File name: Pandora247s1_WhittierCA_20241105_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20241125T204054.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20241105_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20241105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241105T144737.6Z 9075.616407 53 1 54.34 2 84.70 113.28 130.30 101.03 0.00 1 0.00 1 0 25 1.091e+00 5.113e-02 4.081e-01 1.623e-02 9.452914e-01 1.000309e-02 1.407179e-02 -6.000000e+00 6.746638e-01 225.18 -2.00 3.36 -2.00 322.34 0.00e+00 -4.276824e-02 6.108256e-03 1.156524e-02 -6.000000e+00 3.644159e-02 286.01 -2.00 20.00 -2.00 321.84 0.00e+00 9.395 0.012 302.00 328.00 3 2.2579e-01 4.2812e-02 1.0948e-01 -6.0000e+00 1.6675e+00 1.5154e+00 5.7387e-02 6.0610e-02 -6.0000e+00 1.8205e+00 -2.1816e+00 4.2541e-02 6.1601e-02 -6.0000e+00 1.0784e+00 8.6238e-01 1.9487e-02 3.8045e-02 -6.0000e+00 4.6140e-01 1.9582e-05 8.2315e-04 4.9803e-04 7.2194e-04 -6.0000e+00 3.5790e-02 1.1884e-03 -1.6149e-05 12 8 8 10 0 0 4.47 25.20 1.31 0.00119 0.00737 30 3 1 5 0 1811.190 33.25 20.00 25.20 21.14 34.0 1001.92 216684 322903 900000 69719 160699 900000 -10692 357848 900000 82729 900000 329688 900000 900000 900000 148376 900000 165636 143001 179827 64845 900000 56150 294661 900000 17253 900000 900000 175484 15330 313682 116958 900000 244039 900000 900000 900000 80445 276715 271952 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5349 3858 4508 3534 5390 6167 4666 2579 4912 5272 1692 6625 165 -3395 2608 -661 2975 3306 1333 -3331 -4547 -6943 1909 -3567 -671 -3883 -159 134 -1416 -584 -2767 -5236 -2742 -2047 2404 3357 349 4187 -1344 -11607 1377 -2046 -1587 -2455 -5751 3370 5305 6807 -562 5186 5278 1023 -899 644 -5893 1082 2085 -682 182 2705 371 7314 1484 537 -3835 -8175 SS 20241105T151852.3Z 9075.638105 60 1 54.40 2 78.86 118.06 124.28 104.23 0.00 1 0.00 1 0 17 2.082e-01 7.107e-03 5.642e-02 1.787e-03 5.955953e-01 9.498037e-04 6.608319e-03 -6.000000e+00 1.230605e-01 225.18 -2.00 3.36 -2.00 320.15 0.00e+00 1.805466e-03 3.465704e-04 9.702915e-04 -6.000000e+00 5.587205e-03 286.01 -2.00 20.00 -2.00 319.48 0.00e+00 4.996 0.002 302.00 328.00 3 1.3809e+00 2.8425e-03 5.7194e-02 -6.0000e+00 3.0330e-01 2.7058e-02 3.5620e-03 2.9866e-02 -6.0000e+00 3.2877e-01 -7.6382e-02 3.1917e-03 1.5541e-02 -6.0000e+00 1.9666e-01 2.4108e-02 1.6204e-03 5.0991e-03 -6.0000e+00 8.4276e-02 5.4306e-04 6.3301e-06 5.1862e-05 6.3730e-05 -6.0000e+00 6.2874e-03 9.8199e-04 -9.1071e-05 11 8 0 10 0 0 99.63 25.21 0.36 0.00098 0.00103 115 11 1 5 0 472.962 33.25 19.99 25.21 24.25 34.1 1001.94 -76244 -69677 -33133 -106052 -26432 -52208 -113623 -4965 -69303 -63293 -23212 -50069 -23706 -45067 -11733 -41596 -16437 -4795 -10205 -6013 -19614 -6306 -12131 -13351 -15979 -19605 -18032 -7060 -8510 -7267 896 -7040 1807 -7853 -6495 3466 -2660 -3533 2749 310 -1383 329 -12312 893 3875 1692 2073 536 -881 1731 2202 2757 2613 2195 2405 2474 1203 1563 148 1986 2189 2688 317 3692 688 483 429 -74 1673 738 898 577 845 256 -611 -810 -432 -1956 -1868 -967 -975 -1670 -2056 -1291 -706 37 417 699 768 67 612 -82 30 255 146 -154 664 585 -278 -357 -952 -840 -384 -303 -1301 -884 -801 -497 367 287 457 232 234 189 -182 -103 358 131 325 -147 17 269 365 455 469 -2 501 929 195 110 -347 -448 -287 