File name: Pandora247s1_WhittierCA_20240629_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20241125T193408.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20240629_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240629T150304.9Z 8946.627140 249 1 54.42 2 63.86 78.59 28.49 201.02 0.00 1 0.00 1 0 17 1.565e-02 7.116e-03 6.203e-03 1.906e-03 2.887130e-01 1.010235e-03 3.252718e-03 -6.000000e+00 9.495677e-03 232.08 -2.00 3.36 -2.00 317.33 0.00e+00 7.480019e-04 1.504208e-04 1.525284e-04 -6.000000e+00 4.292789e-04 291.11 -2.00 20.00 -2.00 316.45 0.00e+00 2.256 0.000 302.00 328.00 3 4.3792e+00 2.6914e-03 2.6579e-02 -6.0000e+00 2.3750e-02 -7.1060e-04 3.0167e-03 1.4453e-02 -6.0000e+00 2.5592e-02 -4.9974e-03 1.8047e-03 6.9795e-03 -6.0000e+00 1.5269e-02 -1.7559e-03 8.8311e-04 1.9714e-03 -6.0000e+00 6.4845e-03 5.0853e-04 3.2993e-04 5.9227e-05 2.3632e-05 -6.0000e+00 4.7372e-04 -1.1865e-03 -1.1323e-04 11 8 0 10 0 0 99.86 25.91 0.35 -0.00119 0.00129 35 3 1 5 0 1554.593 33.75 20.00 25.91 28.69 35.1 997.62 -6600 -2164 1220 -4769 -1338 5611 -790 1306 -4633 -1570 -4636 -4954 -2719 476 1999 -2542 330 -636 -809 2974 976 1540 1225 996 1804 -1672 -1064 -657 514 -437 1104 -2457 1025 -1172 -4509 -207 -2163 97 1188 -597 -1032 325 -4032 422 1417 -194 -178 836 -1443 1149 417 749 1994 841 943 1617 795 530 940 500 1157 1395 230 2110 -418 -578 -620 -263 1358 426 561 329 378 162 -62 -146 -198 -1196 -508 -1206 -1386 -1704 -2425 -1278 -744 -504 -75 295 611 -86 579 -315 -60 456 15 247 555 463 -2 -538 -805 -1119 -502 108 -847 -511 -403 -602 354 574 607 216 65 -251 342 -374 731 22 639 -121 422 310 365 224 690 -217 294 972 321 194 -200 -382 -287 376 -119 -1 184 379 -200 -123 -371 -993 -735 -242 129 -494 -126 498 -82 148 -599 -202 -630 -737 -454 89 411 -535 71 -144 -191 695 235 373 310 267 502 -486 -298 -173 131 -116 312 -783 330 -379 -1469 -68 -823 39 560 -320 -595 177 -2339 235 783 -108 -106 484 -857 691 250 477 1325 589 678 1179 587 388 680 370 838 1092 195 1799 -351 -454 -469 -205 1155 377 526 314 352 143 -53 -114 -156 -902 -418 -1052 -1347 -1688 -2563 -1420 -829 -594 -91 362 732 -98 639 -322 -62 485 16 282 700 593 -2 -676 -995 -1304 -582 133 -1118 -667 -552 -869 510 875 951 335 96 -361 458 -493 980 32 919 -182 630 452 543 318 930 -299 397 1291 462 280 -302 -592 -461 599 -201 -1 313 650 -341 -212 -620 -1625 SS 20240629T150734.2Z 8946.630256 252 1 11.91 2 62.95 79.13 28.82 203.19 0.00 1 0.00 1 0 17 1.379e-02 6.782e-03 8.270e-03 3.068e-03 2.836898e-01 1.631005e-03 3.205240e-03 -6.000000e+00 8.364458e-03 232.08 -2.00 3.36 -2.00 316.92 0.00e+00 -1.155617e-05 2.196903e-04 8.148557e-05 -6.000000e+00 3.782757e-04 291.11 -2.00 20.00 -2.00 316.05 0.00e+00 2.187 0.000 302.00 328.00 3 3.8587e+00 4.3075e-03 2.5859e-02 -6.0000e+00 2.0921e-02 -8.7089e-03 4.8125e-03 1.4172e-02 -6.0000e+00 2.2544e-02 -1.3827e-03 2.8227e-03 6.8290e-03 -6.0000e+00 1.3451e-02 -2.7125e-03 1.3547e-03 1.8562e-03 -6.0000e+00 5.7110e-03 9.2613e-04 -7.6833e-05 9.4621e-05 2.3458e-05 -6.0000e+00 4.1744e-04 -5.3953e-04 -1.5197e-04 12 9 1 12 1 1 96.28 25.91 0.23 -0.00054 -0.00112 6 3 1 5 0 1700.795 33.75 19.99 25.91 28.68 35.2 997.55 -7497 2078 -2596 -4752 -2194 1927 852 2186 484 -4373 -4181 -2441 -1010 -1084 940 119 1155 666 1390 2261 2661 1359 -272 1096 2447 -1228 -495 -602 -831 321 1141 -258 1299 -2444 -3053 -214 -1818 -756 -328 -530 -656 241 -3276 -328 620 -590 77 305 14 379 850 439 112 897 266 1659 1225 833 499 929 -305 1750 400 1392 -750 42 -341 -271 1533 624 1084 512 -288 23 -61 -255 -759 -445 -599 -1922 -1009 -1697 -1821 -643 -1015 -489 -9 553 35 713 683 482 117 530 242 -58 358 498 224 -516 -1229 -1079 162 301 -780 -586 -399 -288 104 253 508 -74 302 -131 -57 -67 355 355 250 -35 -194 188 401 23 614 32 171 1255 617 -119 -319 -89 -466 20 87 -21 354 707 -173 -255 -325 -1034 -999 264 -338 -641 -270 232 114 324 71 -692 -677 -422 -197 -242 230 32 317 176 378 628 743 390 -83 350 807 -424 -164 -189 -253 99 379 -94 489 -939 -1148 -82 -745 -365 -172 -312 -387 146 -2093 -204 382 -364 46 180 9 233 556 308 78 647 199 1247 930 628 374 706 -234 1422 353 1243 -657 34 -267 -219 1350 579 1062 486 -283 21 -54 -207 -619 -366 -511 -1765 -967 -1775 -1920 -712 -1151 -586 -11 658 43 818 757 517 120 557 264 -67 436 651 298 -662 -1543 -1272 189 371 -993 -783 -533 -405 148 382 755 -109 436 -184 -74 -89 486 494 355 -51 -287 272 582 33 844 42 222 1690 858 -170 -473 -134 -705 31 140 -36 603 1168 -284 -422 -519 -1682 SS 20240629T152333.9Z 8946.641364 264 1 54.57 2 59.68 81.05 30.22 210.57 0.00 1 0.00 1 0 17 8.788e-03 6.300e-03 6.071e-04 3.092e-04 2.570295e-01 1.656016e-04 2.930598e-03 -6.000000e+00 5.331956e-03 232.08 -2.00 3.36 -2.00 316.16 0.00e+00 4.278468e-04 1.839786e-05 5.517784e-05 -6.000000e+00 2.410116e-04 291.11 -2.00 20.00 -2.00 315.32 0.00e+00 1.973 0.000 302.00 328.00 3 1.2922e+00 4.3235e-04 2.3359e-02 -6.0000e+00 1.3336e-02 -2.2592e-02 4.8057e-04 1.2827e-02 -6.0000e+00 1.4370e-02 -3.2940e-03 2.7631e-04 6.1919e-03 -6.0000e+00 8.5736e-03 -2.0775e-03 1.2668e-04 1.7131e-03 -6.0000e+00 3.6413e-03 1.5554e-02 3.2807e-04 9.5125e-06 2.2178e-05 -6.0000e+00 2.6597e-04 -1.2150e-03 -9.2474e-05 10 0 0 10 0 0 99.87 25.92 0.28 -0.00121 0.00125 963 95 1 5 0 56.659 33.75 20.00 25.92 29.36 35.2 998.76 -707 -725 -1468 -3421 -1822 -1237 -173 453 -412 -2048 -2282 -772 -673 127 463 -653 400 682 826 1274 421 881 898 612 886 482 -538 -189 125 926 959 1314 890 -2359 -2435 -1802 -1655 -133 -67 -864 -839 -356 -689 -570 270 -327 -378 -210 -327 559 1016 576 1175 734 701 1167 595 283 502 610 1184 1347 1377 957 -469 -238 -669 -171 1347 296 283 217 142 375 -170 -426 -962 -924 -433 -1223 -1438 -1776 -2205 -1129 -856 -366 127 258 504 365 593 -60 -25 516 493 306 606 571 -119 -357 -772 -968 -112 212 -1028 -789 -552 -552 348 526 505 244 208 -6 -11 320 285 350 409 -57 -74 163 309 247 769 -92 358 987 378 293 -174 -410 -215 100 -7 -215 170 109 -151 -69 -291 -789 -144 -155 -307 -673 -329 -225 -34 99 -97 -500 -568 -189 -187 40 150 -227 144 254 298 469 158 332 351 254 383 211 -229 -76 48 362 403 556 395 -1059 -1062 -816 -802 -71 -40 -549 -569 -249 -469 -388 191 -230 -261 -142 -220 387 709 430 876 571 560 947 488 230 404 500 977 1149 1253 856 -424 -208 -562 -147 1213 285 279 217 139 360 -156 -370 -787 -763 -389 -1144 -1437 -1856 -2362 -1272 -995 -435 156 310 611 432 666 -64 -26 536 536 358 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