File name: Pandora208s1_Windsor-West_20220620_L2Fit_fout2c1d20211014p1-8.txt File generation date: 20220929T221915.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.33 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v1d20211014.txt Level 1 file used: Pandora208s1_Windsor-West_20220620_L1_smca1c1d20211014p1-8.txt.bz2 Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220620 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.1175 305.2587 305.3999 305.5410 305.6822 305.8233 305.9644 306.1055 306.2466 306.3877 306.5288 306.6699 306.8109 306.9520 307.0930 307.2340 307.3750 307.5160 307.6570 307.7980 307.9390 308.0799 308.2209 308.3618 308.5027 308.6436 308.7845 308.9254 309.0663 309.2071 309.3480 309.4888 309.6297 309.7705 309.9113 310.0521 310.1929 310.3336 310.4744 310.6152 310.7559 310.8966 311.0374 311.1781 311.3188 311.4594 311.6001 311.7408 311.8814 312.0221 312.1627 312.3033 312.4439 312.5845 312.7251 312.8657 313.0062 313.1468 313.2873 313.4278 313.5683 313.7088 313.8493 313.9898 314.1303 314.2707 314.4112 314.5516 314.6920 314.8324 314.9728 315.1132 315.2536 315.3940 315.5343 315.6747 315.8150 315.9553 316.0956 316.2359 316.3762 316.5165 316.6567 316.7970 316.9372 317.0774 317.2177 317.3579 317.4980 317.6382 317.7784 317.9185 318.0587 318.1988 318.3389 318.4791 318.6192 318.7592 318.8993 319.0394 319.1794 319.3195 319.4595 319.5995 319.7395 319.8795 320.0195 320.1595 320.2994 320.4394 320.5793 320.7192 320.8592 320.9991 321.1389 321.2788 321.4187 321.5585 321.6984 321.8382 321.9780 322.1178 322.2576 322.3974 322.5372 322.6769 322.8167 322.9564 323.0962 323.2359 323.3756 323.5153 323.6549 323.7946 323.9343 324.0739 324.2135 324.3532 324.4928 324.6324 324.7719 324.9115 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220620T124338.4Z 8206.530306 252 1 47.03 2 61.91 82.89 54.53 207.88 0.00 1 0.00 1 0 25 1.895e-02 5.834e-03 1.507e-02 2.668e-03 2.939975e-01 1.389474e-03 3.516674e-03 -6.000000e+00 1.125296e-02 232.86 -2.00 3.53 -2.00 318.50 0.00e+00 8.704968e-04 2.748358e-04 3.663318e-04 -6.000000e+00 4.925549e-04 285.46 -2.00 20.00 -2.00 317.71 0.00e+00 2.113 0.000 302.00 328.00 3 3.7988e+00 3.7972e-03 2.6133e-02 -6.0000e+00 2.8275e-02 2.5391e-02 4.3043e-03 1.5731e-02 -6.0000e+00 3.0511e-02 7.2015e-03 2.8317e-03 7.6771e-03 -6.0000e+00 1.8125e-02 -9.4907e-03 1.4609e-03 2.1597e-03 -6.0000e+00 7.6770e-03 1.0212e-03 -3.3625e-04 8.1309e-05 2.4132e-05 -6.0000e+00 5.3686e-04 -5.5143e-03 -3.9307e-05 10 0 0 10 0 0 99.91 19.37 0.21 -0.00551 -0.00804 140 38 1 5 0 335.500 22.80 14.98 19.37 23.15 6.7 982.65 -3425 1301 -10305 6050 -6402 -201 -1913 -3291 2077 -6034 -609 -8303 -482 -5039 1469 487 2932 305 1702 13 -1170 2828 602 1963 -2588 1747 -862 -377 1389 -1019 1718 -1944 190 -3859 -1042 -3788 -1649 -1259 -605 -474 -2007 197 -1391 -524 -695 -34 -1335 258 -49 -356 979 -361 1959 509 1739 157 1397 576 370 662 797 1585 1362 990 600 727 -136 661 1101 566 485 236 708 -218 -111 -963 -564 -926 -834 -1326 -1275 -1862 -1748 -620 -429 326 250 949 483 471 -23 -605 194 -149 -5 -39 932 146 76 -639 -838 -554 -476 -547 -1288 -651 -730 -93 403 725 324 -10 184 -403 338 -70 779 272 437 -358 43 122 275 739 52 362 579 660 38 -24 60 -337 -126 -230 93 -55 265 -79 -28 -218 -178 -419 -198 77 -688 315 -344 -10 -107 -210 137 -446 -43 -679 -42 -532 166 60 371 42 239 2 -176 410 93 317 -459 304 -164 -67 232 -179 320 -409 42 -878 -218 -841 -405 -366 -208 -170 -784 78 -576 -216 -287 -15 -591 111 -21 -158 460 -184 1032 285 987 93 821 337 213 385 489 1048 977 678 432 484 -87 429 788 456 382 190 606 -178 -83 -650 -352 -582 -576 -1042 -1117 -1788 -1770 -658 -448 358 286 1098 551 505 -24 -600 180 -142 -6 -46 1092 187 99 -802 -1064 -651 -553 -681 -1729 -911 -982 -130 600 1143 530 -17 281 -572 482 -97 1109 413 650 -557 66 184 436 1108 74 493 774 926 58 -39 101 -581 -205 -396 169 -104 508 -154 -53 -405 -317 -727 SS 20220620T133359.2Z 8206.565269 286 1 47.64 2 52.62 91.06 59.51 221.19 0.00 1 0.00 1 0 17 2.186e-02 8.273e-03 1.922e-02 5.747e-03 2.358024e-01 2.996204e-03 2.785448e-03 -6.000000e+00 1.298316e-02 232.86 -2.00 3.53 -2.00 317.78 0.00e+00 3.568050e-04 4.669513e-04 1.613488e-04 -6.000000e+00 5.682360e-04 285.46 -2.00 20.00 -2.00 316.95 0.00e+00 1.643 0.000 302.00 328.00 3 5.6007e+00 8.0566e-03 2.0464e-02 -6.0000e+00 3.2622e-02 5.3286e-02 9.0526e-03 1.2405e-02 -6.0000e+00 3.5199e-02 6.9686e-03 5.4447e-03 5.9895e-03 -6.0000e+00 2.0911e-02 -8.2296e-03 2.6705e-03 1.6400e-03 -6.0000e+00 8.8590e-03 2.8769e-04 1.9835e-06 1.7582e-04 1.9037e-05 -6.0000e+00 6.1924e-04 -6.4045e-03 -1.0123e-05 11 8 0 10 0 0 99.75 19.30 0.24 -0.00640 -0.00639 27 7 1 5 0 1764.170 22.71 15.01 19.30 24.53 6.7 993.59 -9703 -168 3801 -6925 1468 -5072 4828 2998 -1929 -2971 -5092 -8419 884 -3042 1337 -231 537 1746 500 4929 -2431 4150 1027 7559 -2026 256 998 441 4572 841 2203 -2333 3110 -6079 -3746 -2238 -1865 -432 -1537 67 -1344 -255 -1097 555 -1503 -1604 130 -852 -514 319 2952 89 2677 1038 1472 580 -399 -112 67 1700 1445 2288 685 -459 -636 127 -1124 821 -520 379 1461 622 822 -241 478 -605 -2782 -1325 -1275 -1572 -1273 -1437 -1908 102 -581 581 844 1211 668 597 650 -77 -1026 -575 199 -299 941 176 -39 140 -1214 -489 -870 -795 -1220 -54 -632 -59 160 805 653 275 509 -849 -189 -1389 216 -176 554 155 