File name: Pandora247s1_WhittierCA_20240711_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20240712T080252.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20240711_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20240711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240711T163953.6Z 8958.694371 147 1 53.47 2 44.86 92.16 108.94 73.35 0.00 1 0.00 1 0 17 3.624e-02 1.555e-02 1.543e-02 6.243e-03 2.106228e-01 3.314123e-03 2.367380e-03 -6.000000e+00 2.223996e-02 231.88 -2.00 3.36 -2.00 316.80 0.00e+00 -4.543448e-04 4.350769e-04 4.103733e-05 -6.000000e+00 1.012547e-03 292.05 -2.00 20.00 -2.00 315.93 0.00e+00 1.409 0.000 302.00 328.00 3 7.7809e+00 8.7278e-03 1.7497e-02 -6.0000e+00 5.5573e-02 1.3412e-02 9.7581e-03 1.0461e-02 -6.0000e+00 5.9843e-02 -8.1223e-04 5.6579e-03 5.0540e-03 -6.0000e+00 3.5741e-02 1.2584e-03 2.6828e-03 1.3987e-03 -6.0000e+00 1.5168e-02 4.3189e-05 1.4876e-03 1.9909e-04 1.7861e-05 -6.0000e+00 1.1312e-03 -5.6367e-03 3.7651e-04 12 9 8 11 8 0 99.97 25.95 1.70 -0.00564 0.00554 20 2 1 5 0 2673.018 33.50 20.00 25.95 30.41 35.1 998.77 900000 1011 586 6105 -12791 6897 13555 18718 11296 -3559 -1097 -9398 -5139 6839 512 2247 -1987 -2990 -2808 -1383 -956 3989 1901 750 4442 9831 -2554 -575 -1951 1188 -1504 369 -2885 4189 -1405 -1864 6925 -5404 1244 3152 -1239 -2842 -127 -12665 514 2221 -3856 -3785 3164 855 1682 1934 721 3033 -1100 996 1525 3943 2367 3422 1421 1041 393 -4609 1771 1419 -2136 -1392 2250 3445 155 -228 236 -269 606 -2602 361 1797 -1511 214 -1133 -21 -765 -1685 -371 -1556 642 194 471 2080 -971 1453 501 -94 -1302 178 27 450 1204 -525 -648 -1800 -52 214 -1337 -600 -969 -451 -575 -69 1603 457 -34 1376 -610 -863 -3357 255 23 407 -269 382 462 405 887 956 494 339 -188 -35 671 -523 699 130 -96 221 -220 -75 480 499 518 -1155 -1297 900000 164 98 933 -2172 898 1667 2381 1712 -665 -203 -1911 -1063 1395 124 585 -568 -892 -861 -430 -303 1209 594 245 1471 3201 -942 -199 -645 364 -476 121 -1036 1443 -500 -649 2306 -2309 587 1694 -772 -1738 -78 -8914 317 1470 -2420 -2534 1922 526 1053 1274 508 2188 -777 705 1091 3036 1665 2602 1020 790 322 -4183 1522 1163 -1677 -1138 1820 2745 140 -219 229 -257 542 -2198 294 1344 -1170 177 -957 -19 -763 -1792 -413 -1876 803 253 618 2626 -1189 1593 506 -90 -1286 187 31 568 1606 -720 -850 -2223 -59 247 -1661 -790 -1343 -650 -794 -99 2388 701 -51 2090 -871 -1151 -4471 336 32 606 -385 545 705 595 1236 1265 625 421 -244 -48 961 -780 1049 202 -144 347 -360 -126 806 829 836 -1832 -2011 SS 20240711T164905.1Z 8958.700753 150 1 6.39 2 42.96 93.55 107.19 74.79 0.00 1 0.00 1 0 17 1.484e-02 9.123e-03 1.091e-02 6.451e-03 2.015588e-01 3.485984e-03 2.283179e-03 -6.000000e+00 9.091149e-03 231.88 -2.00 3.36 -2.00 315.53 0.00e+00 -1.823157e-04 3.447206e-04 2.667769e-05 -6.000000e+00 4.135483e-04 292.05 -2.00 20.00 -2.00 314.74 0.00e+00 1.365 0.000 302.00 328.00 3 5.8435e+00 9.0364e-03 1.6844e-02 -6.0000e+00 2.2716e-02 5.4222e-03 1.0018e-02 9.9498e-03 -6.0000e+00 2.4458e-02 -9.9541e-03 5.7187e-03 4.8162e-03 -6.0000e+00 1.4620e-02 -1.1153e-04 2.5363e-03 1.3197e-03 -6.0000e+00 6.1672e-03 3.1939e-04 2.0084e-04 2.0265e-04 1.8508e-05 -6.0000e+00 4.6048e-04 -4.0883e-03 1.3560e-04 12 9 1 12 1 1 999.00 25.97 0.46 -0.00409 -0.00258 1 2 