File name: Pandora208s1_Windsor-West_20220711_L2Fit_fout2c1d20211014p1-8.txt File generation date: 20220930T021113.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.33 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v1d20211014.txt Level 1 file used: Pandora208s1_Windsor-West_20220711_L1_smca1c1d20211014p1-8.txt.bz2 Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.1175 305.2587 305.3999 305.5410 305.6822 305.8233 305.9644 306.1055 306.2466 306.3877 306.5288 306.6699 306.8109 306.9520 307.0930 307.2340 307.3750 307.5160 307.6570 307.7980 307.9390 308.0799 308.2209 308.3618 308.5027 308.6436 308.7845 308.9254 309.0663 309.2071 309.3480 309.4888 309.6297 309.7705 309.9113 310.0521 310.1929 310.3336 310.4744 310.6152 310.7559 310.8966 311.0374 311.1781 311.3188 311.4594 311.6001 311.7408 311.8814 312.0221 312.1627 312.3033 312.4439 312.5845 312.7251 312.8657 313.0062 313.1468 313.2873 313.4278 313.5683 313.7088 313.8493 313.9898 314.1303 314.2707 314.4112 314.5516 314.6920 314.8324 314.9728 315.1132 315.2536 315.3940 315.5343 315.6747 315.8150 315.9553 316.0956 316.2359 316.3762 316.5165 316.6567 316.7970 316.9372 317.0774 317.2177 317.3579 317.4980 317.6382 317.7784 317.9185 318.0587 318.1988 318.3389 318.4791 318.6192 318.7592 318.8993 319.0394 319.1794 319.3195 319.4595 319.5995 319.7395 319.8795 320.0195 320.1595 320.2994 320.4394 320.5793 320.7192 320.8592 320.9991 321.1389 321.2788 321.4187 321.5585 321.6984 321.8382 321.9780 322.1178 322.2576 322.3974 322.5372 322.6769 322.8167 322.9564 323.0962 323.2359 323.3756 323.5153 323.6549 323.7946 323.9343 324.0739 324.2135 324.3532 324.4928 324.6324 324.7719 324.9115 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220711T112326.4Z 8227.474611 148 1 39.41 2 77.90 71.08 130.54 270.83 0.00 1 0.00 1 0 25 5.175e-01 2.936e-02 3.711e-01 2.397e-02 5.514269e-01 1.325237e-02 7.933594e-03 -6.000000e+00 3.089611e-01 232.91 -2.00 3.53 -2.00 321.03 0.00e+00 2.188330e-03 5.580753e-03 8.554021e-03 -6.000000e+00 1.402731e-02 287.41 -2.00 20.00 -2.00 320.38 0.00e+00 4.625 0.002 302.00 328.00 3 4.1185e+00 4.3846e-02 7.0758e-02 -6.0000e+00 7.7569e-01 2.6984e-01 5.4670e-02 6.7844e-02 -6.0000e+00 8.3783e-01 -3.8843e-01 4.2462e-02 2.0584e-02 -6.0000e+00 4.9850e-01 1.7658e-01 2.0769e-02 6.9749e-03 -6.0000e+00 2.1065e-01 4.8869e-05 -1.8025e-03 7.4145e-04 8.1737e-05 -6.0000e+00 1.4877e-02 -1.6020e-03 -4.9558e-05 12 9 9 12 1 1 99.98 19.25 0.37 -0.00160 -0.01515 17 6 1 5 0 2178.730 22.61 15.01 19.25 25.52 7.1 986.83 -75897 -142549 -138957 63217 191719 -139084 2909 -118256 -113975 -64313 83046 -144762 900000 