660 762 661 478 -499 431 -434 56 -864 321 -40 -169 262 -84 29 406 970 -284 395 -453 -596 -734 -1075 -19 419 -773 136 -500 467 330 -243 -387 -671 -1211 131 -531 250 -47 112 373 112 1089 -580 926 245 1779 -548 69 259 107 1008 194 535 -636 853 -1791 -1016 -614 -574 -155 -662 32 -696 -135 -598 298 -820 -866 67 -431 -256 161 1541 51 1565 643 927 375 -262 -73 43 1076 963 1633 534 -372 -491 89 -755 547 -387 312 1269 556 718 -202 362 -453 -1961 -912 -956 -1328 -1090 -1334 -1873 104 -640 672 1014 1472 802 672 669 -80 -996 -563 209 -350 1104 224 -51 173 -1535 -573 -1016 -994 -1639 -69 -847 -82 236 1239 1034 426 741 -1256 -257 -1856 291 -253 849 249 1055 1190 997 685 -685 557 -553 75 -1230 477 -62 -266 421 -143 52 750 1823 -547 746 -832 -1060 -1269 SS 20220620T153643.4Z 8206.650503 360 1 28.09 2 30.74 118.54 77.05 247.17 0.00 1 0.00 1 0 17 1.094e-02 7.338e-03 7.039e-03 3.631e-03 1.705627e-01 1.898812e-03 2.046774e-03 -6.000000e+00 6.497941e-03 232.86 -2.00 3.53 -2.00 316.13 0.00e+00 3.829973e-04 2.038830e-04 1.027482e-04 -6.000000e+00 2.843788e-04 285.47 -2.00 20.00 -2.00 315.40 0.00e+00 1.163 0.000 302.00 328.00 3 5.5104e+00 4.9804e-03 1.4601e-02 -6.0000e+00 1.6327e-02 3.4971e-02 5.5335e-03 8.9417e-03 -6.0000e+00 1.7616e-02 -4.7814e-03 3.1776e-03 4.3237e-03 -6.0000e+00 1.0465e-02 -3.0315e-03 1.4586e-03 1.1824e-03 -6.0000e+00 4.4345e-03 5.7500e-04 6.5833e-05 1.0736e-04 1.4610e-05 -6.0000e+00 3.0982e-04 -6.5702e-03 4.8594e-05 12 9 1 12 1 1 99.93 19.38 0.38 -0.00657 -0.00608 12 6 1 5 0 2147.160 22.80 14.98 19.38 26.84 6.8 1012.71 1636 -1281 -415 -1656 -3302 -3266 444 -1084 -977 -3287 -2588 380 -255 833 -276 -993 343 -451 1754 1392 1771 1688 1469 597 974 360 -1069 -122 -1183 902 220 1812 -194 -1460 -3461 -3143 -1687 -719 -397 -956 241 -368 -336 -939 525 -520 -774 -948 122 361 8 1175 991 1199 837 1605 670 918 -190 774 1932 1541 2266 587 -265 -675 -265 -502 1018 -147 492 245 507 306 -652 -273 -788 -1092 -2124 -1760 -1497 -2196 -1042 -1346 -156 -236 333 220 786 366 34 -284 -811 -454 -556 233 601 685 368 -459 -381 -1406 25 -663 -836 -997 -376 -34 673 542 330 649 -50 -71 -116 -268 -180 393 821 274 267 207 589 410 329 509 603 67 201 420 -78 -594 -302 247 -32 458 137 490 -213 -610 -443 -1075 366 -309 -97 -355 -645 -626 88 -242 -236 -824 -628 93 -69 249 -92 -351 122 -165 646 527 669 633 567 243 409 154 -450 -47 -430 318 81 698 -80 -595 -1347 -1245 -737 -365 -238 -647 170 -270 -250 -702 384 -378 -545 -643 80 237 6 850 751 939 668 1290 546 736 -152 621 1606 1381 2145 577 -248 -575 -210 -399 875 -143 505 258 522 300 -591 -221 -583 -795 -1680 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