1 5 0 3193.829 33.75 20.00 25.97 30.58 35.0 999.02 2086 -56 1759 -613 -8250 -209 1601 5837 -295 -3892 -219 728 2007 1669 1795 -1445 2694 -1680 1 -804 700 1213 1735 1720 3335 3177 -1831 -3479 -463 -258 -741 224 446 1016 -1117 -2221 -763 -2192 101 1372 262 -2816 -1041 -2112 -1825 1121 -388 -947 165 139 -342 1021 576 1801 -560 1832 -1892 1570 1472 1320 389 2258 669 643 -147 -1334 197 -918 363 2392 -27 -132 418 -1246 714 -1262 206 705 778 188 -1045 -1137 -1490 -1794 -1197 -288 -225 350 -189 1338 -629 1001 150 1040 1499 1043 25 704 -344 118 -519 -488 464 -314 -246 -709 -937 -609 -641 372 303 53 -288 975 639 214 -526 -638 1390 247 -480 -147 -475 28 712 -209 410 559 367 -701 -547 246 -121 -357 34 107 -758 4 1233 -322 14 522 -645 508 -15 482 -166 -2208 -48 365 1389 -82 -1193 -66 218 629 534 640 -580 1089 -731 1 -367 321 557 798 817 1509 1492 -903 -1672 -220 -117 -339 107 207 483 -529 -1121 -366 -1209 60 926 185 -2175 -814 -1689 -1455 861 -297 -707 118 99 -250 774 463 1497 -461 1506 -1640 1317 1223 1091 331 1983 601 610 -141 -1236 176 -791 317 2241 -27 -139 443 -1315 699 -1225 178 601 664 163 -1023 -1154 -1542 -1967 -1385 -334 -277 423 -232 1664 -751 1138 157 1078 1568 1113 30 861 -431 148 -662 -580 546 -374 -295 -913 -1205 -816 -854 517 441 79 -419 1313 836 276 -664 -828 1781 343 -665 -204 -649 39 928 -274 510 681 464 -902 -739 339 -171 -496 50 156 -1154 7 1909 -501 22 795 -970 SS 20240711T171939.3Z 8958.721983 156 1 54.60 2 36.66 98.63 101.27 79.38 0.00 1 0.00 1 0 17 8.039e-03 6.552e-03 1.969e-04 1.437e-04 1.776063e-01 7.823345e-05 2.051511e-03 -6.000000e+00 4.924614e-03 231.88 -2.00 3.36 -2.00 314.64 0.00e+00 2.755196e-04 6.508714e-06 2.123265e-05 -6.000000e+00 2.240374e-04 292.06 -2.00 20.00 -2.00 313.94 0.00e+00 1.246 0.000 302.00 328.00 3 1.4324e+00 2.0110e-04 1.5211e-02 -6.0000e+00 1.2305e-02 -4.1473e-02 2.2175e-04 8.8344e-03 -6.0000e+00 1.3249e-02 -2.8652e-03 1.2701e-04 4.2815e-03 -6.0000e+00 7.9196e-03 -1.6778e-03 5.4748e-05 1.1809e-03 -6.0000e+00 3.3404e-03 3.1426e-02 3.6421e-05 4.4927e-06 1.7812e-05 -6.0000e+00 2.4947e-04 -3.0506e-03 1.4643e-04 11 8 0 10 0 0 58.74 26.07 0.30 -0.00305 -0.00278 1704 169 1 5 0 32.037 33.75 20.01 26.07 33.10 35.2 1001.04 796 -521 -1174 -1977 -2609 -235 342 1189 1262 88 -1498 -871 630 138 371 276 -667 308 746 661 1043 278 909 1008 614 609 -26 -863 -25 713 1485 1213 1249 268 -2610 -1666 -853 -956 59 -380 -1233 -1195 -700 -918 -819 -207 -744 -691 -401 -267 717 1012 567 1014 527 573 1037 530 324 616 881 1373 1297 1085 474 -761 -73 -164 437 1588 195 36 97 52 301 -209 -179 -422 -343 -7 -1108 -1417 -1790 -2087 -995 -735 -424 54 68 259 251 579 155 408 885 656 321 475 280 -402 -392 -637 -627 94 118 -1212 -882 -634 -613 226 348 266 135 246 186 279 588 421 343 243 -192 -136 124 309 306 887 145 619 995 302 179 -263 -381 -135 132 -69 -260 127 48 -211 -74 -266 -739 289 -197 -459 -791 -964 -83 121 428 500 35 -616 -357 269 62 177 136 -349 164 388 353 567 153 499 570 349 357 -15 -492 -14 391 810 665 723 154 -1503 -964 -489 -596 39 -277 -969 -963 -578 -769 -686 -171 -606 -563 -316 -207 561 831 477 859 462 497 910 468 284 536 780 1275 1216 1073 462 -731 -68 -145 393 1501 194 37 101 54 299 -202 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