140 -60 -54 271 195 -61 -78 -104 -592 -784 -740 -248 -1570 -170 -455 -2058 -35 -1014 -937 -255 -863 -396 -1170 -264 -1449 -495 -140 -336 -198 -755 -220 -482 -586 -771 -1011 -908 -315 -400 -381 51 -505 130 -629 -509 261 -248 -404 355 47 -235 58 -2332 166 714 326 408 101 -179 374 528 726 750 677 778 828 412 526 50 668 792 1083 134 1616 312 215 193 -36 909 417 539 351 494 152 -332 -407 -212 -1047 -1154 -639 -738 -1311 -1742 -1160 -628 35 403 679 728 61 551 -71 26 238 144 -165 805 734 -362 -446 -1168 -946 -421 -350 -1616 -1088 -1050 -666 539 440 746 367 379 291 -268 -151 536 207 540 -236 28 428 560 671 703 -2 738 1411 318 197 -637 -865 -559 289 -125 -117 571 413 -133 -161 -213 -1170 SS 20241105T152409.9Z 9075.641781 63 1 54.16 2 77.90 118.91 123.26 104.77 0.00 1 0.00 1 0 17 2.582e-01 1.410e-02 1.596e-01 5.336e-03 5.508544e-01 2.850848e-03 6.090923e-03 -6.000000e+00 1.536929e-01 225.18 -2.00 3.36 -2.00 320.51 0.00e+00 9.076395e-04 1.147365e-03 1.339162e-03 -6.000000e+00 7.263719e-03 286.01 -2.00 20.00 -2.00 319.85 0.00e+00 4.628 0.001 302.00 328.00 3 3.4465e+00 8.9665e-03 5.3215e-02 -6.0000e+00 3.7865e-01 7.6809e-02 1.1395e-02 2.8521e-02 -6.0000e+00 4.1072e-01 -1.4919e-01 1.0199e-02 1.4538e-02 -6.0000e+00 2.4482e-01 5.8401e-02 5.0849e-03 4.2559e-03 -6.0000e+00 1.0481e-01 1.0082e-04 1.8608e-05 1.6462e-04 5.9208e-05 -6.0000e+00 7.8557e-03 2.0166e-03 -1.1760e-04 12 8 8 10 0 0 99.98 25.21 0.32 0.00202 0.00216 57 6 1 5 0 949.980 33.25 20.00 25.21 24.39 33.9 1001.30 -86176 -113144 86062 -74119 -16313 900000 -161250 -76870 -9234 -33385 900000 -60063 41921 6319 45521 -40864 28576 -11651 17510 26815 48442 34972 -15303 -2246 17418 -27946 8084 19707 17475 -5359 8491 -11961 5172 655 760 41668 1248 9447 27239 5414 -410 4421 -39380 3785 10841 3999 6917 10048 -8894 -3832 4610 8536 3713 6826 6751 8351 4810 1390 1947 7519 2160 1390 -6697 9948 906 374 736 -867 1349 -937 3543 -334 -229 790 -762 -215 1008 -531 -1011 -682 -987 -420 -1743 -813 473 475 -425 1336 550 -731 69 -2036 132 -488 462 -542 228 -673 -561 -1098 -364 -1550 -193 530 -950 -1033 -1161 -1112 509 638 868 581 182 335 -376 -1224 424 28 431 -20 -312 601 1218 533 455 123 -122 708 179 255 55 -295 229 -300 -80 151 -414 574 161 -45 73 -1154 -1263 -2354 448 -981 -116 900000 -5642 -1309 -96 -469 900000 -1406 436 115 663 -1594 609 -400 474 683 1008 855 -661 -92 625 -1613 320 677 627 -268 428 -846 334 44 51 1951 101 855 2465 695 -61 658 -9340 591 1596 639 1090 1578 -1772 -785 959 1874 925 1754 1815 2280 1371 403 553 2053 667 481 -2787 3720 370 149 294 -376 646 -464 1783 -177 -116 407 -362 -94 423 -241 -528 -375 -620 -290 -1308 -645 395 420 -393 1225 496 -631 55 -1571 99 -397 422 -573 248 -810 -692 -1304 -394 -1710 -207 593 -1056 -1215 -1453 -1502 745 1021 1358 921 281 530 -570 -1847 650 45 677 -32 -492 985 1917 813 667 175 -176 1099 288 447 102 -581 473 -613 -174 335 -945 1302 358 -95 147 -2450 SS 20241105T152930.9Z 9075.645497 66 1 54.66 2 76.93 119.78 122.24 105.32 0.00 1 0.00 1 0 17 1.178e-01 6.119e-03 1.368e-02 8.120e-04 5.242330e-01 4.252773e-04 5.849592e-03 -6.000000e+00 6.961611e-02 225.18 -2.00 3.36 -2.00 319.46 0.00e+00 1.289358e-03 1.226218e-04 5.533767e-04 -6.000000e+00 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