File name: Pandora247s1_WhittierCA_20250711_L2Fit_fout2c6d20230505p1-8.txt File generation date: 20250712T081115.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Peter Peterson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 247 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora247_OF_v2d20221027.txt Instrument calibration file used: Pandora247s1_CF_v6d20230505.txt Level 1 file used: Pandora247s1_WhittierCA_20250711_L1_smca1c6d20230505p1-8.txt Full location name: Whittier College SLC Short location name: WhittierCA Country of location: United States Location latitude [deg]: 33.9768 Location longitude [deg]: -118.0299 Location altitude [m]: 130 Local noon date: 20250711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "based on session 2 trying to improve labcal" First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1400 305.2810 305.4219 305.5629 305.7038 305.8447 305.9856 306.1265 306.2673 306.4082 306.5491 306.6899 306.8307 306.9715 307.1124 307.2531 307.3939 307.5347 307.6755 307.8162 307.9569 308.0977 308.2384 308.3791 308.5198 308.6605 308.8011 308.9418 309.0824 309.2231 309.3637 309.5043 309.6449 309.7855 309.9260 310.0666 310.2072 310.3477 310.4882 310.6287 310.7692 310.9097 311.0502 311.1907 311.3311 311.4716 311.6120 311.7524 311.8929 312.0333 312.1736 312.3140 312.4544 312.5947 312.7351 312.8754 313.0157 313.1560 313.2963 313.4366 313.5769 313.7171 313.8574 313.9976 314.1379 314.2781 314.4183 314.5585 314.6986 314.8388 314.9790 315.1191 315.2592 315.3993 315.5395 315.6796 315.8196 315.9597 316.0998 316.2398 316.3799 316.5199 316.6599 316.7999 316.9399 317.0799 317.2198 317.3598 317.4997 317.6397 317.7796 317.9195 318.0594 318.1993 318.3391 318.4790 318.6188 318.7587 318.8985 319.0383 319.1781 319.3179 319.4577 319.5974 319.7372 319.8769 320.0167 320.1564 320.2961 320.4358 320.5755 320.7151 320.8548 320.9944 321.1341 321.2737 321.4133 321.5529 321.6925 321.8321 321.9716 322.1112 322.2507 322.3902 322.5298 322.6693 322.8087 322.9482 323.0877 323.2271 323.3666 323.5060 323.6454 323.7848 323.9242 324.0636 324.2030 324.3424 324.4817 324.6210 324.7604 324.8997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250711T151734.3Z 9323.637203 248 1 55.42 2 61.85 81.27 111.45 253.98 0.00 1 0.00 1 0 17 1.671e-02 7.645e-03 7.569e-03 2.357e-03 2.733658e-01 1.251032e-03 3.076490e-03 -6.000000e+00 1.012980e-02 231.90 -2.00 3.36 -2.00 317.30 0.00e+00 4.566663e-04 1.869437e-04 9.519445e-05 -6.000000e+00 4.597497e-04 291.97 -2.00 20.00 -2.00 316.41 0.00e+00 2.109 0.000 302.00 328.00 3 4.8945e+00 3.3269e-03 2.4940e-02 -6.0000e+00 2.5318e-02 -1.2774e-03 3.7312e-03 1.3669e-02 -6.0000e+00 2.7279e-02 6.9460e-03 2.2164e-03 6.5899e-03 -6.0000e+00 1.6287e-02 -7.3523e-03 1.0841e-03 1.8329e-03 -6.0000e+00 