File name: Pandora208s1_Windsor-West_20220720_L2Fit_fout2c1d20211014p1-8.txt File generation date: 20220930T034504.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.33 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v1d20211014.txt Level 1 file used: Pandora208s1_Windsor-West_20220720_L1_smca1c1d20211014p1-8.txt.bz2 Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.1175 305.2587 305.3999 305.5410 305.6822 305.8233 305.9644 306.1055 306.2466 306.3877 306.5288 306.6699 306.8109 306.9520 307.0930 307.2340 307.3750 307.5160 307.6570 307.7980 307.9390 308.0799 308.2209 308.3618 308.5027 308.6436 308.7845 308.9254 309.0663 309.2071 309.3480 309.4888 309.6297 309.7705 309.9113 310.0521 310.1929 310.3336 310.4744 310.6152 310.7559 310.8966 311.0374 311.1781 311.3188 311.4594 311.6001 311.7408 311.8814 312.0221 312.1627 312.3033 312.4439 312.5845 312.7251 312.8657 313.0062 313.1468 313.2873 313.4278 313.5683 313.7088 313.8493 313.9898 314.1303 314.2707 314.4112 314.5516 314.6920 314.8324 314.9728 315.1132 315.2536 315.3940 315.5343 315.6747 315.8150 315.9553 316.0956 316.2359 316.3762 316.5165 316.6567 316.7970 316.9372 317.0774 317.2177 317.3579 317.4980 317.6382 317.7784 317.9185 318.0587 318.1988 318.3389 318.4791 318.6192 318.7592 318.8993 319.0394 319.1794 319.3195 319.4595 319.5995 319.7395 319.8795 320.0195 320.1595 320.2994 320.4394 320.5793 320.7192 320.8592 320.9991 321.1389 321.2788 321.4187 321.5585 321.6984 321.8382 321.9780 322.1178 322.2576 322.3974 322.5372 322.6769 322.8167 322.9564 323.0962 323.2359 323.3756 323.5153 323.6549 323.7946 323.9343 324.0739 324.2135 324.3532 324.4928 324.6324 324.7719 324.9115 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220720T112412.7Z 8236.475147 249 1 4.77 2 78.87 72.18 34.56 181.83 0.00 1 0.00 1 0 25 5.151e-01 2.791e-02 3.338e-01 2.002e-02 6.139204e-01 1.134565e-02 7.148474e-03 -6.000000e+00 3.112549e-01 232.75 -2.00 3.53 -2.00 321.10 0.00e+00 -8.548079e-03 5.195591e-03 4.453781e-03 -6.000000e+00 1.527662e-02 287.92 -2.00 20.00 -2.00 320.47 0.00e+00 4.996 0.002 302.00 328.00 3 2.7125e+00 3.8393e-02 6.6371e-02 -6.0000e+00 7.8239e-01 1.2639e-01 5.0791e-02 5.5470e-02 -6.0000e+00 8.4622e-01 -3.6909e-01 4.3624e-02 1.7183e-02 -6.0000e+00 5.0032e-01 1.7591e-01 2.0624e-02 1.2317e-02 -6.0000e+00 2.1387e-01 1.4825e-04 1.7988e-04 6.2370e-04 7.5926e-05 -6.0000e+00 1.5322e-02 -1.3522e-02 2.6233e-05 12 9 9 12 1 1 -102.22 19.25 0.53 -0.01352 -0.01217 3 11 1 5 0 1147.040 22.61 15.00 19.25 30.54 7.4 1021.91 -80480 900000 900000 900000 -141771 900000 20102 900000 -100432 196132 -167944 -121216 -85381 -68710 900000 -78274 278704 -101843 900000 -56342 900000 157816 -23816 900000 -41595 112119 -91116 900000 12830 14234 -19020 49951 46254 14329 -12184 60985 110654 -19451 111664 28102 75523 8433 59106 23858 5545 38094 5287 43604 5412 24206 17532 18315 -2322 45516 17676 10266 33856 8826 10736 8028 25821 -1380 8710 11609 14380 10596 -8558 10159 -704 5236 414 12464 -987 9192 2242 -7482 -1584 2028 -7897 -1045 -636 -8175 -1498 -4857 916 -621 983 -2284 -2435 4174 -3586 -1164 2022 1179 -1708 75 -1293 -1168 -1428 -1912 379 -5674 294 -2230 76 -2400 -3079 -1313 -1787 1584 -203 1629 -567 986 -986 2232 -537 841 839 -337 2496 970 2988 -1569 1661 185 2295 400 1223 2096 1005 -1086 -1556 -436 936 582 -181 -197 -549 -680 487 -1746 -1568 900000 900000 900000 -3354 900000 392 900000 -2516 3822 -9350 -4724 -2733 -2200 900000 -3595 5431 -6804 900000 -2588 900000 3075 -895 900000 -2316 2185 -8497 900000 375 436 -927 1497 1481 638 -678 1828 2322 -1705 3515 2229 4099 939 4031 2291 633 3128 603 3459 655 2628 2269 2600 -443 5828 3174 2086 5560 1830 2107 1598 4492 -348 2218 3102 3743 2773 -2728 2856 -251 1997 179 4875 -429 3365 796 -2655 -509 660 -3253 -471 -329 -5120 -947 -3168 607 -444 721 -1753 -1838 2986 -2585 -776 1295 817 -1291 64 -1284 -1289 -1636 -2124 379 -5513 261 -2152 77 -2625 -3612 -1634 -2473 2353 -309 2498 -870 1417 -1464 3158 -807 1235 1301 -538 3793 1544 4514 -2382 2352 257 3127 606 1934 3622 1885 -2188 -3325 -927 2085 1344 -428 -471 -1282 -1505 1069 -3750 SS 20220720T112901.8Z 8236.478493 253 1 47.13 2 78.02 72.94 34.59 183.89 0.00 1 0.00 1 0 25 3.546e-01 7.076e-03 1.253e-01 3.250e-03 5.920513e-01 1.777248e-03 6.803891e-03 -6.000000e+00 2.105413e-01 232.75 -2.00 3.53 -2.00 321.09 0.00e+00 2.496192e-03 8.400711e-04 1.819284e-03 -6.000000e+00 9.313051e-03 287.92 -2.00 20.00 -2.00 320.45 0.00e+00 4.669 0.002 302.00 328.00 3 1.2629e+00 6.0769e-03 5.6442e-02 -6.0000e+00 5.2843e-01 2.6292e-02 8.1667e-03 3.3766e-02 -6.0000e+00 5.6994e-01 -6.7546e-02 7.7603e-03 1.7662e-02 -6.0000e+00 3.3912e-01 2.1081e-02 3.7235e-03 5.4359e-03 -6.0000e+00 1.4408e-01 8.2618e-04 -5.7723e-04 9.7289e-05 7.1134e-05 -6.0000e+00 1.0044e-02 -7.2477e-03 -5.0640e-06 11 8 0 10 0 0 89.98 19.25 0.36 -0.00725 -0.01159 239 65 1 5 0 197.150 22.61 15.02 19.25 30.98 7.4 1024.84 -125469 -144690 -42048 -134665 -87079 -173276 -122200 -117245 -58310 -106756 -95038 -86341 -65233 6304 -69066 -14557 -36604 -8048 -27138 -27627 -18624 -25058 -6708 -18549 -3798 -10458 -18390 -24727 -717 2893 -13200 -6783 -14491 -3313 -8167 -3186 -4800 -10545 -6433 573 -4341 -2170 4017 -387 3067 -846 3394 -2342 1747 750 1212 344 2585 5277 3352 4352 35 3735 1891 1819 2921 4263 4847 3314 1712 3304 1178 1154 2080 1555 2517 128 1274 60 -581 -1408 -2303 -377 -1836 -1313 -1280 -1092 -1244 -1346 -365 -204 1090 249 1208 220 723 -1065 -477 -505 -661 295 432 183 -501 -345 -1206 -593 -755 -1046 -1432 -1014 -514 -460 365 211 461 62 499 -251 -141 179 72 397 93 -38 326 438 285 736 -81 272 840 20 245 -4 69 -70 -74 -264 -54 -24 164 258 -148 -114 -249 -334 -1153 -1667 -200 -1536 -579 -2800 -1317 -1375 -425 -1353 -1144 -1122 -868 52 -1488 -212 -742 -135 -593 -639 -401 -588 -140 -476 -90 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4.9383e-01 -1.3508e-01 2.4861e-02 1.8675e-02 -6.0000e+00 2.8937e-01 5.6042e-02 1.2082e-02 5.5369e-03 -6.0000e+00 1.2378e-01 1.1390e-04 -7.3936e-04 3.5813e-04 1.0142e-04 -6.0000e+00 8.7121e-03 -6.6021e-03 -4.9088e-05 12 8 8 10 0 0 95.27 19.29 0.70 -0.00660 -0.01216 33 9 1 5 0 1415.040 22.71 15.00 19.29 31.40 7.3 1027.57 900000 -103890 900000 -63905 900000 900000 -150628 900000 -140054 900000 -133668 900000 -17934 33509 81932 -20923 -14604 -18579 900000 18770 68197 -41101 900000 -23725 -18631 -913 -18003 440 -66430 32897 -37309 81526 -43202 2695 -17928 17526 -12246 3246 34784 -20839 12461 -32 24075 14437 1046 5044 8738 7729 -8222 8271 -8419 6056 -6209 5238 938 3093 5003 3527 15149 7923 15321 2039 10578 3350 12746 4010 4177 6732 -1977 7166 -2918 2552 -159 5161 -775 1121 675 -5191 74 -3500 2392 -5637 1914 -1935 732 -2870 384 -1888 64 1786 -88 -193 -3048 1218 -1542 681 328 77 -774 -324 -1207 -3139 -837 -1607 -1101 -1015 -526 -458 -342 -405 492 1596 -793 532 -600 314 339 304 1493 -525 119 102 2430 -750 2675 -1536 2514 -62 294 665 -655 44 -501 269 -538 118 266 696 -579 79 -128 -1087 900000 -1759 900000 -703 900000 900000 -3954 900000 -4032 900000 -3962 900000 -243 369 902 -514 -371 -535 900000 413 1001 -1671 900000 -904 -710 -30 -701 14 -4106 905 -2243 1870 -3548 141 -1108 787 -840 228 2150 -2594 1213 -4 2304 1553 131 619 1051 962 -1246 1142 -1518 1036 -1299 1042 202 673 1080 761 2861 1630 3127 530 2830 1038 3583 1182 1220 2012 -727 2712 -1309 1104 -68 1971 -285 398 231 -1976 31 -1618 1193 -3384 1139 -1273 504 -2170 293 -1497 49 1266 -64 -131 -2089 851 -1251 620 316 83 -863 -346 -1295 -3136 -794 -1626 -1186 -1151 -631 -590 -446 -580 745 2414 -1190 804 -868 442 493 469 2408 -881 195 162 3643 -1110 3673 -2114 3325 -91 480 1182 -1259 89 -1053 598 -1178 265 609 1602 -1317 184 -284 -2340 SS 20220720T130744.0Z 8236.547038 369 1 46.69 2 60.07 88.57 41.34 221.90 0.00 1 0.00 1 0 17 1.060e-02 4.838e-03 4.643e-03 9.769e-04 2.664076e-01 5.088530e-04 3.201476e-03 -6.000000e+00 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