File name: Pandora208s1_Windsor-West_20220812_L2Fit_fout2c1d20211014p1-8.txt File generation date: 20220930T071306.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.33 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v1d20211014.txt Level 1 file used: Pandora208s1_Windsor-West_20220812_L1_smca1c1d20211014p1-8.txt.bz2 Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.1175 305.2587 305.3999 305.5410 305.6822 305.8233 305.9644 306.1055 306.2466 306.3877 306.5288 306.6699 306.8109 306.9520 307.0930 307.2340 307.3750 307.5160 307.6570 307.7980 307.9390 308.0799 308.2209 308.3618 308.5027 308.6436 308.7845 308.9254 309.0663 309.2071 309.3480 309.4888 309.6297 309.7705 309.9113 310.0521 310.1929 310.3336 310.4744 310.6152 310.7559 310.8966 311.0374 311.1781 311.3188 311.4594 311.6001 311.7408 311.8814 312.0221 312.1627 312.3033 312.4439 312.5845 312.7251 312.8657 313.0062 313.1468 313.2873 313.4278 313.5683 313.7088 313.8493 313.9898 314.1303 314.2707 314.4112 314.5516 314.6920 314.8324 314.9728 315.1132 315.2536 315.3940 315.5343 315.6747 315.8150 315.9553 316.0956 316.2359 316.3762 316.5165 316.6567 316.7970 316.9372 317.0774 317.2177 317.3579 317.4980 317.6382 317.7784 317.9185 318.0587 318.1988 318.3389 318.4791 318.6192 318.7592 318.8993 319.0394 319.1794 319.3195 319.4595 319.5995 319.7395 319.8795 320.0195 320.1595 320.2994 320.4394 320.5793 320.7192 320.8592 320.9991 321.1389 321.2788 321.4187 321.5585 321.6984 321.8382 321.9780 322.1178 322.2576 322.3974 322.5372 322.6769 322.8167 322.9564 323.0962 323.2359 323.3756 323.5153 323.6549 323.7946 323.9343 324.0739 324.2135 324.3532 324.4928 324.6324 324.7719 324.9115 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220812T112815.9Z 8259.477962 215 1 46.78 2 81.69 77.40 95.97 250.53 0.00 1 0.00 1 0 17 6.089e-01 1.529e-02 2.833e-01 5.318e-03 8.787237e-01 3.081727e-03 9.892186e-03 -6.000000e+00 3.604427e-01 231.91 -2.00 3.53 -2.00 322.07 0.00e+00 6.690281e-03 1.937889e-03 1.747290e-03 -6.000000e+00 1.602403e-02 288.39 -2.00 20.00 -2.00 321.58 0.00e+00 6.495 0.005 302.00 328.00 3 -3.0509e-01 1.2869e-02 8.0515e-02 -6.0000e+00 9.0260e-01 5.8048e-01 1.8806e-02 5.0920e-02 -6.0000e+00 9.7403e-01 -7.9276e-01 1.8097e-02 2.7798e-02 -6.0000e+00 5.8016e-01 3.1804e-01 8.1018e-03 1.1812e-02 -6.0000e+00 2.4706e-01 4.9217e-04 -1.3758e-03 1.4582e-04 1.7047e-04 -6.0000e+00 1.7243e-02 -8.1365e-03 -2.8094e-05 12 8 8 10 0 0 -2.92 19.38 0.32 -0.00814 -0.01847 315 85 1 5 0 148.460 22.80 15.01 19.38 20.96 7.8 934.86 -244781 -91962 -223171 -214280 -126687 -202551 -55188 -239904 68718 -207576 -122050 -184100 -97600 -112212 -123225 25709 -72130 3580 -95013 63645 -95205 -31611 -79522 278 -46010 -87638 -519 -77644 64980 -56887 80340 -5725 4805 -15261 3781 18699 -17021 53234 -4728 30313 3691 68443 13053 28531 8756 14910 12176 6929 38539 8016 42526 13757 33192 12759 23967 19996 11218 19667 4084 24696 8481 19749 6567 16059 7333 12172 9278 8691 15300 3788 16432 3984 11205 2094 2368 -3670 -2437 2088 -4740 4450 -185 3072 -2016 1235 -1573 1133 1472 114 2672 1188 827 -1527 241 -3180 -1336 -2127 -1463 -775 -1945 -324 -2493 -69 -3158 -1230 -3043 -2694 -1288 -1860 15 -854 294 -661 477 -759 287 -251 -15 0 288 790 544 1841 1301 1694 144 733 406 607 222 406 803 32 559 -452 186 -188 323 -157 -161 -157 -542 -931 -4731 -477 -3998 -3232 -717 -2387 -286 -4637 356 -3229 -949 -2951 -962 -1687 -2382 147 -1234 32 -2365 330 -2370 -410 -1732 3 -787 -2318 -6 -1771 371 -1298 583 -119 102 -404 78 339 -494 911 -174 912 159 1633 562 1065 404 665 581 370 1619 507 2161 1041 2272 1158 2038 1825 1123 1754 409 1998 857 2028 892 2223 1148 1818 1477 1505 2832 892 3647 1010 2516 470 473 -710 -463 418 -1217 1260 -65 1180 -883 557 -778 574 771 61 1367 583 382 -697 111 -1687 -820 -1566 -1260 -685 -1830 -319 -2295 -55 -2455 -974 -2619 -2442 -1240 -1991 18 -1077 407 -970 693 -1083 391 -376 -23 0 445 1211 881 2804 1924 2407 201 990 564 948 405 763 1657 72 1329 -1166 508 -530 919 -448 -445 -406 -1303 -2119 SS 20220812T114339.5Z 8259.488652 220 1 46.22 2 78.91 79.89 98.53 252.97 0.00 1 0.00 1 0 25 5.341e-01 6.486e-03 8.010e-02 1.678e-03 7.052195e-01 9.566196e-04 8.149393e-03 -6.000000e+00 3.161729e-01 231.91 -2.00 3.53 -2.00 321.47 0.00e+00 4.120340e-03 5.007659e-04 2.183445e-03 -6.000000e+00 1.405602e-02 288.39 -2.00 20.00 -2.00 320.87 0.00e+00 5.010 0.002 302.00 328.00 3 -3.9483e-01 3.5085e-03 6.3086e-02 -6.0000e+00 7.9174e-01 9.7374e-02 4.9552e-03 4.0545e-02 -6.0000e+00 8.5440e-01 -1.0473e-01 4.9485e-03 2.2492e-02 -6.0000e+00 5.0890e-01 3.1164e-02 2.3103e-03 7.8668e-03 -6.0000e+00 2.1671e-01 2.6832e-03 -8.1381e-04 4.9235e-05 1.1064e-04 -6.0000e+00 1.5126e-02 -8.2749e-03 -3.6277e-05 11 8 0 10 0 0 14.25 19.39 0.27 -0.00827 -0.01439 773 209 1 5 0 59.700 22.80 15.00 19.39 22.92 7.8 951.63 -199385 -175805 -190274 -178275 -198084 -161976 -200485 -150644 -106296 -166127 -131330 -111607 -96259 -101192 -65844 -82588 -46286 -36343 -43230 -37781 -26050 -26398 -40390 -31423 -35606 -27835 -38403 -36784 -30387 -27209 -17677 -17370 -7253 -12779 -12629 -13527 -9841 -5972 -3359 -852 1125 -444 -257 -1080 1704 3585 904 480 2573 967 4896 4352 4743 4908 4925 2084 2489 1355 808 993 2913 4048 4423 4172 2377 2739 1012 2021 2387 