File name: Pandora247s1_WhittierCA_20241014_L2Fit_fwvt1c6d20230505p1-8.txt File generation date: 20241125T203935.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20241014_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20241014 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 1616 1766 Nominal wavelengths inside fitting window [nm]: 492.0537 492.1745 492.2954 492.4162 492.5370 492.6577 492.7785 492.8992 493.0200 493.1407 493.2614 493.3820 493.5027 493.6233 493.7440 493.8646 493.9852 494.1057 494.2263 494.3468 494.4674 494.5879 494.7084 494.8288 494.9493 495.0697 495.1901 495.3105 495.4309 495.5513 495.6717 495.7920 495.9123 496.0326 496.1529 496.2732 496.3934 496.5137 496.6339 496.7541 496.8743 496.9944 497.1146 497.2347 497.3548 497.4749 497.5950 497.7151 497.8351 497.9552 498.0752 498.1952 498.3152 498.4351 498.5551 498.6750 498.7949 498.9148 499.0347 499.1545 499.2744 499.3942 499.5140 499.6338 499.7536 499.8734 499.9931 500.1128 500.2325 500.3522 500.4719 500.5916 500.7112 500.8308 500.9504 501.0700 501.1896 501.3091 501.4287 501.5482 501.6677 501.7872 501.9067 502.0261 502.1456 502.2650 502.3844 502.5038 502.6231 502.7425 502.8618 502.9811 503.1004 503.2197 503.3390 503.4582 503.5774 503.6967 503.8158 503.9350 504.0542 504.1733 504.2925 504.4116 504.5307 504.6497 504.7688 504.8878 505.0069 505.1259 505.2449 505.3638 505.4828 505.6017 505.7206 505.8395 505.9584 506.0773 506.1962 506.3150 506.4338 506.5526 506.6714 506.7902 506.9089 507.0276 507.1463 507.2650 507.3837 507.5024 507.6210 507.7397 507.8583 507.9769 508.0954 508.2140 508.3325 508.4511 508.5696 508.6881 508.8065 508.9250 509.0434 509.1618 509.2802 509.3986 509.5170 509.6353 509.7537 509.8720 509.9903 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241014T212725.0Z 9053.894039 181 1 5.95 2 49.85 216.49 119.56 78.96 0.00 1 0.00 1 0 15 3.313e-03 3.287e-03 1.016e-04 1.015e-04 1.249944e+03 5.665097e+00 9.346556e+01 -6.000000e+00 1.787205e+02 288.33 -2.00 20.00 -2.00 505.27 0.00e+00 6.235887e-04 2.768253e-06 3.738425e-05 -6.000000e+00 9.237846e-05 288.33 -2.00 20.00 -2.00 500.47 0.00e+00 6.929243e-02 1.930969e-03 9.643067e-03 -6.000000e+00 6.342700e-02 226.78 -2.00 3.36 -2.00 502.06 0.00e+00 1.548 0.000 489.00 513.00 1 -4.1346e-01 1.4809e-04 2.4909e-03 -6.0000e+00 4.8660e-03 -3.4298e-03 3.8630e-05 2.3917e-04 -6.0000e+00 1.2697e-03 2.3491e+00 4.0315e-04 8.2990e-06 1.4697e-05 -6.0000e+00 2.7676e-04 1.6546e-03 -2.4578e-07 10 0 0 10 0 0 31.94 24.68 1.90 0.00165 0.00445 807 80 2 4 0 7.361 28.50 20.82 24.68 31.19 40.5 1002.87 -813 -669 -163 50 269 456 512 601 447 263 256 29 -222 -340 -430 -400 -270 -15 69 121 253 139 114 310 290 375 494 346 -237 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235 333 434 559 632 531 383 349 142 29 137 233 149 341 305 197 364 458 148 146 7 -318 -409 -166 -138 -28 213 194 91 134 189 252 305 196 -48 -355 -465 -603 -520 SQ 20241014T212731.0Z 9053.894109 181 2 5.95 2 49.86 216.52 119.54 78.98 0.00 1 0.00 1 0 15 3.307e-03 3.281e-03 1.017e-04 1.016e-04 1.242539e+03 5.667678e+00 9.273448e+01 -6.000000e+00 1.783657e+02 288.33 -2.00 20.00 -2.00 505.27 0.00e+00 6.289920e-04 2.771073e-06 3.778035e-05 -6.000000e+00 9.219551e-05 288.33 -2.00 20.00 -2.00 500.48 0.00e+00 7.414623e-02 1.932450e-03 9.675113e-03 -6.000000e+00 6.330025e-02 226.78 -2.00 3.36 -2.00 502.07 0.00e+00 1.548 0.000 489.00 513.00 1 -4.1204e-01 1.4821e-04 