6.9261e-03 3.5698e-04 6.7782e-04 7.3335e-05 2.1637e-05 -6.0000e+00 5.0556e-04 4.6052e-04 -1.6740e-05 11 9 0 11 8 0 99.94 26.06 0.40 0.00046 0.00555 31 3 1 5 0 1787.688 33.75 20.00 26.06 29.05 34.3 999.81 -1972 -2396 3315 -9391 3107 5568 696 2525 -1518 -2814 -4299 -3340 -507 -487 2790 -813 -2816 887 1190 3003 1181 1319 418 2086 3702 -2450 -614 1234 1714 -22 176 -4422 457 -2648 -1787 448 -1319 130 1004 -1241 -1422 -447 -5053 -293 708 -368 -491 369 -1548 533 1094 200 1510 469 1377 1205 1544 661 1026 892 1365 1617 -211 1721 -169 -1021 -889 767 1591 373 420 357 767 94 -868 -484 -709 -356 -216 -958 -565 -1564 -2328 -1613 -539 -511 325 389 947 152 666 -252 -12 847 474 -21 315 634 215 -698 -695 -991 3 -4 -1038 -1234 -579 -609 419 570 449 210 424 228 -322 -689 82 249 730 -185 -128 454 130 476 875 2 91 659 731 303 -522 -610 -228 230 -164 285 -21 279 64 250 -530 -898 -215 -275 351 -1042 285 505 73 290 -195 -374 -593 -496 -84 -92 569 -184 -682 216 300 764 309 348 106 548 1001 -711 -169 347 465 -6 49 -1394 143 -841 -547 140 -480 55 499 -646 -792 -255 -3081 -171 409 -213 -279 204 -873 306 666 131 1029 336 1005 830 1064 455 755 618 997 1275 -181 1480 -142 -804 -672 590 1344 327 390 337 704 89 -751 -377 -520 -263 -175 -880 -533 -1612 -2560 -1747 -619 -622 408 493 1166 178 711 -267 -13 869 531 -24 405 818 282 -885 -870 -1172 4 -5 -1310 -1640 -800 -885 603 866 701 323 613 325 -432 -906 110 354 1037 -274 -191 656 193 671 1170 2 124 870 1033 457 -773 -925 -357 377 -268 483 -37 489 112 419 -861 -1512 SS 20250711T152245.3Z 9323.640803 251 1 10.69 2 60.79 81.90 112.44 254.58 0.00 1 0.00 1 0 17 9.241e-03 6.395e-03 1.062e-03 5.534e-04 2.671054e-01 2.961644e-04 3.044840e-03 -6.000000e+00 5.602143e-03 231.90 -2.00 3.36 -2.00 316.12 0.00e+00 3.715217e-04 3.292722e-05 6.794237e-05 -6.000000e+00 2.543755e-04 291.97 -2.00 20.00 -2.00 315.28 0.00e+00 2.039 0.000 302.00 328.00 3 7.7404e-01 7.7277e-04 2.4180e-02 -6.0000e+00 1.4001e-02 -2.5087e-02 8.5937e-04 1.3301e-02 -6.0000e+00 1.5087e-02 -3.5664e-03 4.9307e-04 6.4170e-03 -6.0000e+00 9.0079e-03 -2.2226e-03 2.2563e-04 1.7617e-03 -6.0000e+00 3.8296e-03 2.4120e-02 2.5428e-04 1.6984e-05 2.3577e-05 -6.0000e+00 2.7969e-04 1.2255e-03 -6.1397e-05 12 1 1 12 1 1 98.78 26.07 0.31 0.00123 0.00314 166 84 1 5 0 64.001 33.75 20.00 26.07 29.39 34.4 1000.06 -941 -1346 -1804 -3531 -2282 -1723 -631 278 -317 -2227 -2004 -408 -714 -158 292 -279 215 1163 931 1028 388 1010 1362 1083 949 928 -309 -34 410 1202 1416 1735 1018 -2260 -2167 -1533 -1616 -451 -221 -1110 -1065 -516 -963 -685 250 -354 -391 -498 -336 536 960 638 1011 580 710 1128 589 128 519 531 1243 1447 1458 952 -516 -213 -610 -77 1506 311 359 154 108 379 -97 -348 -766 -894 -507 -1305 -1330 -1749 -2161 -1094 -798 -369 188 287 552 298 519 -193 -28 605 437 278 