File name: Pandora247s1_WhittierCA_20241105_L2Fit_fout2c2d20221229p1-8.txt File generation date: 20241106T074339.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v2d20221229.txt Level 1 file used: Pandora247s1_WhittierCA_20241105_L1_smca1c2d20221229p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20241105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0208 305.1616 305.3025 305.4433 305.5842 305.7250 305.8658 306.0066 306.1474 306.2881 306.4289 306.5696 306.7104 306.8511 306.9918 307.1325 307.2732 307.4139 307.5546 307.6952 307.8359 307.9765 308.1171 308.2577 308.3983 308.5389 308.6795 308.8201 308.9607 309.1012 309.2417 309.3823 309.5228 309.6633 309.8038 309.9443 310.0847 310.2252 310.3656 310.5061 310.6465 310.7869 310.9273 311.0677 311.2081 311.3484 311.4888 311.6291 311.7695 311.9098 312.0501 312.1904 312.3307 312.4710 312.6112 312.7515 312.8917 313.0320 313.1722 313.3124 313.4526 313.5928 313.7330 313.8731 314.0133 314.1534 314.2936 314.4337 314.5738 314.7139 314.8540 314.9941 315.1341 315.2742 315.4142 315.5542 315.6943 315.8343 315.9743 316.1142 316.2542 316.3942 316.5341 316.6740 316.8140 316.9539 317.0938 317.2337 317.3736 317.5134 317.6533 317.7931 317.9330 318.0728 318.2126 318.3524 318.4922 318.6320 318.7717 318.9115 319.0512 319.1910 319.3307 319.4704 319.6101 319.7498 319.8894 320.0291 320.1687 320.3084 320.4480 320.5876 320.7272 320.8668 321.0064 321.1460 321.2855 321.4251 321.5646 321.7041 321.8436 321.9831 322.1226 322.2621 322.4016 322.5410 322.6804 322.8199 322.9593 323.0987 323.2381 323.3775 323.5168 323.6562 323.7955 323.9349 324.0742 324.2135 324.3528 324.4921 324.6314 324.7706 324.9099 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241105T144737.6Z 9075.616407 53 1 54.34 2 84.70 113.28 130.30 101.03 0.00 1 0.00 1 0 33 1.211e+00 5.176e-02 4.160e-01 1.625e-02 9.521303e-01 1.012162e-02 1.480583e-02 -6.000000e+00 7.554807e-01 225.18 -2.00 3.36 -2.00 322.36 0.00e+00 -4.214784e-02 6.253439e-03 1.588163e-02 -6.000000e+00 4.086266e-02 286.01 -2.00 20.00 -2.00 321.86 0.00e+00 9.395 0.012 302.00 328.00 3 9.9730e-01 4.3515e-02 1.2101e-01 -6.0000e+00 1.8669e+00 1.5301e+00 5.8538e-02 9.0563e-02 -6.0000e+00 2.0381e+00 -2.1928e+00 4.3539e-02 7.6845e-02 -6.0000e+00 1.2078e+00 8.6771e-01 1.9850e-02 3.7949e-02 -6.0000e+00 5.1480e-01 8.8261e-06 -1.9501e-04 5.0498e-04 7.7055e-04 -6.0000e+00 4.1035e-02 -1.0288e-04 1.0284e-04 12 8 8 10 0 0 19.28 25.20 1.31 -0.00010 -0.00157 30 3 1 5 0 1811.190 33.25 20.00 25.20 21.14 34.0 1001.92 900000 225236 361036 900000 72800 172729 900000 -8371 425180 900000 82624 900000 368412 900000 900000 900000 153629 900000 182620 