File name: Pandora208s1_Windsor-West_20230730_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20230802T090715.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20230730_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20230730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230730T111827.2Z 8611.471148 123 1 47.66 2 81.30 72.86 130.07 265.75 0.00 1 0.00 1 0 25 7.297e-01 1.349e-01 5.460e-01 1.278e-01 7.712597e-01 7.511957e-02 8.805244e-03 -6.000000e+00 4.499364e-01 232.39 -2.00 3.53 -2.00 320.41 0.00e+00 -3.627978e-03 1.702401e-02 3.941940e-03 -6.000000e+00 2.351329e-02 288.13 -2.00 20.00 -2.00 319.58 0.00e+00 6.233 0.004 302.00 328.00 3 4.7958e+00 2.1798e-01 7.6440e-02 -6.0000e+00 1.1353e+00 1.5329e+00 2.5259e-01 5.0218e-02 -6.0000e+00 1.2297e+00 -1.5681e+00 1.4394e-01 1.8651e-02 -6.0000e+00 7.3087e-01 6.3940e-01 7.5132e-02 8.8260e-03 -6.0000e+00 3.1988e-01 2.8250e-06 -3.5460e-04 3.6507e-03 4.8301e-05 -6.0000e+00 2.1859e-02 -1.3727e-02 8.8424e-04 12 8 8 10 0 0 99.80 19.24 4.55 -0.01373 -0.01639 13 4 1 5 0 3665.730 22.61 15.01 19.24 27.11 13.0 1011.81 900000 900000 900000 111721 -68196 60885 -17991 -36822 211973 81248 900000 900000 900000 900000 46430 45744 900000 900000 81802 900000 -35199 900000 205058 900000 -51953 25385 36292 -70255 900000 900000 -45216 109389 900000 -39492 268585 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-4638 -5830 9287 16047 3965 11932 -30220 19458 9259 12726 13038 9536 1370 -6732 17462 11462 3667 -399 13387 -1011 -8685 -16793 -1477 -8408 5775 -15116 658 -1055 19619 9971 8930 -5820 11017 16758 -16628 -20907 4632 100 -1894 -6243 13788 2820 16861 -9875 -20045 -4299 -5699 2257 6976 8872 11190 8698 15966 -14716 4571 22154 -5924 2102 -20845 -9564 -9551 10869 21699 18940 4301 -3796 -11759 -6842 -1549 2270 -118 -13456 -6580 1214 8416 -14525 4487 -1784 111 -3157 26889 6269 986 -19212 2051 SS 20230730T125735.7Z 8611.539997 177 1 2.86 2 63.27 88.76 147.27 283.40 0.00 1 0.00 1 0 17 4.971e-02 1.291e-02 4.017e-02 1.023e-02 2.863242e-01 5.329366e-03 3.359961e-03 -6.000000e+00 2.948602e-02 232.39 -2.00 3.53 -2.00 317.64 0.00e+00 1.059487e-03 8.482018e-04 9.542620e-05 -6.000000e+00 1.305344e-03 288.13 -2.00 20.00 -2.00 316.81 0.00e+00 2.210 0.000 302.00 328.00 3 4.7967e+00 1.4266e-02 2.6490e-02 -6.0000e+00 7.3936e-02 -6.1297e-03 1.6041e-02 1.5093e-02 -6.0000e+00 7.9739e-02 2.9490e-02 9.8377e-03 7.2924e-03 -6.0000e+00 4.7470e-02 -2.0355e-02 4.9213e-03 2.1800e-03 -6.0000e+00 2.0199e-02 3.5106e-04 4.3303e-04 3.0426e-04 2.2992e-05 -6.0000e+00 1.4045e-03 -6.4194e-03 -1.8686e-05 12 9 9 12 1 1 999.00 19.26 0.72 -0.00642 -0.00317 1 9 1 5 0 1340.080 22.71 15.00 19.26 30.46 13.1 1038.94 -14592 -16844 -15190 19087 4515 -4396 -12826 23341 -10485 -801 -7948 2730 -24283 -1614 7096 213 -69 -4862 4745 -3821 4678 2371 9019 -3898 3217 5662 -6780 10496 489 4915 -113 -1240 -798 1433 306 951 224 2027 713 -2619 5070 -7196 151 -2811 1984 202 2495 555 -1307 2503 208 3510 -230 815 -1787 -1401 2987 2044 -216 -582 3092 -83 4343 -396 421 -2389 -266 -68 327 -11 464 1475 -219 1997 -1377 724 -1393 -2543 -479 -1151 -627 -1856 -2105 -2288 -533 -1477 1678 385 1281 440 1425 -1148 -225 746 -445 543 -1522 111 -654 -393 -1381 -501 1495 -211 -443 -1356 -682 