559 500 -182 -357 -844 -966 -89 155 -976 -793 -609 -543 293 479 550 143 242 14 12 388 326 415 417 -87 12 112 319 250 857 -70 400 936 421 239 -251 -439 -242 110 -9 -175 169 122 -159 -34 -281 -859 -201 -303 -397 -729 -435 -331 -132 64 -73 -535 -490 -106 -199 -50 96 -99 79 416 346 392 150 393 550 438 401 396 -129 -14 165 491 587 775 453 -1020 -1002 -698 -798 -250 -136 -709 -725 -348 -664 -473 171 -240 -272 -340 -229 375 685 468 779 450 565 912 481 104 417 434 1030 1249 1299 871 -458 -182 -519 -65 1340 299 355 155 106 362 -88 -296 -636 -751 -449 -1226 -1344 -1808 -2307 -1229 -905 -431 228 350 658 344 581 -205 -29 644 477 320 690 631 -234 -451 -1021 -1132 -104 186 -1236 -1028 -805 -736 409 690 793 207 339 19 16 494 428 563 590 -126 18 158 444 341 1130 -91 511 1214 573 338 -361 -633 -361 168 -14 -281 270 198 -256 -55 -441 -1322 SS 20250711T152750.9Z 9323.644339 254 1 54.61 2 59.74 82.53 113.41 255.17 0.00 1 0.00 1 0 17 9.162e-03 6.408e-03 3.289e-04 1.786e-04 2.588844e-01 9.567258e-05 2.949390e-03 -6.000000e+00 5.555078e-03 231.90 -2.00 3.36 -2.00 316.00 0.00e+00 3.876764e-04 1.031689e-05 5.286799e-05 -6.000000e+00 2.521756e-04 291.97 -2.00 20.00 -2.00 315.16 0.00e+00 1.976 0.000 302.00 328.00 3 2.2647e-01 2.4913e-04 2.3421e-02 -6.0000e+00 1.3884e-02 -2.8199e-02 2.7676e-04 1.2871e-02 -6.0000e+00 1.4960e-02 -3.1277e-03 1.5876e-04 6.2079e-03 -6.0000e+00 8.9319e-03 -2.3995e-03 7.2267e-05 1.7123e-03 -6.0000e+00 3.7979e-03 4.4981e-02 4.4037e-04 5.4770e-06 2.2840e-05 -6.0000e+00 2.7728e-04 5.0780e-04 -4.4858e-05 11 8 0 10 0 0 44.77 26.07 0.29 0.00051 0.00382 1635 162 1 5 0 33.392 33.75 20.00 26.07 29.90 34.4 1000.47 -954 -1104 -1991 -3514 -2217 -1882 -367 299 -390 -2249 -2021 -715 -521 300 506 -489 397 895 808 1355 482 1073 1284 1090 1081 629 -297 71 477 1119 1330 1549 944 -2290 -2092 -1603 -1553 -191 -282 -943 -1045 -504 -747 -640 161 -376 -474 -362 -382 468 911 582 1128 674 617 1041 563 233 402 591 1213 1428 1422 973 -490 -193 -533 17 1427 323 239 232 142 402 -192 -337 -749 -842 -389 -1218 -1419 -1785 -2207 -1153 -825 -352 199 192 434 366 644 -50 51 593 543 275 528 514 -203 -361 -811 -949 -91 213 -1085 -795 -598 -543 364 504 449 205 184 37 30 342 339 369 375 -101 -73 168 357 285 788 -65 433 977 364 273 -185 -426 -167 154 -13 -201 182 106 -196 -118 -324 -803 -222 -250 -443 -787 -458 -392 -83 69 -97 -583 -532 -201 -155 95 177 -174 146 341 319 547 198 442 518 466 483 284 -131 29 201 454 579 688 440 -1080 -956 -762 -799 -110 -174 -625 -710 -353 -534 -459 115 -265 -327 -245 -258 324 644 440 861 537 487 835 455 187 319 478 997 1223 1300 882 -446 -168 -447 14 1295 306 233 230 138 379 -177 -293 -633 -720 -350 -1160 -1411 -1870 -2389 -1276 -949 -417 238 232 525 429 710 -53 54 618 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