2.4951e-03 -6.0000e+00 4.8563e-03 -3.5552e-03 3.8659e-05 2.3888e-04 -6.0000e+00 1.2671e-03 2.3446e+00 3.6747e-04 8.3053e-06 1.4706e-05 -6.0000e+00 2.7621e-04 1.6118e-03 1.4701e-06 10 0 0 10 0 0 25.85 24.68 1.90 0.00161 0.00416 807 80 2 4 0 7.361 29.25 20.82 24.68 31.19 40.5 1002.87 -799 -670 -170 34 287 470 504 573 441 268 256 37 -217 -356 -424 -383 -258 5 67 104 251 149 125 299 280 387 496 336 -218 -284 -457 -522 -279 204 227 377 300 47 -105 -175 -109 -74 157 201 380 354 388 300 207 -238 -469 -748 -910 -704 -488 -238 -19 96 23 37 27 130 137 257 183 102 36 -1 -198 -434 -307 -252 -94 153 131 98 16 -83 -301 -401 -229 -222 -250 -33 -19 -15 -65 -120 -177 -169 -176 115 198 209 310 339 175 -27 -428 -630 -763 -679 -413 2 -110 74 -67 -377 -421 -344 -244 -41 226 318 420 553 630 524 363 360 147 30 152 232 145 360 327 217 356 464 132 173 3 -332 -423 -180 -162 -7 208 221 100 156 178 273 331 208 -53 -399 -517 -635 -544 -779 -656 -170 34 295 488 528 600 462 279 265 38 -222 -362 -429 -389 -262 6 70 108 261 156 130 312 294 406 519 349 -225 -287 -455 -522 -281 208 237 395 313 48 -108 -178 -111 -76 161 208 395 370 402 310 210 -240 -466 -732 -888 -690 -482 -238 -19 99 23 38 28 133 140 262 186 102 36 -1 -196 -428 -299 -246 -91 151 130 98 15 -80 -290 -384 -220 -214 -243 -33 -18 -15 -64 -118 -174 -167 -175 115 199 210 311 337 174 -27 -411 -599 -721 -643 -398 2 -110 73 -67 -372 -408 -336 -239 -41 226 319 423 558 634 529 364 358 146 30 148 228 142 352 320 213 350 452 128 166 3 -318 -402 -172 -156 -7 204 219 99 154 177 273 328 208 -52 -389 -497 -605 -523 SQ 20241014T212737.1Z 9053.894179 181 3 5.95 2 49.87 216.55 119.52 78.99 0.00 1 0.00 1 0 15 3.296e-03 3.271e-03 1.018e-04 1.017e-04 1.251166e+03 5.672851e+00 9.376320e+01 -6.000000e+00 1.777805e+02 288.33 -2.00 20.00 -2.00 505.27 0.00e+00 6.357917e-04 2.772495e-06 3.817317e-05 -6.000000e+00 9.189288e-05 288.33 -2.00 20.00 -2.00 500.48 0.00e+00 7.319877e-02 1.933735e-03 9.684919e-03 -6.000000e+00 6.309280e-02 226.78 -2.00 3.36 -2.00 502.07 0.00e+00 1.549 0.000 489.00 513.00 1 -4.1090e-01 1.4829e-04 2.4993e-03 -6.0000e+00 4.8403e-03 -3.5585e-03 3.8684e-05 2.3940e-04 -6.0000e+00 1.2630e-03 2.3417e+00 4.1291e-04 8.3142e-06 1.4890e-05 -6.0000e+00 2.7530e-04 1.5466e-03 1.4528e-06 10 0 0 10 0 0 25.99 24.68 1.90 0.00155 0.00441 807 80 2 4 0 7.361 29.25 20.82 24.68 31.19 40.5 1002.87 -787 -666 -157 31 275 492 495 565 453 274 234 51 -218 -352 -437 -383 -241 -21 70 101 243 140 123 299 252 390 492 355 -239 -298 -441 -522 -253 215 214 361 286 33 -91 -166 -101 -53 143 232 381 362 361 320 208 -221 -464 -762 -912 -715 -466 -247 -18 111 17 40 18 125 137 251 188 108 37 -12 -208 -425 -345 -264 -105 161 155 109 7 -95 -281 -398 -259 -227 -239 -50 -18 -30 -72 -101 -163 -167 -165 101 210 220 317 354 192 -56 -433 -625 -751 -682 -419 -27 -94 87 -74 -387 -414 -334 -243 -50 240 318 441 551 618 527 347 362 150 25 150 240 148 349 331 209 364 444 132 149 17 -309 -408 -172 -164 -38 216 203 103 175 184 241 324 206 -52 -382 -519 -622 -547 -767 -651 -156 32 283 510 519 592 474 286 242 52 -223 -357 -441 -389 -245 -21 72 107 256 146 129 312 265 409 514 369 -248 -301 -439 -522 -254 220 223 378 298 34 -94 -169 -103 -54 147 241 396 377 373 331 212 -224 -461 -745 -890 -700 -460 -247 -19 113 18 41 19 128 140 255 192 109 37 -12 -205 -418 -336 -258 -103 159 154 108 7 -92 -271 -382 -249 -219 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