File name: Pandora208s1_Windsor-West_20230626_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20230628T001727.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20230626_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20230626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230626T115942.2Z 8577.499794 105 1 46.59 2 70.16 76.02 138.75 6.34 0.00 1 0.00 1 0 25 9.359e-02 7.448e-03 6.738e-02 4.471e-03 4.165057e-01 2.361021e-03 4.832308e-03 -6.000000e+00 5.556923e-02 232.87 -2.00 3.53 -2.00 319.72 0.00e+00 1.816315e-03 6.919121e-04 2.258550e-04 -6.000000e+00 2.435825e-03 286.02 -2.00 20.00 -2.00 318.99 0.00e+00 2.914 0.000 302.00 328.00 3 4.7137e+00 6.8319e-03 3.6402e-02 -6.0000e+00 1.3961e-01 4.9771e-02 8.1000e-03 2.2352e-02 -6.0000e+00 1.5061e-01 -9.3915e-03 6.3354e-03 1.1123e-02 -6.0000e+00 8.9500e-02 -3.7967e-04 3.2818e-03 3.7659e-03 -6.0000e+00 3.7937e-02 1.5748e-04 -9.1589e-05 1.3624e-04 3.9056e-05 -6.0000e+00 2.6447e-03 -4.7288e-03 -1.3393e-04 11 8 0 10 0 0 99.84 19.37 0.46 -0.00473 -0.00542 33 9 1 5 0 1411.560 22.71 14.99 19.37 25.62 12.1 1035.34 -26822 28765 39046 -35322 17781 -47516 -30643 -34629 -3004 -9083 -20561 -16093 -13819 7654 -22406 18204 -11832 8773 -2660 328 12618 4946 -1686 2290 1231 -6745 5850 -13404 3941 -554 2773 -1651 2168 -1396 -3891 -361 -5920 -497 -2923 3534 -3192 -68 -3395 2401 1335 819 2229 -3994 4388 -412 2734 -1819 1804 -607 2032 2125 435 853 481 1933 134 2582 -63 1945 524 -807 -189 -500 872 -927 1099 -174 1371 37 466 -759 -932 -1157 66 -686 -1953 -1429 -2456 -1525 -483 208 1086 1145 1273 13 1092 -64 306 -709 345 -407 1296 1138 373 -831 -928 -659 -1688 -390 -1438 -386 -833 14 -120 382 643 42 12 -594 383 -848 259 -218 637 -42 -130 597 282 609 -201 851 -135 59 -58 484 253 -200 176 -128 238 -169 338 94 -74 -177 -359 -501 -596 426 536 -955 260 -1336 -795 -1057 -74 -249 -650 -540 -542 292 -1363 829 -784 507 -182 23 784 334 -128 179 103 -632 478 -1262 305 -48 259 -181 252 -169 -461 -42 -834 -79 -575 752 -789 -17 -913 616 349 217 581 -1111 1140 -118 828 -625 641 -234 791 850 179 345 192 766 57 1183 -32 1046 280 -412 -93 -255 490 -597 743 -122 919 23 269 -401 -464 -590 37 -448 -1460 -1169 -2156 -1407 -473 215 1158 1239 1350 13 1006 -55 252 -614 327 -439 1551 1424 481 -1092 -1126 -734 -1858 -450 -1794 -499 -1143 21 -179 610 1073 70 20 -893 561 -1225 381 -340 1000 -69 -209 927 445 911 -290 1160 -184 86 -91 823 432 -354 323 -249 488 -360 732 206 -158 -364 -708 -954 SS 20230626T121022.9Z 8577.507209 108 1 6.31 2 68.24 77.65 138.52 10.21 0.00 1 0.00 1 0 17 4.894e-02 7.820e-03 4.390e-02 5.432e-03 3.896606e-01 2.840434e-03 4.598041e-03 -6.000000e+00 2.907423e-02 232.87 -2.00 3.53 -2.00 318.68 0.00e+00 1.129598e-03 6.129934e-04 4.090506e-04 -6.000000e+00 1.273643e-03 286.02 -2.00 20.00 -2.00 317.91 0.00e+00 2.673 0.000 302.00 328.00 3 4.1494e+00 7.8295e-03 3.3648e-02 -6.0000e+00 7.3046e-02 5.5806e-02 8.9474e-03 2.0777e-02 -6.0000e+00 7.8783e-02 -1.5722e-03 6.2010e-03 1.0186e-02 -6.0000e+00 4.6820e-02 -8.6210e-03 3.2454e-03 2.9906e-03 -6.0000e+00 1.9858e-02 3.5951e-04 4.5784e-04 1.6066e-04 3.2362e-05 -6.0000e+00 1.3828e-03 -6.3093e-03 -3.6137e-05 12 9 1 12 1 1 -140.62 19.37 0.46 -0.00631 -0.00287 5 12 