133894 -32339 900000 170337 154532 -5923 212544 4017 -31399 -14665 5718 -24925 159333 900000 31068 98879 -15461 37685 38399 79432 103254 22099 -7429 -4325 8982 12443 53991 21493 27670 14784 40663 28381 38422 4544 -15764 9111 12181 10056 14842 25194 30424 4674 5325 -7781 13930 -10615 8352 15404 15275 7728 7060 17266 2735 6248 14334 6459 8377 9318 4291 -2746 -3266 5711 -10210 6723 4152 -1012 5346 -7968 -3497 -8996 -3390 -3831 -1863 -1525 -77 1605 374 -1895 -681 1800 402 -3764 865 -1942 -1217 -1866 -1017 -5759 -3535 -3867 -3510 -1094 913 -4824 -53 815 2691 -281 1537 918 1095 207 9 1797 133 508 2492 1205 1823 1368 1208 2031 87 168 8 -5 375 -420 -610 1433 -1063 939 -1592 576 -30 -376 735 -1361 -1028 -2026 -7548 -7142 1477 4479 -6266 68 -5131 -5135 -1824 1940 -10629 900000 3128 -1349 900000 3979 3610 -257 4965 161 -1781 -734 248 -1539 3722 900000 1117 2310 -877 1558 1794 2712 2783 1180 -545 -346 749 1204 3964 2367 3001 1875 4003 3173 3911 652 -2815 1307 1809 1678 2576 4246 5178 1069 1244 -2091 2952 -2799 1826 3316 3645 2218 2191 4811 844 1845 4090 2242 3215 3794 1869 -1242 -1384 2001 -3799 2175 1440 -392 2266 -4414 -2060 -5989 -2268 -2762 -1396 -1186 -60 1205 268 -1389 -462 1168 281 -3098 780 -1912 -1320 -2105 -1178 -6447 -3532 -3759 -3595 -1172 1009 -5999 -68 1130 4033 -463 2524 1473 1657 299 13 2586 207 829 4071 1957 2846 2075 1756 2810 119 228 12 -8 668 -804 -1225 2957 -2390 2193 -3935 1419 -75 -918 1686 -3018 -2176 SS 20220711T113914.1Z 8227.485580 154 1 46.89 2 75.12 73.52 133.32 273.44 0.00 1 0.00 1 0 17 1.743e-01 6.361e-03 1.607e-01 5.268e-03 4.923811e-01 2.862206e-03 5.718320e-03 -6.000000e+00 1.035123e-01 232.91 -2.00 3.53 -2.00 320.61 0.00e+00 6.916913e-04 1.113769e-03 9.594994e-04 -6.000000e+00 4.567067e-03 287.41 -2.00 20.00 -2.00 319.91 0.00e+00 3.815 0.001 302.00 328.00 3 2.3624e+00 9.0353e-03 4.6194e-02 -6.0000e+00 2.5995e-01 3.3267e-03 1.1399e-02 2.7313e-02 -6.0000e+00 2.8039e-01 9.1499e-03 9.9970e-03 1.3539e-02 -6.0000e+00 1.6676e-01 -1.3702e-02 4.9753e-03 3.8028e-03 -6.0000e+00 7.0761e-02 6.7271e-04 -2.2675e-04 1.6376e-04 4.8192e-05 -6.0000e+00 4.9372e-03 -4.7189e-03 8.5316e-07 11 1 0 11 8 0 99.98 19.32 0.41 -0.00472 -0.00642 478 129 1 5 0 98.070 22.71 14.99 19.32 26.08 7.1 991.73 -50886 -83519 43385 -20112 -26615 -76116 -48963 -43357 -65552 -79891 -67623 -28537 -8369 -8251 -11408 -10359 -10344 -8728 1101 -25243 -6099 -14940 -15567 -4559 -3525 -4810 -3288 -7645 -1217 -908 4740 -6190 -6392 -4603 -9759 -3865 -4902 -1391 -1977 -2378 1130 -6551 -2641 656 2905 1930 3387 1125 526 3420 240 -26 2676 3409 1570 1434 3596 4373 -218 2491 2030 