File name: Pandora247s1_WhittierCA_20250619_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20250620T080840.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20250619_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20250619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250619T160432.9Z 9301.669825 288 1 5.63 2 50.68 86.11 36.18 221.47 0.00 1 0.00 1 0 17 8.390e-03 6.688e-03 1.901e-03 1.256e-03 2.087698e-01 6.778569e-04 2.397986e-03 -6.000000e+00 5.092934e-03 232.26 -2.00 3.36 -2.00 315.22 0.00e+00 3.882778e-04 6.197926e-05 2.855599e-05 -6.000000e+00 2.292630e-04 290.26 -2.00 20.00 -2.00 314.48 0.00e+00 1.575 0.000 302.00 328.00 3 2.2702e+00 1.7534e-03 1.8760e-02 -6.0000e+00 1.2748e-02 -1.5901e-02 1.9393e-03 1.0418e-02 -6.0000e+00 1.3737e-02 -1.3132e-03 1.1078e-03 5.0249e-03 -6.0000e+00 8.1902e-03 -3.1261e-03 4.8806e-04 1.3907e-03 -6.0000e+00 3.4735e-03 9.2924e-03 3.1237e-04 3.8568e-05 1.9628e-05 -6.0000e+00 2.5393e-04 1.0968e-04 -7.6233e-05 12 9 1 12 1 1 99.32 25.87 0.31 0.00011 0.00246 24 24 1 5 0 224.974 33.50 20.00 25.87 29.41 34.4 997.56 -79 -183 -1481 -2509 -1138 -1183 380 838 -283 -1052 -1412 92 427 -167 260 -380 -91 226 1108 1399 297 706 1204 838 850 306 -150 115 638 1429 1390 1812 920 -2525 -1991 -1652 -2023 -323 -233 -1020 -973 -730 -786 -779 30 -600 -747 -435 -566 651 766 834 850 361 638 1060 892 83 356 597 1095 1334 1383 844 -365 22 -589 54 1816 335 303 196 75 486 -59 -339 -677 -769 -30 -1354 -1500 -1706 -2291 -1080 -770 -436 -21 238 488 583 545 -149 -175 523 489 588 541 566 -33 -250 -811 -844 -89 151 -1120 -727 -541 -588 326 620 458 117 218 -227 46 425 262 260 345 -40 -82 96 298 218 778 -73 487 972 198 377 -187 -495 -229 91 173 -204 70 231 -146 -131 -340 -747 -25 -60 -474 -743 -330 -345 111 271 -98 -349 -473 32 167 -70 112 -174 -43 104 520 671 145 344 603 421 443 161 -76 57 304 682 703 924 490 -1355 -1028 -886 -1177 -209 -160 -756 -737 -569 -622 -617 24 -465 -563 -330 -425 497 593 658 702 299 539 907 766 71 302 515 958 1251 1329 799 -343 20 -520 49 1709 330 306 201 75 477 -55 -307 -591 -673 -28 -1301 -1541 -1777 -2536 -1217 -900 -524 -26 292 583 692 611 -158 -181 545 533 665 656 714 -41 -308 -957 -969 -102 179 -1396 -924 -699 -794 449 871 657 164 295 -298 58 532 328 338 467 -55 -115 131 400 286 993 -92 598 1233 255 497 -255 -674 -321 130 255 -305 107 349 -225 -195 -503 -1085 SS 20250619T161841.7Z 9301.679649 298 1 54.60 2 47.76 87.96 38.12 226.21 0.00 1 0.00 1 0 17 8.240e-03 6.578e-03 2.001e-04 1.390e-04 1.972564e-01 7.515360e-05 2.268927e-03 -6.000000e+00 5.001940e-03 232.26 -2.00 3.36 -2.00 314.99 0.00e+00 3.029063e-04 6.556857e-06 2.618233e-05 -6.000000e+00 2.251715e-04 290.26 -2.00 20.00 -2.00 314.28 0.00e+00 1.485 0.000 302.00 328.00 3 3.1331e-01 1.9385e-04 1.7695e-02 -6.0000e+00 1.2520e-02 -3.0624e-02 2.1405e-04 9.8308e-03 -6.0000e+00 1.3491e-02 -1.0196e-03 1.2246e-04 4.7454e-03 -6.0000e+00 8.0439e-03 -3.3243e-03 5.3537e-05 1.3058e-03 -6.0000e+00 3.4114e-03 7.3791e-02 2.5339e-04 4.2685e-06 1.8817e-05 -6.0000e+00 2.4939e-04 2.1736e-04 -7.5650e-05 11 8 0 10 0 0 86.02 25.88 0.30 0.00022 0.00212 2033 201 1 5 0 26.852 33.50 19.99 25.88 30.99 34.4 996.94 -490 -723 -1423 -2776 -961 -573 765 1223 215 -1483 -1387 2 -201 358 490 -477 308 761 768 1273 487 961 1061 716 898 536 -433 35 500 1219 1236 1495 909 -2360 -2079 -1597 -1600 -280 -316 -1089 -1060 -637 -833 -727 0 -565 -574 -434 -500 433 890 537 1049 626 549 1050 578 222 428 599 1148 1356 1398 910 -501 -203 -571 11 1447 306 227 254 217 493 -117 -291 -716 -725 -289 -1178 -1437 -1779 -2164 -1130 -771 -367 139 189 449 350 595 -64 35 605 539 307 598 560 -149 -330 -770 -928 -111 193 -1072 -813 -617 -607 293 489 448 207 186 53 1 335 272 340 388 -67 -54 138 323 275 822 -54 404 938 384 275 -203 -388 -186 158 5 -186 197 115 -185 -93 -327 -846 -168 -257 -491 -943 -297 -177 254 422 80 -565 -530 1 -80 160 227 -223 148 374 389 656 254 501 545 387 481 289 -236 18 254 618 662 811 513 -1338 -1136 -904 -942 -185 -225 -808 -834 -498 -662 -577 0 -453 -447 -327 -386 327 707 438 862 534 478 897 497 190 375 517 1039 1275 1350 867 -473 -187 -500 10 1357 302 231 263 220 485 -113 -260 -617 -624 -260 -1122 -1470 -1860 -2335 -1249 -887 -436 167 230 546 411 672 -68 36 628 587 350 711 696 -189 -399 -914 -1072 -128 230 -1320 -1025 -793 -814 402 685 626 290 250 69 1 410 344 434 520 -92 -75 186 430 357 1033 -66 500 1168 498 367 -274 -522 -257 224 8 -278 294 174 -278 -139 -483 -1229 SS 20250619T162400.9Z 9301.683344 301 1 54.60 2 46.65 88.67 38.89 227.89 0.00 1 0.00 1 0 17 8.181e-03 6.562e-03 1.921e-04 1.345e-04 1.930564e-01 7.283632e-05 2.225849e-03 -6.000000e+00 4.966220e-03 232.26 -2.00 3.36 -2.00 314.95 0.00e+00 3.246469e-04 6.307291e-06 2.417016e-05 -6.000000e+00 2.235711e-04 290.26 -2.00 20.00 -2.00 314.24 0.00e+00 1.454 0.000 302.00 328.00 3 2.8518e-01 1.8782e-04 1.7337e-02 -6.0000e+00 1.2431e-02 -3.1190e-02 2.0737e-04 9.6409e-03 -6.0000e+00 1.3395e-02 -4.2655e-04 1.1865e-04 4.6535e-03 -6.0000e+00 7.9865e-03 -3.5929e-03 5.1811e-05 1.2820e-03 -6.0000e+00 3.3870e-03 7.8773e-02 2.3283e-04 4.1331e-06 1.8557e-05 -6.0000e+00 2.4762e-04 2.2538e-04 -8.0335e-05 11 8 0 10 0 0 90.20 25.90 0.30 0.00023 0.00197 2115 209 1 5 0 25.810 33.50 20.00 25.90 31.31 34.3 996.73 -445 -692 -1378 -2604 -820 -627 806 1285 262 -1533 -1232 48 -304 303 442 -515 340 722 838 1241 461 906 971 739 869 519 -494 -27 519 1212 1249 1474 843 -2400 -2119 -1632 -1616 -291 -372 -1080 -1088 -646 -836 -724 34 -556 -580 -432 -497 447 900 611 1089 601 576 1090 585 262 391 585 1183 1347 1378 934 -513 -212 -565 0 1449 337 230 235 211 470 -101 -276 -721 -718 -277 -1168 -1418 -1757 -2156 -1096 -761 -371 176 204 450 379 568 -97 25 590 517 295 608 567 -152 -326 -748 -943 -105 213 -1063 -800 -600 -583 298 459 431 210 195 48 -1 327 285 336 362 -65 -79 140 304 276 830 -38 403 931 388 294 -189 -427 -174 180 6 -189 176 109 -184 -89 -317 -835 -160 -242 -497 -868 -264 -202 263 462 95 -574 -461 19 -126 133 212 -250 168 366 417 630 237 465 514 394 480 288 -266 -14 271 631 655 820 466 -1333 -1185 -904 -973 -189 -261 -818 -845 -515 -677 -586 27 -439 -460 -332 -377 343 702 506 908 520 494 944 511 227 337 512 1053 1247 1311 903 -491 -191 -500 0 1373 335 236 239 216 468 -95 -250 -627 -624 -251 -1122 -1422 -1851 -2344 -1220 -882 -445 213 250 538 448 629 -103 26 615 565 338 726 707 -188 -396 -892 -1093 -121 256 -1315 -1013 -774 -768 400 632 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