149110 190502 68232 900000 58202 321378 900000 15071 900000 900000 188277 17844 382524 122896 900000 271713 900000 900000 900000 83621 297870 310727 139939 99878 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3996 4640 3663 5477 6218 4728 2637 4928 5247 1616 6553 90 -3388 2687 -513 3157 3478 1508 -3319 -4452 -7180 1686 -3701 -615 -3484 152 195 -1454 -711 -2690 -5113 -2716 -2332 2100 3143 435 4493 -982 -11179 1645 -1996 -1745 -2552 -5730 3240 5209 6671 -668 5358 5658 954 -1215 382 -5981 1326 2381 -729 -7 2617 270 7049 1369 662 -3598 -7929 SS 20241105T151852.3Z 9075.638105 60 1 54.40 2 78.86 118.06 124.28 104.23 0.00 1 0.00 1 0 17 2.145e-01 6.930e-03 5.971e-02 1.793e-03 5.986837e-01 9.569190e-04 6.657478e-03 -6.000000e+00 1.280880e-01 225.18 -2.00 3.36 -2.00 320.16 0.00e+00 2.150099e-03 3.507380e-04 7.400041e-04 -6.000000e+00 5.826851e-03 286.01 -2.00 20.00 -2.00 319.49 0.00e+00 4.996 0.002 302.00 328.00 3 2.1590e+00 2.8660e-03 5.7266e-02 -6.0000e+00 3.1563e-01 3.5430e-02 3.5863e-03 2.9958e-02 -6.0000e+00 3.4193e-01 -8.1854e-02 3.2001e-03 1.5517e-02 -6.0000e+00 2.0472e-01 2.6519e-02 1.6230e-03 5.1834e-03 -6.0000e+00 8.6916e-02 2.4549e-04 -7.3388e-04 5.2601e-05 6.5004e-05 -6.0000e+00 6.6430e-03 -9.0956e-04 6.6873e-05 11 8 0 10 0 0 99.63 25.21 0.36 -0.00091 -0.00642 115 11 1 5 0 472.962 33.25 19.99 25.21 24.25 34.1 1001.94 -79836 -74738 -68705 -31617 -105040 -23178 -49523 -111495 -2907 -68883 -62432 -21074 -48249 -22021 -44023 -10906 -41094 -15799 -4243 -9847 -5740 -19181 -5654 -11809 -13072 -16504 -20433 -18593 -6867 -7736 -6397 1397 -6784 1374 -7961 -5835 4717 -1761 -3112 2639 -110 -1762 -43 -12693 684 3733 1626 2131 753 -439 2098 2464 2849 2656 2112 2266 2168 793 1325 148 2277 2543 2819 145 3272 507 718 941 488 1856 576 603 215 492 -88 -748 -586 33 -1375 -1455 -772 -906 -1666 -1965 -1179 -701 -54 226 433 483 -105 609 133 417 590 368 -33 624 335 -554 -502 -852 -464 -51 -320 -1456 -946 -812 -464 313 112 234 82 218 342 112 203 536 155 195 -258 -10 288 344 443 478 171 729 953 56 -27 -408 -380 -199 149 -126 -91 239 107 -137 -67 -36 -468 -712 -758 -721 -232 -1543 -146 -424 -1989 -20 -1000 -917 -228 -827 -366 -1139 -244 -1430 -475 -124 -324 -189 -738 -197 -469 -571 -797 -1054 -936 -306 -364 -336 80 -486 99 -639 -458 356 -164 -357 342 -17 -300 -8 -2409 128 689 314 420 157 -89 455 592 752 764 653 735 727 272 447 50 767 921 1139 61 1436 230 321 426 239 1011 326 362 131 289 -52 -407 -295 16 -739 -901 -511 -688 -1312 -1670 -1062 -625 -51 219 422 459 -95 550 115 361 552 366 -35 759 422 -724 -630 -1049 -525 -57 -371 -1816 -1170 -1069 -624 461 172 383 130 355 529 166 297 806 247 324 -415 -16 