1 5 0 1023.040 22.80 15.00 19.37 26.14 12.1 1038.60 -3884 -21879 1449 -927 -11907 -23149 6344 -27102 11812 -17095 -786 -14127 -7310 -9319 1851 3413 -10787 440 -3108 10082 -1881 2796 -4537 -1857 440 2319 136 -948 1457 661 380 -334 2225 -6743 -2625 -2911 -5094 -1565 -468 565 -2631 4088 463 1698 -2642 748 1139 120 -299 -50 2543 1253 4360 -233 1726 -514 340 -1375 -1546 1501 2038 2728 679 2256 155 1092 -1383 -911 -440 529 582 -117 1143 -575 534 -1287 -516 -2227 -772 -1318 -1323 -1540 -870 195 -701 -282 190 825 58 393 690 579 -1187 211 485 340 256 -92 -303 -537 -129 -1547 -410 132 -750 -981 -851 -481 -44 942 746 662 235 -472 247 245 1008 -75 91 -611 -65 459 619 97 241 -271 857 1262 -324 126 46 -411 -466 -524 346 24 225 663 71 -492 -195 -723 -132 -979 53 -32 -423 -920 216 -1385 477 -919 -39 -827 -472 -733 152 309 -1206 47 -361 1071 -228 326 -597 -255 62 335 20 -132 192 92 59 -58 416 -1386 -492 -563 -1137 -402 -137 188 -980 1493 181 661 -1080 297 447 47 -120 -21 1128 581 2094 -124 931 -291 193 -785 -868 825 1175 1636 456 1573 108 705 -886 -597 -319 410 483 -100 940 -453 395 -873 -341 -1516 -551 -1039 -1175 -1445 -860 202 -757 -322 216 948 69 435 730 565 -1126 204 516 393 320 -121 -410 -698 -160 -1861 -478 163 -961 -1322 -1162 -692 -66 1444 1199 1060 372 -700 352 341 1429 -110 142 -987 -104 708 919 143 338 -378 1168 1754 -499 199 75 -686 -809 -930 645 45 429 1272 134 -926 -351 -1262 SS 20230626T122512.5Z 8577.517506 115 1 1.21 2 65.55 79.92 137.99 15.50 0.00 1 0.00 1 0 17 4.745e-02 1.201e-02 4.867e-02 1.009e-02 3.484154e-01 5.257888e-03 4.122897e-03 -6.000000e+00 2.819502e-02 232.87 -2.00 3.53 -2.00 317.99 0.00e+00 1.203461e-03 9.239657e-04 1.531055e-04 -6.000000e+00 1.235047e-03 286.02 -2.00 20.00 -2.00 317.21 0.00e+00 2.399 0.000 302.00 328.00 3 3.6133e+00 1.4195e-02 3.0094e-02 -6.0000e+00 7.0837e-02 2.8693e-02 1.6023e-02 1.8485e-02 -6.0000e+00 7.6399e-02 -3.5928e-03 1.0137e-02 8.9783e-03 -6.0000e+00 4.5403e-02 -3.8970e-03 5.1621e-03 2.7328e-03 -6.0000e+00 1.9259e-02 8.5796e-04 1.0514e-03 2.9567e-04 2.8671e-05 -6.0000e+00 1.3408e-03 -7.1952e-03 -4.7366e-05 12 9 9 12 1 1 999.00 19.37 0.43 -0.00720 0.00071 1 25 1 5 0 512.320 22.71 15.01 19.37 26.72 12.1 1043.11 -18109 17112 -20571 8485 -13648 -19485 -8929 -15297 -2645 -13587 -413 -233 -2166 -16192 -188 -1248 5549 -946 -5582 -1516 502 12379 -1506 2267 -3301 229 -2495 738 1649 4310 5617 -3241 6165 1844 -2605 -4521 66 -2774 -2638 -991 -1240 -27 -1083 -340 -896 2849 -3002 782 -797 -716 1893 2109 2958 1024 2858 811 2578 1126 1799 -226 1895 700 1648 1052 2343 4781 -2534 2063 -747 -1151 253 481 -998 -722 -245 -3085 532 -497 -546 -3337 -3332 -1021 -1739 -1436 -1293 664 603 881 82 1001 -1499 738 1285 1324 431 224 1223 657 -814 -2463 -393 -59 -1168 -841 -468 -285 -18 -742 228 419 -412 605 155 -17 -250 -534 757 -281 348 -1156 426 881 1419 994 142 4 1819 195 -558 463 246 389 1003 667 -556 208 574 907 -2045 -94 -917 -1076 -1255 954 -1619 485 -889 -1342 -602 -1239 -208 -1241 -33 -20 -217 -2201 -25 -187 824 -159 -1028 -279 91 2009 -294 453 -703 49 -535 151 322 854 1210 -807 1516 472 -662 -1205 19 -936 -1023 -433 -564 -13 -528 -166 -442 1353 -1493 371 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