File name: Pandora247s1_WhittierCA_20250516_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20250517T080100.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20250516_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20250516 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250516T171111.7Z 9267.716108 300 1 54.61 2 37.82 102.65 107.60 247.28 0.00 1 0.00 1 0 17 7.993e-03 6.530e-03 1.807e-04 1.318e-04 1.856531e-01 7.120784e-05 2.146004e-03 -6.000000e+00 4.835468e-03 231.26 -2.00 3.36 -2.00 314.71 0.00e+00 3.182820e-04 5.854253e-06 1.816901e-05 -6.000000e+00 2.155908e-04 287.22 -2.00 20.00 -2.00 314.07 0.00e+00 1.265 0.000 302.00 328.00 3 4.4641e-01 1.8293e-04 1.5593e-02 -6.0000e+00 1.2087e-02 -2.2504e-02 2.0193e-04 9.2066e-03 -6.0000e+00 1.3040e-02 -3.7308e-03 1.1561e-04 4.4678e-03 -6.0000e+00 7.7666e-03 -2.5898e-03 5.0199e-05 1.2409e-03 -6.0000e+00 3.2917e-03 8.1153e-02 3.0129e-04 4.0349e-06 1.8230e-05 -6.0000e+00 2.4180e-04 -1.9152e-03 -6.2740e-05 11 8 0 10 0 0 99.92 25.26 0.28 -0.00192 0.00035 2114 209 1 5 0 25.825 33.50 20.00 25.26 27.93 34.2 1001.16 -542 -720 -1350 -2537 -830 -504 834 1256 431 -1401 -1326 -58 -205 325 461 -497 289 773 794 1224 416 911 1005 663 816 439 -502 35 582 1191 1242 1463 883 -2313 -1947 -1435 -1447 -236 -352 -1085 -1140 -679 -866 -749 -74 -556 -590 -432 -464 499 929 611 1075 624 573 1048 589 292 470 621 1173 1318 1255 833 -530 -197 -485 2 1413 297 185 219 155 474 -84 -207 -611 -607 -210 -1163 -1409 -1741 -2169 -1134 -808 -429 93 142 390 326 586 -29 95 655 534 334 575 532 -163 -304 -695 -820 -22 248 -1053 -785 -594 -593 271 417 401 188 174 45 66 381 349 373 378 -65 -73 135 324 247 828 2 430 939 358 240 -181 -388 -155 183 -2 -200 161 93 -200 -103 -317 -841 -208 -286 -520 -902 -284 -172 305 477 175 -554 -524 -24 -89 150 232 -253 150 410 414 649 223 487 554 383 469 254 -293 19 312 636 668 832 521 -1370 -1108 -843 -886 -162 -261 -841 -907 -554 -718 -619 -60 -448 -476 -337 -356 387 756 509 904 544 510 914 518 254 418 545 1079 1260 1233 807 -507 -183 -427 2 1329 293 189 228 158 469 -81 -186 -542 -536 -193 -1131 -1429 -1855 -2384 -1275 -946 -506 113 171 471 381 656 -31 99 686 570 382 686 662 -201 -369 -827 -948 -26 290 -1299 -990 -764 -777 363 570 559 256 232 58 81 462 424 470 499 -88 -99 181 427 317 1029 2 512 1150 456 314 -239 -523 -210 253 -2 -291 235 137 -294 -150 -459 -1194 SS 20250516T171726.3Z 9267.720443 304 1 9.91 2 36.56 103.91 108.74 247.98 0.00 1 0.00 1 0 17 8.098e-03 6.577e-03 8.438e-04 6.240e-04 1.829603e-01 3.374690e-04 2.116581e-03 -6.000000e+00 4.899208e-03 231.26 -2.00 3.36 -2.00 314.62 0.00e+00 3.436063e-04 2.727391e-05 1.698752e-05 -6.000000e+00 2.184382e-04 287.22 -2.00 20.00 -2.00 313.99 0.00e+00 1.244 0.000 302.00 328.00 3 1.8524e+00 8.6624e-04 1.5350e-02 -6.0000e+00 1.2246e-02 -9.4549e-03 9.5550e-04 9.0785e-03 -6.0000e+00 1.3212e-02 -4.0335e-03 5.4762e-04 4.4053e-03 -6.0000e+00 7.8690e-03 -2.5659e-03 2.3755e-04 1.2271e-03 -6.0000e+00 3.3351e-03 2.0299e-02 2.4646e-04 1.9105e-05 1.8234e-05 -6.0000e+00 2.4499e-04 -2.0621e-03 -7.0856e-05 12 9 1 12 1 1 98.71 25.28 0.31 -0.00206 -0.00021 78 43 1 5 0 125.243 33.50 20.00 25.28 28.63 34.5 1002.05 -406 -718 -1372 -2601 -374 -552 904 1311 525 -1345 -1221 71 -316 344 385 -717 115 715 837 1267 534 1063 979 590 932 413 -610 -125 574 1110 1330 1497 928 -2272 -2058 -1657 -1780 -384 -365 -1106 -964 -645 -876 -865 27 -589 -470 -384 -394 575 962 544 1065 676 594 1034 485 254 458 665 1110 1239 1185 853 -542 -358 -607 -29 1458 364 324 222 154 493 -64 -233 -587 -644 -209 -1091 -1317 -1810 -2131 -1093 -772 -391 26 102 421 319 518 -73 183 652 541 307 518 514 -228 -293 -670 -849 32 169 -1040 -759 -628 -696 310 425 488 150 244 144 -23 370 396 340 349 -171 -17 149 227 260 821 12 483 950 363 340 -233 -448 -266 185 16 -197 187 98 -204 -114 -371 -744 -161 -278 -544 -952 -131 -193 339 511 219 -545 -494 30 -141 162 198 -372 61 386 463 683 291 577 547 346 542 241 -360 -69 311 600 754 859 552 -1356 -1181 -982 -1099 -265 -272 -861 -794 -528 -728 -718 22 -492 -379 -310 -312 461 782 453 922 588 527 927 438 228 406 599 1017 1179 1158 845 -531 -330 -547 -26 1397 367 336 228 160 496 -61 -213 -514 -562 -190 -1045 -1353 -1900 -2304 -1209 -889 -466 31 124 512 374 585 -78 192 670 581 344 620 627 -283 -357 -780 -961 36 198 -1284 -958 -807 -912 413 580 676 208 324 184 -28 447 480 427 460 -231 -23 199 298 333 1016 15 586 1157 459 441 -305 -598 -357 253 22 -284 275 143 -302 -165 -530 -1042 SS 20250516T172103.6Z 9267.722958 307 1 5.41 2 35.84 104.67 109.41 248.38 0.00 1 0.00 1 0 17 7.992e-03 6.535e-03 1.099e-03 8.167e-04 1.812874e-01 4.423407e-04 2.097346e-03 -6.000000e+00 4.834937e-03 231.26 -2.00 3.36 -2.00 314.59 0.00e+00 2.754464e-04 3.553771e-05 1.684144e-05 -6.000000e+00 2.155651e-04 287.22 -2.00 20.00 -2.00 313.97 0.00e+00 1.233 0.000 302.00 328.00 3 1.7920e+00 1.1356e-03 1.5206e-02 -6.0000e+00 1.2085e-02 -1.1197e-02 1.2528e-03 8.9855e-03 -6.0000e+00 1.3038e-02 -3.8234e-03 7.1754e-04 4.3627e-03 -6.0000e+00 7.7657e-03 -2.7244e-03 3.1068e-04 1.2100e-03 -6.0000e+00 3.2913e-03 2.1899e-02 2.7913e-04 2.5021e-05 1.7992e-05 -6.0000e+00 2.4177e-04 -1.8462e-03 -5.8554e-05 12 9 1 12 1 1 99.94 25.30 0.30 -0.00185 0.00025 45 46 1 5 0 117.398 33.50 20.00 25.30 29.31 34.3 1002.19 -372 -863 -1393 -2739 -528 -77 791 694 271 -1436 -1209 164 13 244 303 -631 461 1008 502 1331 472 745 1103 563 899 575 -744 187 812 1330 1376 1319 836 -2319 -2081 -1448 -1419 -295 -129 -1119 -1158 -638 -779 -747 -43 -477 -629 -475 -481 533 873 427 1083 643 465 1093 505 191 515 470 1104 1321 1135 839 -475 -161 -429 -34 1502 223 46 226 99 615 -77 -176 -701 -622 -151 -1173 -1316 -1662 -2111 -1088 -876 -507 58 184 421 339 594 37 111 695 478 422 576 677 -169 -299 -819 -871 -52 214 -1004 -783 -505 -650 214 567 298 220 235 85 45 359 270 328 389 -28 -91 144 259 237 872 -64 395 873 345 307 -227 -407 -206 233 -1 -193 191 1 -190 -83 -264 -801 -143 -344 -538 -1031 -190 -28 287 279 110 -598 -502 71 6 118 152 -335 248 531 273 733 263 415 630 324 534 343 -431 105 449 732 761 773 486 -1353 -1217 -837 -890 -200 -94 -888 -942 -532 -658 -631 -36 -392 -517 -378 -376 421 722 362 924 568 407 965 449 168 450 418 1028 1240 1128 821 -459 -151 -380 -30 1418 222 48 235 101 610 -75 -158 -624 -550 -139 -1140 -1333 -1766 -2315 -1220 -1024 -612 71 227 507 394 662 40 115 723 520 479 681 835 -208 -360 -968 -999 -60 254 -1226 -979 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