 633 502 380 354 -234 -148 138 419 349 1069 199 662 1199 420 240 -255 -468 -166 252 -125 -391 158 63 -352 -125 -360 -1049 SS 20240601T203338.0Z 8918.856690 353 1 21.26 2 15.17 221.89 73.79 262.69 0.00 1 0.00 1 0 17 7.768e-03 6.522e-03 1.780e-03 1.351e-03 1.571293e-01 7.378712e-04 1.808180e-03 -6.000000e+00 4.760950e-03 231.87 -2.00 3.36 -2.00 314.34 0.00e+00 1.904410e-04 5.740829e-05 1.920113e-05 -6.000000e+00 2.135224e-04 288.78 -2.00 20.00 -2.00 313.73 0.00e+00 1.036 0.000 302.00 328.00 3 5.0809e+00 1.8931e-03 1.2933e-02 -6.0000e+00 1.1910e-02 -3.1253e-03 2.0835e-03 7.7811e-03 -6.0000e+00 1.2828e-02 -1.4927e-03 1.1952e-03 3.7782e-03 -6.0000e+00 7.6527e-03 -2.7118e-03 5.1119e-04 1.0400e-03 -6.0000e+00 3.2187e-03 1.0288e-03 2.7214e-04 4.2192e-05 1.6198e-05 -6.0000e+00 2.4096e-04 -6.7560e-03 1.8139e-04 12 9 1 12 1 1 99.93 26.01 0.33 -0.00676 -0.00471 17 5 1 5 0 1180.653 33.75 20.01 26.01 35.05 35.4 999.00 724 -1024 -1700 -1574 -1774 202 412 1579 1117 373 -1154 -937 424 402 198 643 -539 274 183 694 550 -28 1383 803 553 1121 -252 -1014 309 968 1361 1201 757 754 -1941 -1428 -903 -896 -101 -333 -1234 -1162 -1028 -1252 -884 -90 -718 -799 -557 -777 775 1125 369 1204 1026 435 850 564 596 970 714 1382 1162 897 446 -424 -357 -159 385 1476 84 -28 146 200 68 -175 -31 -268 -606 34 -1071 -1259 -1719 -1989 -891 -796 -481 -89 129 351 266 478 147 375 804 822 294 306 495 -79 -439 -655 -702 263 32 -1216 -818 -645 -545 162 521 237 -85 223 31 312 423 287 398 312 -37 -235 237 528 193 749 137 590 892 336 113 -132 -478 -302 281 -49 -115 16 167 -167 -207 -268 -691 282 -439 -700 -665 -687 76 156 590 460 164 -517 -418 182 190 97 339 -299 155 106 408 310 -16 778 466 335 697 -158 -614 184 542 755 694 462 442 -1137 -856 -526 -589 -73 -251 -1037 -983 -893 -1102 -774 -78 -609 -654 -460 -632 630 954 315 1064 934 388 764 509 532 898 644 1303 1119 910 456 -414 -333 -147 360 1419 86 -29 154 206 70 -172 -29 -231 -544 31 -1041 -1286 -1815 -2220 -1002 -919 -588 -108 158 422 313 534 156 387 833 872 329 360 619 -97 -535 -777 -790 296 39 -1513 -1024 -841 -713 220 710 328 -114 291 39 373 511 342 503 407 -49 -314 310 688 240 914 167 696 1079 415 141 -169 -623 -404 378 -68 -163 23 238 -236 -296 -373 -977 SS 20240601T203928.9Z 8918.860751 357 1 54.57 2 16.01 225.84 74.95 263.55 0.00 1 0.00 1 0 17 7.939e-03 6.579e-03 1.287e-04 1.001e-04 1.573089e-01 5.480729e-05 1.820816e-03 -6.000000e+00 4.866325e-03 231.87 -2.00 3.36 -2.00 314.22 0.00e+00 2.472193e-04 4.182364e-06 1.425400e-05 -6.000000e+00 2.182388e-04 288.78 -2.00 20.00 -2.00 313.63 0.00e+00 1.040 0.000 302.00 328.00 3 9.4806e-01 1.4049e-04 1.2985e-02 -6.0000e+00 1.2173e-02 -3.1649e-02 1.5452e-04 7.8165e-03 -6.0000e+00 1.3112e-02 -2.2435e-03 8.8735e-05 3.7955e-03 -6.0000e+00 7.8221e-03 -1.6283e-03 3.7809e-05 1.0509e-03 -6.0000e+00 3.2900e-03 6.4521e-02 2.4677e-04 3.1238e-06 1.6446e-05 -6.0000e+00 2.4628e-04 -6.8326e-03 1.8808e-04 11 8 0 10 0 0 99.08 26.05 0.31 -0.00683 -0.00498 3228 319 1 5 0 16.901 33.75 19.99 26.05 34.83 35.7 997.50 850 -635 -1193 -1801 -2485 -162 459 1381 1323 150 -1440 -786 621 121 319 220 -734 198 709 646 1026 374 932 1021 648 671 32 -840 15 745 1408 1266 1231 444 -2438 -1625 -812 -968 -11 -441 -1290 -1284 -777 -954 -864 -179 -724 -676 -332 -287 659 983 587 1023 549 526 1048 553 334 628 844 1314 1275 1028 489 -710 -122 -123 386 1579 199 -11 80 -2 315 -134 -122 -332 -294 36 -1079 -1431 -1728 -2047 -1014 -737 -481 -6 -15 200 213 575 161 404 937 686 311 444 302 -372 -383 -582 -581 132 185 -1174 -886 -634 -617 203 319 267 107 214 216 291 584 436 343 258 -181 -163 115 310 288 883 183 601 1020 319 198 -217 -376 -122 150 -81 -259 89 31 -237 -103 -244 -758 351 -289 -531 -813 -1033 -64 180 581 581 67 -658 -356 291 60 166 119 -418 114 416 373 601 221 550 618 394 421 20 -532 9 430 802 752 738 274 -1509 -966 -498 -645 -8 -343 -1050 -1073 -665 -827 -748 -152 -627 -565 -275 -233 539 814 513 899 484 473 950 505 302 564 771 1221 1230 1016 489 -698 -116 -113 350 1501 199 -12 84 -2 317 -131 -114 -296 -260 33 -1045 -1443 -1828 -2234 -1133 -858 -579 -7 -19 240 247 640 172 415 962 735 348 529 366 -459 -464 -674 -655 148 216 -1418 -1121 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