85 727 -156 970 678 136 21 -621 1374 1742 88 -460 1729 -823 199 -607 -899 166 229 1652 745 51 -1083 352 -361 -34 1138 -979 449 825 111 -544 -75 -83 -1317 -1382 -1688 -1590 1313 326 -344 -1183 1687 -1171 -84 -899 297 -3782 -245 1129 38 -13 -1002 928 -845 962 500 1850 -964 779 1379 -1838 2248 111 1088 -28 -345 -238 417 85 269 72 722 308 -1280 2471 -3961 83 -1532 1079 111 1322 295 -703 1336 117 2037 -147 541 -1200 -959 1978 1407 -144 -394 2123 -64 3334 -332 338 -1896 -197 -51 259 -10 425 1370 -203 1782 -1162 559 -1018 -1875 -379 -998 -582 -1903 -2205 -2544 -605 -1739 1999 473 1534 518 1578 -1193 -226 757 -480 624 -1922 145 -879 -521 -1714 -592 1712 -263 -573 -1795 -942 118 1070 -239 1523 1053 207 30 -843 1837 2385 126 -688 2627 -1243 301 -893 -1300 227 307 2141 1022 74 -1623 542 -555 -54 1876 -1695 770 1445 199 -966 -132 -140 -2190 SS 20230730T131020.9Z 8611.548853 186 1 5.00 2 60.91 90.90 149.42 286.37 0.00 1 0.00 1 0 17 4.302e-02 1.262e-02 3.354e-02 1.012e-02 2.633328e-01 5.267868e-03 3.160402e-03 -6.000000e+00 2.551413e-02 232.39 -2.00 3.53 -2.00 317.34 0.00e+00 -8.169384e-04 7.694059e-04 2.341076e-04 -6.000000e+00 1.129676e-03 288.13 -2.00 20.00 -2.00 316.50 0.00e+00 2.047 0.000 302.00 328.00 3 5.4830e+00 1.4034e-02 2.4543e-02 -6.0000e+00 6.3976e-02 5.2646e-03 1.5731e-02 1.4054e-02 -6.0000e+00 6.9001e-02 5.9647e-03 9.4219e-03 6.7379e-03 -6.0000e+00 4.1077e-02 -1.9000e-03 4.6431e-03 1.9873e-03 -6.0000e+00 1.7476e-02 2.1587e-04 7.8468e-04 3.0229e-04 2.2462e-05 -6.0000e+00 1.2155e-03 -6.7164e-03 -6.2591e-05 12 9 9 12 1 1 999.00 19.25 0.18 -0.00672 -0.00082 1 5 1 5 0 2408.780 22.61 15.00 19.25 30.85 13.1 1041.65 11378 7294 -4514 -10068 -4619 4931 5214 26822 7689 19146 -9257 -9364 -6468 4926 -7258 397 901 -6766 7916 -3198 7976 -2766 2338 5950 3882 1443 2226 7 -2768 -6014 -2134 3862 -4020 -1674 -2535 -11497 -1643 -2178 -644 -2798 -2612 -97 -643 -1606 4544 871 -577 -2383 2506 2670 3550 2594 -800 1580 -1299 2074 3637 -85 1358 -644 -204 -342 3909 -366 2631 1173 -824 -1335 -168 -93 696 -764 1111 -1245 499 -1299 -2029 -2483 -354 -898 -1064 -2446 -1480 -334 -441 -2973 1658 1735 1923 427 1070 -1089 -350 -58 -42 810 1361 470 -724 402 -969 -1446 -1440 -1370 -751 -313 -282 -73 1386 565 143 660 570 -931 -501 822 197 335 532 66 -32 -119 12 -202 -36 -631 1061 1185 -99 -903 -308 -1162 814 243 664 -81 -279 731 71 -409 230 -1014 1062 759 -529 -1143 -471 454 522 2446 936 2151 -1375 -1403 -1062 824 -1547 85 198 -1676 1758 -821 1846 -715 599 1564 1097 430 642 2 -736 -1670 -610 1123 -1353 -544 -785 -3992 -582 -881 -307 -1490 -1490 -56 -381 -924 2553 503 -330 -1356 1342 1467 2064 1625 -526 1064 -924 1460 2547 -61 946 -462 -153 -267 3154 -307 2134 889 -630 -1039 -137 -82 651 -742 1039 -1130 422 -1046 -1519 -1855 -283 -782 -997 -2527 -1541 -365 -500 -3556 2044 2102 2363 501 1183 -1125 -349 -59 -45 945 1695 619 -979 515 -1206 -1683 -1723 -1693 -956 -416 -393 -103 2041 862 226 1019 857 -1309 -673 1096 262 474 779 102 -47 -179 17 -288 -49 -844 1368 1598 -140 -1321 -465 -1804 1277 392 1094 -139 -477 1289 125 -694 386 -1673 SS 20230730T131526.0Z 8611.552384 189 1 2.34 2 59.97 91.77 150.27 287.64 0.00 1 0.00 1 0 17 1.509e-02 7.195e-03 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