2160 1804 1403 759 811 49 -1541 -963 -1221 -647 -822 -556 -971 -1372 -917 -415 -47 394 523 644 270 22 -477 -434 -81 -408 -278 314 42 -291 -451 -1044 -1041 -752 -1089 -1365 -1091 -762 -330 196 408 362 344 326 -151 211 125 418 25 30 -185 459 444 336 419 163 158 539 289 23 124 -109 -119 45 -269 -73 32 130 -21 -59 -18 -54 -225 -1566 -1265 -1681 -1341 -1717 -1007 -2033 -1060 -539 -1658 -1010 -858 -835 -1208 -700 -1243 -553 -440 -608 -531 -332 -345 -654 -509 -646 -492 -760 -704 -567 -570 -413 -486 -210 -403 -386 -436 -351 -249 -168 -49 70 -30 -18 -79 125 267 72 40 226 95 525 524 626 702 743 337 407 221 129 160 493 766 954 996 590 667 255 541 726 747 673 535 281 278 15 -445 -270 -370 -229 -346 -271 -535 -818 -579 -279 -30 263 353 468 186 14 -294 -268 -54 -316 -228 297 45 -322 -481 -1026 -1014 -699 -1065 -1299 -1091 -811 -381 252 585 564 550 513 -228 303 177 610 39 48 -303 724 672 491 587 221 206 711 422 39 229 -219 -252 102 -648 -187 83 349 -57 -155 -44 -125 -499 SS 20220812T114944.8Z 8259.492880 223 1 46.05 2 77.80 80.88 99.55 253.93 0.00 1 0.00 1 0 25 4.081e-01 5.848e-03 5.407e-02 1.243e-03 6.525544e-01 6.947168e-04 7.565766e-03 -6.000000e+00 2.415744e-01 231.91 -2.00 3.53 -2.00 321.21 0.00e+00 2.969891e-03 3.358785e-04 1.572529e-03 -6.000000e+00 1.073949e-02 288.39 -2.00 20.00 -2.00 320.57 0.00e+00 4.589 0.002 302.00 328.00 3 -4.1981e-01 2.4215e-03 5.7718e-02 -6.0000e+00 6.0494e-01 6.0874e-02 3.3097e-03 3.6638e-02 -6.0000e+00 6.5281e-01 -5.0253e-02 3.2314e-03 1.9556e-02 -6.0000e+00 3.8883e-01 7.0388e-03 1.5386e-03 6.4516e-03 -6.0000e+00 1.6559e-01 4.3103e-03 -7.0273e-04 3.6590e-05 8.6674e-05 -6.0000e+00 1.1556e-02 -8.5053e-03 -3.6922e-05 10 0 0 10 0 0 15.63 19.39 0.23 -0.00851 -0.01379 998 270 1 5 0 45.950 22.80 15.01 19.39 23.52 7.8 955.57 -125984 -132797 -133874 -139715 -143760 -155628 -144687 -132278 -100718 -128939 -100362 -100350 -73542 -57237 -50970 -35885 -41977 -36480 -28577 -28044 -35122 -25605 -21495 -23458 -11203 -21455 -24501 -27357 -18979 -22572 -11789 -1148 -1712 -6780 -10500 -10716 -10273 -2324 -2806 -1263 -238 -1955 -1104 669 1354 661 2923 -117 1237 1217 2284 1561 3222 2111 2589 2539 1287 1208 -60 1679 1570 3418 4011 3024 2273 1767 615 945 2077 1492 1207 856 905 464 -234 -867 -2200 -1034 -1080 -1100 -854 -1442 -1598 -1156 -442 -65 431 329 794 601 718 15 -304 -44 -260 244 444 393 -348 -302 -1108 -971 -624 -1343 -1508 -1141 -667 -368 322 512 422 207 171 -87 216 266 414 163 -141 -200 136 306 365 456 131 189 620 274 37 22 21 -294 -21 -191 -110 -2 227 58 -69 15 -164 -135 -717 -933 -1006 -1066 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