File name: Pandora247s1_WhittierCA_20250416_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20250417T075512.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20250416_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20250416 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250416T195155.7Z 9237.827728 395 1 16.17 2 23.55 180.07 144.72 270.61 0.00 1 0.00 1 0 17 7.823e-03 6.481e-03 1.897e-03 1.399e-03 1.743846e-01 7.518227e-04 2.025179e-03 -6.000000e+00 4.699567e-03 229.31 -2.00 3.36 -2.00 314.58 0.00e+00 1.805433e-04 6.039626e-05 1.963166e-05 -6.000000e+00 2.086038e-04 284.50 -2.00 20.00 -2.00 314.00 0.00e+00 1.091 0.000 302.00 328.00 3 4.0323e+00 1.9225e-03 1.3842e-02 -6.0000e+00 1.1702e-02 7.2028e-03 2.1237e-03 8.5540e-03 -6.0000e+00 1.2649e-02 -4.9656e-03 1.2176e-03 4.1885e-03 -6.0000e+00 7.5334e-03 -2.5837e-03 5.2966e-04 1.1665e-03 -6.0000e+00 3.1982e-03 2.6904e-03 3.0909e-04 4.2780e-05 1.7591e-05 -6.0000e+00 2.3651e-04 -3.6679e-03 -6.9315e-05 12 9 1 12 1 1 99.88 25.39 0.35 -0.00367 -0.00135 15 5 1 5 0 1010.471 33.50 20.00 25.39 27.80 34.3 1002.16 -854 -409 -1147 -2820 -1181 7 531 1225 846 -773 -1263 186 -550 594 626 -635 164 1029 908 1291 331 532 871 514 807 398 -745 82 240 622 915 1551 910 -2149 -1525 -1157 -1319 -2 -395 -1127 -1332 -639 -982 -801 -58 -668 -658 -318 -707 515 1270 624 1258 534 578 914 586 549 784 408 1473 1218 398 822 -594 -274 -395 -36 1492 146 340 306 217 221 103 -1 -589 -554 -82 -1087 -1461 -1384 -2106 -1092 -972 -203 245 304 192 214 643 -29 -84 619 407 168 500 493 -16 -193 -785 -1019 -125 207 -898 -922 -615 -628 404 358 579 221 137 92 -50 131 258 225 385 -7 49 -32 289 547 823 169 509 760 501 231 -157 -390 -136 131 5 -174 122 125 -241 -83 -297 -922 -325 -159 -433 -1055 -401 2 191 484 332 -311 -508 77 -255 284 326 -329 86 551 499 721 187 300 503 294 477 236 -428 46 128 329 506 901 548 -1295 -878 -687 -837 -1 -291 -887 -1112 -545 -850 -691 -49 -559 -533 -259 -569 416 1021 532 1113 469 517 826 532 493 697 370 1390 1182 395 819 -591 -260 -353 -32 1399 146 347 318 230 222 99 -1 -515 -480 -73 -1039 -1479 -1447 -2336 -1224 -1123 -247 299 375 231 252 714 -31 -86 637 432 189 593 602 -20 -238 -938 -1153 -141 248 -1119 -1165 -781 -831 537 497 791 304 183 117 -61 155 312 279 494 -9 66 -43 371 688 1016 206 606 931 628 294 -206 -503 -180 181 7 -247 178 184 -353 -118 -423 -1291 SS 20250416T211102.1Z 9237.882663 438 1 4.79 2 29.70 222.27 160.24 285.26 0.00 1 0.00 1 0 17 8.489e-03 7.024e-03 3.713e-03 2.674e-03 1.856308e-01 1.436062e-03 2.175350e-03 -6.000000e+00 5.099637e-03 229.32 -2.00 3.36 -2.00 314.73 0.00e+00 2.378056e-04 1.179722e-04 2.062263e-05 -6.000000e+00 2.263768e-04 284.51 -2.00 20.00 -2.00 314.13 0.00e+00 1.151 0.000 302.00 328.00 3 3.8706e+00 3.6760e-03 1.4690e-02 -6.0000e+00 1.2699e-02 9.4705e-03 4.0648e-03 9.1612e-03 -6.0000e+00 1.3726e-02 -6.2638e-03 2.3279e-03 4.4903e-03 -6.0000e+00 8.1749e-03 -3.0610e-04 1.0174e-03 1.2609e-03 -6.0000e+00 3.4703e-03 2.9093e-03 -2.9810e-05 8.1957e-05 1.8908e-05 -6.0000e+00 2.5665e-04 -3.4948e-03 -7.4711e-05 12 9 1 12 1 1 97.88 25.61 0.25 -0.00349 -0.00372 4 6 1 5 0 958.107 33.50 20.00 25.61 28.19 34.4 997.84 -1103 -20 -1435 -2880 -713 106 728 36 -482 -2286 -717 -888 -107 266 1077 -598 701 997 353 1207 1016 395 478 -44 1868 448 247 947 523 835 1391 1732 726 -2277 -1405 -982 -1453 -178 -737 -1206 -736 -1134 -1106 -147 241 -964 -468 -533 -583 552 871 402 1202 329 88 1108 914 283 568 668 879 1241 1641 171 -367 -618 -225 321 1154 451 279 -344 217 446 559 209 -1074 -891 -403 -1142 -1577 -1724 -1955 -1075 -966 -223 -31 277 378 467 1006 206 -423 675 349 414 775 758 -256 -471 -678 -1077 -165 245 -902 -963 -405 -604 248 435 384 409 127 -122 -72 96 569 410 317 -332 -271 52 227 442 741 -352 733 1269 764 550 -399 -196 153 40 -19 -323 281 88 -192 -126 -423 -1078 -400 -7 -520 -1034 -231 34 251 14 -184 -897 -276 -361 -48 124 512 -303 360 524 192 663 561 220 258 -25 1079 263 139 525 276 439 764 949 414 -1303 -812 -552 -877 -119 -548 -956 -589 -938 -926 -122 197 -785 -383 -422 -455 433 717 336 1040 284 78 982 813 250 497 593 819 1185 1587 170 -361 -582 -199 288 1079 449 295 -359 230 446 531 187 -937 -770 -373 -1091 -1602 -1817 -2176 -1213 -1124 -265 -38 345 460 553 1123 218 -439 700 374 471 930 940 -324 -573 -795 -1238 -189 286 -1101 -1236 -522 -787 336 599 538 559 169 -159 -90 117 701 519 417 -445 -365 68 298 569 934 -426 888 1524 943 715 -521 -260 207 55 -27 -473 408 130 -280 -184 -601 -1504 SS 20250416T215918.3Z 9237.916184 454 1 55.17 2 37.45 238.67 168.91 306.74 0.00 1 0.00 1 0 25 8.618e-03 6.740e-03 2.194e-03 1.330e-03 2.044155e-01 7.097446e-04 2.355585e-03 -6.000000e+00 5.177784e-03 229.32 -2.00 3.36 -2.00 315.50 0.00e+00 2.831426e-04 6.776133e-05 3.749283e-05 -6.000000e+00 2.297983e-04 284.51 -2.00 20.00 -2.00 314.83 0.00e+00 1.259 0.000 302.00 328.00 3 4.8923e+00 1.8323e-03 1.6075e-02 -6.0000e+00 1.2893e-02 2.6887e-03 2.0331e-03 1.0025e-02 -6.0000e+00 1.3935e-02 -3.7075e-03 1.1651e-03 4.9093e-03 -6.0000e+00 8.2998e-03 -2.4503e-03 5.2021e-04 1.3752e-03 -6.0000e+00 3.5240e-03 9.1024e-04 3.6523e-04 4.0984e-05 1.8944e-05 -6.0000e+00 2.6053e-04 -4.2391e-03 -5.4868e-05 11 8 0 10 0 0 99.95 25.53 0.17 -0.00424 -0.00149 38 4 1 5 0 1451.610 33.50 20.01 25.53 26.11 34.7 1001.06 -541 -1153 -1179 -3492 -393 785 -450 1005 886 -1576 -1523 -704 675 424 1064 -1026 320 1025 725 1722 -217 789 750 569 1462 220 -213 -178 337 1193 845 912 1215 -1420 -1828 -747 -1660 -249 -24 -1087 -1357 -599 -2325 -683 125 -520 -535 -362 -1092 589 1000 247 1031 873 863 1070 1048 164 730 701 844 1364 1743 939 -640 -681 -646 -139 1182 138 176 27 450 489 123 -185 -828 -582 -70 -1255 -1145 -1675 -1870 -918 -658 -275 22 219 477 375 532 -6 -258 452 702 157 512 747 84 -289 -954 -1011 -151 45 -977 -1063 -601 -514 99 708 580 218 285 59 -77 -281 221 302 412 -235 -48 299 467 482 693 14 206 949 393 169 -275 -589 -363 359 -4 84 96 521 -275 -92 -330 -936 -150 -333 -330 -913 -92 182 -115 280 263 -485 -469 -228 220 156 426 -442 129 424 309 744 -96 347 340 271 716 109 -102 -80 156 550 381 437 601 -702 -875 -367 -930 -151 -16 -804 -1001 -453 -1812 -523 94 -389 -414 -272 -814 442 738 194 842 738 745 937 920 143 630 615 733 1264 1706 887 -617 -605 -578 -119 1094 134 182 29 461 475 116 -167 -699 -488 -63 -1203 -1141 -1808 -2022 -1043 -758 -335 28 266 594 440 602 -7 -266 467 780 183 621 920 106 -366 -1129 -1188 -176 53 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