459 530 656 720 251 1078 1452 91 -48 -751 -736 -389 309 -264 -197 505 227 -296 -139 -75 -927 SS 20241105T152409.9Z 9075.641781 63 1 54.16 2 77.90 118.91 123.26 104.77 0.00 1 0.00 1 0 17 2.763e-01 1.393e-02 1.881e-01 5.361e-03 5.537998e-01 2.872204e-03 6.127398e-03 -6.000000e+00 1.660353e-01 225.18 -2.00 3.36 -2.00 320.52 0.00e+00 1.271768e-03 1.164661e-03 9.577480e-04 -6.000000e+00 7.837839e-03 286.01 -2.00 20.00 -2.00 319.86 0.00e+00 4.628 0.001 302.00 328.00 3 4.2256e+00 9.0517e-03 5.3163e-02 -6.0000e+00 4.0904e-01 8.1792e-02 1.1512e-02 2.8198e-02 -6.0000e+00 4.4337e-01 -1.4941e-01 1.0286e-02 1.4476e-02 -6.0000e+00 2.6465e-01 5.8332e-02 5.1179e-03 4.3706e-03 -6.0000e+00 1.1220e-01 4.5551e-05 -8.5819e-04 1.6735e-04 6.0547e-05 -6.0000e+00 8.6134e-03 1.6528e-04 -1.0088e-06 12 8 8 10 0 0 99.98 25.21 0.34 0.00017 -0.00628 57 6 1 5 0 949.980 33.25 20.00 25.21 24.39 33.9 1001.30 100723 -84952 -113329 101688 -72368 -3127 900000 -161209 -76022 -980 -31431 900000 -58360 46421 8379 51805 -40650 30017 -11199 20261 27644 50003 36361 -15079 -1047 17146 -28138 7674 21814 18598 -4433 9131 -12022 4743 556 1465 43106 2180 9890 27173 4890 -1029 3831 -40064 3385 10536 3765 6842 10175 -8388 -3296 4744 8812 3847 6638 6515 7956 4307 1013 1872 7713 2597 1603 -6968 9480 634 531 1201 -206 1525 -1010 3217 -737 -545 424 -930 -37 1491 102 -549 -433 -883 -393 -1561 -673 505 409 -593 1099 274 -879 85 -1855 518 -134 717 -381 188 -914 -836 -1208 -277 -1144 164 516 -1077 -1077 -1175 -1073 469 479 628 431 156 474 -99 -932 594 43 315 -151 -367 589 1204 532 445 280 119 729 44 103 0 -237 331 -295 -152 111 -447 489 94 -30 146 -1021 526 -1211 -2315 531 -928 -19 900000 -5591 -1264 -9 -427 900000 -1342 461 149 704 -1572 627 -380 529 693 1019 874 -646 -42 609 -1603 301 730 661 -220 458 -848 305 37 97 2005 177 894 2457 629 -153 571 -9527 529 1553 602 1080 1601 -1670 -675 989 1934 959 1710 1757 2179 1231 295 533 2112 804 556 -2910 3557 259 212 481 -90 733 -502 1625 -391 -278 219 -444 -16 627 47 -288 -239 -557 -272 -1176 -536 424 363 -552 1012 248 -762 68 -1438 392 -110 658 -404 206 -1105 -1035 -1441 -301 -1268 177 582 -1203 -1272 -1478 -1456 689 712 987 687 242 753 -151 -1413 915 70 497 -243 -582 970 1905 814 655 401 172 1137 70 182 -1 -468 687 -607 -329 248 -1025 1115 212 -64 295 -2178 SS 20241105T152930.9Z 9075.645497 66 1 54.66 2 76.93 119.78 122.24 105.32 0.00 1 0.00 1 0 17 1.181e-01 5.961e-03 1.484e-02 8.148e-04 5.269276e-01 4.284892e-04 5.899566e-03 -6.000000e+00 7.052480e-02 225.18 -2.00 3.36 -2.00 319.47 0.00e+00 1.414535e-03 1.242614e-04 4.796210e-04 -6.000000e+00 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