File name: Pandora247s1_WhittierCA_20241027_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20241125T203718.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20241027_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20241027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241027T150904.8Z 9066.631306 197 1 5.45 2 78.89 114.24 30.35 141.73 0.00 1 0.00 1 0 17 1.655e-01 8.879e-03 1.655e-01 6.356e-03 5.202761e-01 3.352774e-03 5.771167e-03 -6.000000e+00 9.811441e-02 225.84 -2.00 3.36 -2.00 319.83 0.00e+00 2.326365e-03 1.087868e-03 8.360055e-04 -6.000000e+00 4.457669e-03 286.97 -2.00 20.00 -2.00 319.10 0.00e+00 5.006 0.002 302.00 328.00 3 1.5655e+00 9.7781e-03 5.5361e-02 -6.0000e+00 2.4211e-01 2.4909e-02 1.1850e-02 2.5963e-02 -6.0000e+00 2.6223e-01 -7.8149e-02 9.9056e-03 1.3562e-02 -6.0000e+00 1.5687e-01 2.5537e-02 5.1183e-03 4.9156e-03 -6.0000e+00 6.7229e-02 4.9239e-04 8.9675e-04 1.9183e-04 5.8607e-05 -6.0000e+00 4.9980e-03 1.6043e-04 1.9272e-05 12 9 1 12 1 1 -543.77 25.26 0.48 0.00016 0.00690 7 8 1 5 0 680.637 33.25 20.00 25.26 25.93 34.4 1003.24 -106940 49999 41133 -80189 -33498 -39206 -19234 -45998 -23403 -61799 25847 -101 -13355 -23677 -13276 6124 37393 -11094 -10228 5096 -3504 10771 10402 -19790 -2627 -26730 2482 -11871 -2761 -748 9857 -10839 -5745 -1752 -10579 2237 -2273 2871 2066 -350 -4686 3295 -5844 -1026 673 1779 282 3745 1559 1619 1433 1880 2567 2352 4012 4770 689 2811 1429 -1007 -1187 2126 -164 3119 -1014 272 901 -157 575 630 431 -565 957 1055 -659 -1128 115 -1574 -2025 1018 -1522 -1971 -2133 -1350 -1407 541 145 1231 691 282 287 -1068 -366 -225 814 21 1455 403 373 -903 -738 -1181 -125 -22 -1222 -580 -1347 -329 -97 665 312 242 682 359 -868 -841 823 165 582 -757 379 266 743 617 348 -10 938 676 96 127 -878 -23 -323 314 -378 -207 162 483 -78 253 -641 -393 -2916 310 280 -1739 -436 -559 -250 -884 -392 -1608 304 -2 -339 -822 -494 213 1043 -543 -526 234 -178 487 503 -1398 -166 -2203 151 -817 -178 -52 721 -1115 -609 -179 -1167 230 -283 411 356 -64 -977 670 -1347 -229 151 400 65 863 385 431 422 605 886 865 1516 1846 280 1105 563 -416 -484 934 -82 1593 -537 138 454 -85 324 395 288 -385 622 640 -401 -635 62 -921 -1257 711 -1153 -1655 -1924 -1204 -1344 537 150 1273 702 273 258 -985 -333 -205 828 23 1681 515 489 -1149 -864 -1365 -141 -26 -1481 -738 -1838 -452 -139 1028 487 382 1090 544 -1267 -1213 1207 259 954 -1218 625 426 1146 916 525 -15 1376 1022 153 223 -1571 -42 -604 622 -762 -432 343 1028 -163 507 -1286 -762 SS 20241027T151414.0Z 9066.634884 200 1 54.56 2 77.92 115.05 29.73 143.91 0.00 1 0.00 1 0 17 9.079e-02 6.051e-03 1.199e-02 8.494e-04 4.897028e-01 4.437347e-04 5.472578e-03 -6.000000e+00 5.381893e-02 225.84 -2.00 3.36 -2.00 319.32 0.00e+00 1.313482e-03 1.217744e-04 5.683438e-04 -6.000000e+00 2.446458e-03 286.97 -2.00 20.00 -2.00 318.57 0.00e+00 4.635 0.001 302.00 328.00 3 4.7647e-01 1.2496e-03 5.1421e-02 -6.0000e+00 1.3280e-01 -1.5975e-02 1.4711e-03 2.4326e-02 -6.0000e+00 1.4386e-01 -3.1433e-02 1.1388e-03 1.2183e-02 -6.0000e+00 8.6056e-02 5.9700e-03 5.9833e-04 3.8095e-03 -6.0000e+00 3.6868e-02 2.1595e-03 3.8120e-04 2.5521e-05 4.5361e-05 -6.0000e+00 2.7426e-03 1.2015e-03 -3.4193e-05 10 0 0 10 0 0 87.00 25.26 0.33 0.00120 