3893 1778 221 599 1897 1090 484 2021 387 889 172 -575 198 -1509 -1098 -1882 -1483 -362 -517 -722 -888 -1967 -1689 -652 259 412 476 799 172 943 -642 615 -206 -265 -467 765 583 -394 -756 -674 -505 -715 -517 -1188 -1332 -324 -805 488 270 757 238 127 -90 267 193 99 407 -181 -378 80 176 499 434 17 777 418 631 319 -294 166 -504 -111 -92 -209 136 437 -126 -21 -134 -212 -203 -523 -1330 223 -165 -219 -1056 -578 -557 -1179 -1765 -1389 -454 -133 -161 -275 -282 -308 -278 34 -1063 -216 -591 -664 -190 -156 -225 -150 -350 -52 -42 239 -397 -456 -326 -702 -274 -403 -134 -233 -326 164 -1084 -435 106 466 316 551 191 93 627 50 -6 647 876 429 407 1014 1208 -62 696 606 1264 656 88 236 705 404 189 877 193 472 94 -307 99 -692 -455 -750 -612 -168 -278 -444 -605 -1447 -1319 -541 226 374 438 719 147 739 -477 440 -157 -226 -456 837 704 -493 -909 -746 -511 -709 -544 -1346 -1588 -405 -1081 706 427 1261 401 207 -137 382 271 143 624 -296 -633 131 280 764 636 24 1043 563 914 512 -516 308 -978 -225 -198 -477 321 1047 -306 -50 -305 -459 -424 SS 20220711T114924.5Z 8227.492645 157 1 2.80 2 73.30 75.09 135.10 275.18 0.00 1 0.00 1 0 17 2.096e-01 1.540e-02 2.352e-01 1.560e-02 4.346738e-01 8.253176e-03 5.040165e-03 -6.000000e+00 1.248326e-01 232.91 -2.00 3.53 -2.00 319.47 0.00e+00 5.726896e-04 2.278705e-03 2.916743e-04 -6.000000e+00 5.697378e-03 287.41 -2.00 20.00 -2.00 318.71 0.00e+00 3.426 0.001 302.00 328.00 3 3.3157e+00 2.3580e-02 4.0996e-02 -6.0000e+00 3.1315e-01 2.8212e-02 2.7734e-02 2.3441e-02 -6.0000e+00 3.3785e-01 -2.7866e-02 2.1343e-02 1.1322e-02 -6.0000e+00 2.0076e-01 1.2311e-02 1.1155e-02 3.3013e-03 -6.0000e+00 8.5425e-02 3.9706e-04 -3.1039e-04 4.6723e-04 3.5589e-05 -6.0000e+00 5.9886e-03 -5.5294e-03 -9.7722e-05 12 9 9 12 1 1 999.00 19.31 0.42 -0.00553 -0.00786 1 10 1 5 0 1311.620 22.71 14.98 19.31 26.74 7.0 997.27 18638 -84295 900000 22523 900000 -21089 173683 -58993 -26341 55262 -24985 86943 4616 -590 -9821 1432 26679 17879 -9912 412 64 -18279 20819 4663 24389 -1208 21696 3435 7186 -9059 4312 10525 -5209 7475 -6021 4413 -12001 6483 -2830 -1016 -8252 -10214 4211 5162 -3139 -4444 4792 5028 -5438 3334 -126 5288 5775 4116 -766 6176 -3388 5355 -1987 -1627 1388 -746 4291 -2165 -1809 -3476 2576 -1043 3201 -2378 3376 2367 2390 -185 2186 -1391 -1149 -1583 -2842 1435 -1205 1486 -4140 -3951 -1752 909 -299 1121 2982 45 3784 -3080 -2358 2111 917 -750 226 614 -494 213 -1533 976 -3132 1444 -203 -297 -1606 553 568 -612 1277 -597 591 -1436 -136 387 175 446 -1265 1315 15 1287 -467 313 -393 1222 -2203 1392 738 132 -26 -237 -7 490 -119 -439 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