File name: Pandora208s1_Windsor-West_20230803_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20230805T051813.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20230803_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20230803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230803T114309.1Z 8615.488299 216 1 23.92 2 77.50 77.61 82.94 243.73 0.00 1 0.00 1 0 17 3.952e-01 2.227e-02 3.943e-01 1.790e-02 5.714122e-01 9.956920e-03 7.517909e-03 -6.000000e+00 2.356436e-01 232.24 -2.00 3.53 -2.00 320.94 0.00e+00 4.796188e-03 4.423980e-03 5.766125e-03 -6.000000e+00 1.105098e-02 288.21 -2.00 20.00 -2.00 320.28 0.00e+00 4.490 0.002 302.00 328.00 3 4.6751e+00 3.3042e-02 5.9968e-02 -6.0000e+00 5.9026e-01 1.8853e-01 4.2846e-02 4.6659e-02 -6.0000e+00 6.3771e-01 -2.1579e-01 3.8390e-02 2.0920e-02 -6.0000e+00 3.8052e-01 8.3533e-02 1.8679e-02 4.7020e-03 -6.0000e+00 1.6207e-01 3.0787e-05 4.8224e-05 5.4869e-04 1.0380e-04 -6.0000e+00 1.1480e-02 -2.4937e-03 -1.9525e-04 12 9 9 12 1 1 99.54 19.28 1.07 -0.00249 -0.00213 7 4 1 5 0 2967.550 22.71 14.98 19.28 26.14 13.0 1002.46 -12791 -87826 900000 900000 55777 -35977 -150736 -17773 -92243 -30691 51209 5566 -162301 900000 -53103 900000 -23798 59618 239031 30820 39585 -20384 -26918 124550 900000 29083 15995 -5897 39295 96298 59242 106214 -1868 -29708 -5540 60025 5964 62326 123 19069 30599 1635 9715 28760 2060 -18757 40004 -13407 66975 9672 -6361 -3305 7601 15849 14914 6932 -8319 9877 2645 4860 4709 11514 7280 4058 4541 5997 -1796 -11839 -185 -1468 10571 -5342 -1941 3341 -6150 2421 -7123 7785 -6314 -6679 -5496 1704 -16 -2113 639 -2349 -2419 -606 -1804 1078 4068 -445 5468 -1806 -131 3366 1755 681 1188 -769 -560 -3897 -3544 -1951 -3020 -288 -417 -1749 2110 1136 1857 -94 3516 -1486 -673 -232 -930 21 2018 183 986 1190 983 -1098 -1773 1698 -668 -363 2079 -1077 118 -1656 -681 -591 -595 468 1396 179 -409 -537 118 265 -223 -1532 900000 900000 973 -627 -4062 -310 -1762 -535 893 97 -9520 900000 -1676 900000 -711 1040 4168 640 756 -711 -1051 2172 900000 749 465 -206 925 1679 1498 1945 -107 -2270 -317 1936 374 2663 11 1663 2721 195 1113 2909 263 -3006 3802 -2126 5197 1434 -1167 -645 1439 3095 3056 1508 -2128 2170 611 1110 1150 2932 2171 1348 1497 1877 -606 -4434 -73 -630 4516 -2586 -921 1398 -2558 840 -2621 2606 -2802 -3482 -3244 1040 -11 -1522 480 -1832 -1962 -489 -1516 829 2816 -303 3456 -1315 -106 3041 1756 763 1364 -863 -604 -3958 -3486 -1999 -3341 -327 -504 -2194 2807 1683 2913 -153 5323 -2234 -950 -321 -1342 32 3160 296 1548 1801 1512 -1649 -2575 2292 -930 -550 3430 -1913 220 -3306 -1416 -1307 -1394 1119 3368 439 -984 -1227 253 547 SS 20230803T114843.7Z 8615.492172 219 1 47.32 2 76.49 78.50 83.82 244.71 0.00 1 0.00 1 0 17 3.884e-01 9.323e-03 2.036e-01 4.783e-03 5.501303e-01 2.632393e-03 6.517171e-03 -6.000000e+00 2.324300e-01 232.24 -2.00 3.53 -2.00 320.89 0.00e+00 5.848185e-03 1.145396e-03 1.598019e-03 -6.000000e+00 1.040264e-02 288.21 -2.00 20.00 -2.00 320.22 0.00e+00 4.177 0.001 302.00 328.00 3 3.2886e+00 8.6903e-03 5.0856e-02 -6.0000e+00 5.8235e-01 6.4290e-02 1.1316e-02 3.0264e-02 -6.0000e+00 6.2861e-01 -5.0782e-02 1.0406e-02 1.7650e-02 -6.0000e+00 3.7237e-01 7.2997e-03 5.0872e-03 7.9903e-03 -6.0000e+00 1.5771e-01 1.7236e-04 -6.8792e-05 1.4610e-04 9.8512e-05 -6.0000e+00 1.1155e-02 -4.5534e-03 -5.7218e-05 11 8 0 10 0 0 96.75 19.27 0.57 -0.00455 -0.00507 80 22 1 5 0 591.330 22.71 15.01 19.27 26.50 13.1 1005.46 -39272 -129840 297335 -152870 900000 -133568 900000 -64123 -25436 -26264 -69679 -11881 -65850 94290 -60107 116540 -37986 33283 -23067 17522 1340 18784 9184 -40788 54345 -30573 -2310 -7274 -11733 -9141 -612 12409 -12388 9004 -15478 8112 -17682 20808 -1734 3280 -1372 -52 2962 889 5554 -3155 6280 -3780 7660 -2463 10481 3963 1220 6697 3500 1976 -6225 4582 -4255 2145 -3102 3091 1253 2481 3872 -1372 1833 -1601 3027 311 1853 -75 4225 -122 1770 1545 -3332 626 -3785 710 -3064 907 -2663 -472 -1379 -296 664 289 1347 -1080 2046 -573 992 -140 -422 -113 267 368 -524 42 -899 -198 -2014 71 -1807 -978 -834 -599 486 455 448 84 629 -690 247 -304 770 128 266 -284 -468 465 -200 1155 245 723 125 1037 304 -155 108 -558 63 -270 402 -453 424 -12 65 -90 -325 -231 -231 -2167 1386 -3226 900000 -2163 900000 -629 -187 -206 -889 -99 -1196 464 -1622 664 -1072 506 -662 353 32 383 216 -1691 971 -1260 -72 -232 -419 -355 -26 537 -733 464 -927 418 -1267 1283 -154 321 -155 -6 356 112 683 -434 801 -549 1034 -396 1641 728 250 1390 781 462 -1601 1043 -1040 498 -811 849 395 836 1288 -463 595 -564 1148 137 863 -36 1901 -54 730 580 -1259 239 -1727 363 -1765 559 -1818 -335 -1059 -239 552 245 1110 -860 1465 -416 695 -106 -341 -105 282 431 -639 49 -973 -194 -1944 71 -1966 -1111 -1005 -773 681 703 737 140 1014 -1063 356 -434 1121 199 436 -477 -772 734 -307 1674 344 971 169 1510 498 -279 206 -1126 133 -606 903 -1062 1004 -30 152 -213 -728 -496 SS 20230803T115945.8Z 8615.499836 222 1 47.07 2 74.49 80.26 85.58 246.62 0.00 1 0.00 1 0 25 1.224e-01 5.018e-03 5.199e-02 2.059e-03 4.892310e-01 1.114696e-03 5.681937e-03 -6.000000e+00 7.258423e-02 232.24 -2.00 3.53 -2.00 320.36 0.00e+00 4.119826e-03 4.094798e-04 6.367529e-04 -6.000000e+00 3.216357e-03 288.21 -2.00 20.00 -2.00 319.63 0.00e+00 3.671 0.001 302.00 328.00 3 2.5674e+00 3.4522e-03 4.4680e-02 -6.0000e+00 1.8193e-01 2.0416e-02 4.2813e-03 2.6473e-02 -6.0000e+00 1.9624e-01 -2.7778e-03 3.6862e-03 1.4299e-02 -6.0000e+00 1.1684e-01 -1.1842e-02 1.8588e-03 6.4091e-03 -6.0000e+00 4.9731e-02 6.1890e-04 4.3536e-04 6.3278e-05 6.7090e-05 -6.0000e+00 3.4594e-03 -5.6783e-03 -1.4987e-05 11 1 0 11 8 0 65.41 19.30 0.40 -0.00568 -0.00241 180 49 1 5 0 261.470 22.71 14.99 19.30 27.34 13.1 1012.29 -30584 -43675 -40799 -42800 -56731 -49861 -34444 -49827 -29675 -37825 -28289 -17531 -12981 -13716 -12054 -5655 -11838 -7253 -2774 -530 1232 -3471 -2769 -1964 -6481 -4013 -3284 -9189 -3446 -5683 485 336 -251 -1649 -1412 -6692 -4652 -895 -2200 -1324 -1070 -1693 -601 340 819 -684 -178 -298 1746 171 1900 1442 1928 550 74 1044 545 73 -770 337 534 1959 2219 1350 1763 1083 542 492 805 394 1139 392 211 45 363 -199 -1741 -729 -1343 -1699 -1349 -2398 -1590 -865 -431 300 522 590 1046 668 1277 312 121 -11 123 653 713 182 -279 -435 -828 -758 -245 -863 -1150 -973 -524 -505 221 409 230 184 167 -130 211 -91 269 89 0 -326 -70 -4 260 435 150 65 659 331 274 224 48 -281 160 -198 82 88 179 -41 -83 -191 -130 -236 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