File name: Pandora208s1_Windsor-West_20220801_L2Fit_fout2c1d20211014p1-8.txt File generation date: 20220930T050443.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.33 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v1d20211014.txt Level 1 file used: Pandora208s1_Windsor-West_20220801_L1_smca1c1d20211014p1-8.txt.bz2 Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.1175 305.2587 305.3999 305.5410 305.6822 305.8233 305.9644 306.1055 306.2466 306.3877 306.5288 306.6699 306.8109 306.9520 307.0930 307.2340 307.3750 307.5160 307.6570 307.7980 307.9390 308.0799 308.2209 308.3618 308.5027 308.6436 308.7845 308.9254 309.0663 309.2071 309.3480 309.4888 309.6297 309.7705 309.9113 310.0521 310.1929 310.3336 310.4744 310.6152 310.7559 310.8966 311.0374 311.1781 311.3188 311.4594 311.6001 311.7408 311.8814 312.0221 312.1627 312.3033 312.4439 312.5845 312.7251 312.8657 313.0062 313.1468 313.2873 313.4278 313.5683 313.7088 313.8493 313.9898 314.1303 314.2707 314.4112 314.5516 314.6920 314.8324 314.9728 315.1132 315.2536 315.3940 315.5343 315.6747 315.8150 315.9553 316.0956 316.2359 316.3762 316.5165 316.6567 316.7970 316.9372 317.0774 317.2177 317.3579 317.4980 317.6382 317.7784 317.9185 318.0587 318.1988 318.3389 318.4791 318.6192 318.7592 318.8993 319.0394 319.1794 319.3195 319.4595 319.5995 319.7395 319.8795 320.0195 320.1595 320.2994 320.4394 320.5793 320.7192 320.8592 320.9991 321.1389 321.2788 321.4187 321.5585 321.6984 321.8382 321.9780 322.1178 322.2576 322.3974 322.5372 322.6769 322.8167 322.9564 323.0962 323.2359 323.3756 323.5153 323.6549 323.7946 323.9343 324.0739 324.2135 324.3532 324.4928 324.6324 324.7719 324.9115 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220801T113343.6Z 8248.481754 79 1 23.16 2 78.92 75.74 115.52 52.59 0.00 1 0.00 1 0 25 3.638e-01 1.078e-02 3.082e-01 8.772e-03 6.235715e-01 4.914996e-03 7.242916e-03 -6.000000e+00 2.178525e-01 232.31 -2.00 3.53 -2.00 321.24 0.00e+00 -7.773606e-04 2.382331e-03 3.031974e-03 -6.000000e+00 9.744988e-03 288.17 -2.00 20.00 -2.00 320.60 0.00e+00 5.018 0.002 302.00 328.00 3 2.2229e+00 1.7237e-02 6.2000e-02 -6.0000e+00 5.4597e-01 8.2778e-02 2.3259e-02 4.1004e-02 -6.0000e+00 5.8948e-01 -1.6958e-01 2.1877e-02 1.8427e-02 -6.0000e+00 3.4902e-01 6.6558e-02 1.0403e-02 5.4743e-03 -6.0000e+00 1.4770e-01 2.2440e-04 -4.6272e-04 2.6867e-04 6.4974e-05 -6.0000e+00 1.0469e-02 -6.2074e-03 -1.6720e-05 12 9 9 12 1 1 99.88 19.38 0.53 -0.00621 -0.00968 39 22 1 5 0 574.360 22.80 14.99 19.38 27.45 7.6 990.23 -140022 -91592 -132415 -157851 900000 -107980 900000 -122275 -122707 -102900 -55686 -4370 -127803 -14034 23834 89447 -46907 -6484 -57992 -9861 -8297 -1317 27789 -15690 3079 -72495 23748 -56448 -7819 -41156 -36941 58051 -9914 4419 -13521 24956 -18864 5574 -1457 13223 -2177 3738 6349 11243 14326 11193 8582 -2046 6181 -3978 15613 -4109 5944 1154 -3392 6577 3594 7376 -78 4682 2030 -795 726 1216 5757 227 4514 2402 6690 1308 3558 2951 -2364 21 733 1537 -285 3794 -3119 232 -4080 -633 -2107 -1546 731 797 1439 165 1881 -1132 71 -1954 98 -2262 -1981 140 119 250 -766 -697 -2024 421 -2404 -908 -1883 -1248 317 -747 1380 -32 923 450 223 -233 661 146 -225 779 109 313 -56 511 1 795 505 183 408 123 214 -458 580 -731 590 -433 108 38 73 -27 -544 231 -462 182 -1415 -783 -1441 -2086 900000 -923 900000 -1568 -1784 -1320 -476 -37 -3278 -144 204 765 -1043 -105 -1686 -185 -156 -24 404 -389 68 -3595 447 -2268 -194 -1584 -1611 1142 -432 170 -601 790 -1065 300 -103 950 -201 345 592 1009 1262 1034 829 -227 666 -517 1869 -664 950 209 -679 1243 713 1388 -15 885 418 -188 191 346 1575 64 1227 711 2156 504 1442 1226 -1002 8 254 481 -88 1194 -1216 103 -2181 -366 -1329 -1035 514 593 1108 118 1434 -840 49 -1290 63 -1603 -1597 128 113 264 -848 -742 -2006 408 -2319 -912 -2045 -1419 344 -886 1776 -46 1426 713 346 -345 922 202 -323 1171 175 505 -88 777 1 1118 755 264 593 179 350 -831 1120 -1504 1267 -1003 263 97 188 -71 -1384 553 -1052 395 SS 20220801T113942.2Z 8248.485905 82 1 46.83 2 77.85 76.69 114.69 53.87 0.00 1 0.00 1 0 25 3.217e-01 6.099e-03 9.795e-02 2.695e-03 5.799165e-01 1.483182e-03 6.674996e-03 -6.000000e+00 1.906711e-01 232.31 -2.00 3.53 -2.00 321.05 0.00e+00 1.226840e-03 6.899188e-04 1.763334e-03 -6.000000e+00 8.456587e-03 288.17 -2.00 20.00 -2.00 320.40 0.00e+00 4.609 0.002 302.00 328.00 3 1.0580e+00 5.0476e-03 5.5608e-02 -6.0000e+00 4.7799e-01 -7.9964e-03 6.7258e-03 3.3402e-02 -6.0000e+00 5.1570e-01 -2.9990e-02 6.3643e-03 1.6893e-02 -6.0000e+00 3.0701e-01 3.0565e-03 3.0677e-03 4.8135e-03 -6.0000e+00 1.3058e-01 1.1062e-03 -4.6609e-04 8.1851e-05 6.2601e-05 -6.0000e+00 9.1103e-03 -7.1763e-03 -2.5100e-05 10 0 0 10 0 0 76.05 19.38 0.23 -0.00718 -0.01068 291 79 1 5 0 160.900 22.80 14.99 19.38 27.80 7.6 992.87 -113878 -107359 -99799 -91445 -97326 -121886 -125420 -101352 -86678 -98439 -107709 -61666 -68781 -49431 -27291 -27334 -19615 -30466 -16736 -11418 -10551 -23659 -4321 -20254 3104 -12426 -23758 -20272 -22707 -2950 -15900 230 -14192 -7108 -8624 -3432 -4372 -2491 340 1231 1575 -2543 2120 -837 -669 -2038 698 1713 -536 -770 2341 3767 2969 2944 2488 3271 1644 800 1231 1461 1149 2334 4372 1894 2347 1013 1146 1297 958 1246 1018 1095 -134 941 -1458 -754 -1623 -941 -1734 -1344 -722 -1694 -1270 -1118 -137 -167 1125 649 1149 812 -154 -439 -243 332 -486 526 388 167 -159 -219 -946 -1381 -790 -1415 -1211 -1187 -405 -487 126 489 613 416 183 -75 -78 -54 506 160 83 -73 369 218 489 280 267 -39 687 277 161 26 -56 -322 -54 -145 -157 -56 190 125 -27 -119 -67 -236 -928 -931 -839 -673 -716 -1185 -1417 -1039 -866 -1190 -1528 -648 -976 -727 -394 -460 -340 -648 -334 -228 -213 -560 -91 -548 72 -353 -755 -602 -698 -83 -602 9 -694 -331 -394 -156 -231 -157 26 107 151 -271 225 -93 -76 -238 81 204 -68 -107 352 618 536 573 512 695 362 176 264 315 265 595 1230 592 733 310 352 421 354 521 458 503 -61 393 -565 -264 -553 -336 -719 -651 -400 -1057 -847 -794 -104 -134 928 547 945 633 -113 -304 -166 241 -403 497 382 183 -181 -240 -1055 -1410 -778 -1484 -1357 -1400 -505 -595 169 720 966 667 287 -111 -110 -74 720 241 133 -119 585 335 725 439 402 -57 998 440 261 47 -106 -647 -114 -327 -375 -138 479 319 -67 -282 -149 -510 SS 20220801T114512.9Z 8248.489733 85 1 46.70 2 76.86 77.57 113.90 55.04 0.00 1 0.00 1 0 25 2.525e-01 5.746e-03 6.893e-02 2.230e-03 5.396371e-01 1.212808e-03 6.219419e-03 -6.000000e+00 1.496628e-01 232.31 -2.00 3.53 -2.00 320.83 0.00e+00 2.415295e-03 5.241385e-04 1.233917e-03 -6.000000e+00 6.637793e-03 288.17 -2.00 20.00 -2.00 320.15 0.00e+00 4.285 0.001 302.00 328.00 3 1.0926e+00 3.9656e-03 5.1286e-02 -6.0000e+00 3.7518e-01 -1.1596e-02 5.1559e-03 2.9767e-02 -6.0000e+00 4.0478e-01 -2.2038e-02 4.7464e-03 1.5568e-02 -6.0000e+00 2.4098e-01 -8.5677e-04 2.3285e-03 4.9968e-03 -6.0000e+00 1.0250e-01 1.5015e-03 -4.5831e-04 6.7836e-05 6.0376e-05 -6.0000e+00 7.1510e-03 -7.3221e-03 -3.0518e-05 10 0 0 10 0 0 46.84 19.36 0.32 -0.00732 -0.01077 352 95 1 5 0 132.650 22.80 15.00 19.36 28.17 7.6 996.37 -75362 -108684 -61476 -83334 -80655 -112196 -87159 -75741 -82119 -59967 -77559 -42608 -48618 -30179 -21593 -23331 -17996 -15294 -15150 -19583 -9782 -16442 -5185 -10825 -11877 -11086 -18839 -10889 -8189 -9022 -5065 -1485 -5035 -4094 -7249 -9051 -8581 592 -1228 -1908 2955 -1237 683 457 483 633 1526 -313 214 2370 1470 2201 2064 1881 1993 2889 1360 1133 -473 -145 2434 2476 2945 1740 1879 1297 853 1121 1888 1185 930 1285 -130 -149 -743 -522 -1513 -875 -1457 -813 -1026 -1796 -1343 -1048 -416 -234 779 463 673 460 481 180 -183 158 -424 390 473 419 -398 -265 -634 -961 -734 -1126 -1313 -1137 -557 -318 319 467 467 327 57 -102 147 326 203 36 -44 -239 118 345 195 455 262 228 979 483 72 -1 -225 -163 -26 -230 -141 160 136 92 -88 -96 -249 -167 -623 -1418 -521 -834 -737 -1439 -967 -856 -1107 -691 -1130 -510 -772 -499 -399 -507 -411 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