0.00407 352 35 1 5 0 154.966 33.25 20.00 25.26 26.29 34.2 1003.20 -27930 -31109 -25229 -48623 -26688 -29901 -37261 -27945 -27807 -25619 -13857 -19874 -14620 -7724 752 -9490 -776 -3611 -1372 843 -3677 -2107 -2563 -2809 -5729 -2909 -4458 -3862 -35 -1055 95 -2999 882 -1636 -3142 -1423 -2619 -286 445 -97 -267 -222 -2135 160 1284 364 192 155 -574 689 1197 1039 1233 1108 935 1535 1014 -72 -232 665 1612 2053 1360 2122 311 462 -270 473 1711 707 797 489 171 386 -448 -692 -1375 -1718 -945 -1461 -1352 -1864 -2151 -943 -632 -3 311 612 765 449 767 -232 -54 384 204 147 359 430 -319 -403 -704 -964 -223 42 -1248 -856 -590 -466 326 388 408 187 267 57 -95 203 329 274 237 -114 -91 274 391 223 589 -317 337 972 316 216 -254 -444 -161 82 -45 -220 221 240 -124 -5 -165 -586 -520 -652 -501 -1156 -488 -587 -883 -685 -746 -713 -371 -658 -563 -339 36 -564 -46 -239 -94 59 -274 -159 -207 -247 -553 -280 -429 -361 -3 -107 11 -407 124 -238 -458 -216 -424 -55 101 -25 -76 -61 -618 46 371 107 58 48 -185 236 449 427 504 482 426 718 481 -34 -109 316 815 1065 784 1281 189 271 -159 296 1109 515 579 361 123 276 -294 -448 -869 -1074 -667 -1124 -1110 -1695 -1985 -918 -622 -3 335 663 809 450 754 -216 -49 375 213 166 436 544 -415 -528 -853 -1141 -259 51 -1574 -1085 -792 -642 467 605 643 298 410 86 -142 299 479 423 371 -183 -143 436 603 332 872 -458 486 1442 500 358 -448 -791 -289 157 -88 -431 440 481 -246 -9 -320 -1104 SS 20241027T151931.7Z 9066.638561 203 1 54.56 2 76.93 115.90 29.12 146.23 0.00 1 0.00 1 0 17 6.212e-02 5.918e-03 6.875e-03 6.552e-04 4.583823e-01 3.417963e-04 5.151056e-03 -6.000000e+00 3.681298e-02 225.84 -2.00 3.36 -2.00 318.97 0.00e+00 1.270909e-03 8.354585e-05 4.104327e-04 -6.000000e+00 1.674213e-03 286.97 -2.00 20.00 -2.00 318.18 0.00e+00 4.308 0.001 302.00 328.00 3 3.3568e-01 9.4676e-04 4.7851e-02 -6.0000e+00 9.0836e-02 -2.3011e-02 1.0994e-03 2.2694e-02 -6.0000e+00 9.8407e-02 -2.5824e-02 7.9912e-04 1.1284e-02 -6.0000e+00 5.8867e-02 5.2348e-03 4.1957e-04 3.4785e-03 -6.0000e+00 2.5213e-02 3.4949e-03 1.2115e-04 1.9839e-05 4.1856e-05 -6.0000e+00 1.8769e-03 1.9289e-03 -8.7075e-05 10 0 0 10 0 0 99.56 25.26 0.34 0.00193 0.00284 479 47 1 5 0 113.897 33.25 20.00 25.26 26.74 34.3 1003.53 -18202 -20242 -18508 -27798 -18735 -25665 -26623 -12731 -17444 -19471 -17001 -12029 -13263 -6931 -1683 -3775 -2144 -188 -560 -249 -2028 -204 -1427 -641 -2178 -1495 -3341 -2757 -1935 34 1016 519 1241 -2228 -2341 -1179 -1997 -275 216 -476 -757 226 -1175 7 519 90 190 170 -397 831 1376 1141 1450 1152 907 907 721 0 195 803 1509 1874 1861 1416 4 104 -176 76 1506 466 465 407 135 417 -352 -578 -807 -1137 -837 -1529 -1425 -1801 -1949 -1101 -746 -110 399 491 648 617 618 -4 91 323 259 184 500 404 -288 -540 -971 -1003 -90 19 -1278 -851 -696 -453 353 465 376 198 288 79 46 284 278 351 313 -101 -84 105 353 252 615 -181 422 832 323 197 -203 -370 -194 119 -89 -178 246 89 -89 -23 -200 -585 -464 -570 -513 -797 -469 -713 -835 -394 -617 -741 -678 -527 -714 -424 -115 -294 -178 -16 -52 -24 -202 -20 -154 -74 -273 -190 -425 -339 -239 4 138 80 204 -379 -393 -207 -409 -67 57 -144 -250 78 -423 2 189 31 65 59 -145 320 578 524 664 560 461 475 382 0 101 425 849 1085 1184 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