File name: Pandora208s1_Windsor-West_20231012_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20231013T161958.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20231012_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20231012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231012T155553.4Z 8685.663813 240 1 47.05 2 53.24 154.02 38.81 179.51 0.00 1 0.00 1 0 17 1.631e-02 7.906e-03 1.278e-02 4.897e-03 2.043986e-01 2.483652e-03 2.506728e-03 -6.000000e+00 9.437974e-03 225.99 -2.00 3.53 -2.00 317.14 0.00e+00 9.063770e-04 3.396299e-04 4.828170e-05 -6.000000e+00 4.185732e-04 282.64 -2.00 20.00 -2.00 316.41 0.00e+00 1.667 0.000 302.00 328.00 3 6.3453e+00 6.5093e-03 1.9403e-02 -6.0000e+00 2.3348e-02 5.8441e-02 7.3211e-03 1.0606e-02 -6.0000e+00 2.5336e-02 6.8583e-04 4.3221e-03 5.2234e-03 -6.0000e+00 1.5111e-02 -5.5269e-03 2.0889e-03 1.6149e-03 -6.0000e+00 6.4738e-03 1.4358e-04 2.0794e-05 1.4733e-04 1.8631e-05 -6.0000e+00 4.6029e-04 -3.5047e-04 -1.2933e-04 11 8 0 10 0 0 99.79 19.05 0.29 -0.00035 -0.00019 25 7 1 5 0 1881.660 22.50 15.00 19.05 21.67 14.3 963.81 -3506 -2412 4460 -5712 -2872 -4358 -721 -4870 -3786 -1750 -3128 -3064 -2743 3626 -3529 2508 -2443 3506 -2624 2407 3539 2537 384 -273 2603 -2359 957 -69 480 1006 501 15 -1782 173 -1739 -2672 -2284 919 -2131 36 337 -413 -1015 99 933 35 796 -1811 504 542 1592 1036 494 1799 511 362 666 1071 606 831 1279 1587 1984 450 -71 -1342 381 457 740 -759 1116 34 493 542 -973 -744 -1896 66 -1852 -1067 -1614 -2874 -1771 -952 -799 -197 555 70 1089 263 840 -368 -219 25 -273 -267 1287 656 -1142 -228 -752 -831 -124 -553 -222 -949 -424 -623 612 899 556 599 -226 -27 249 -236 -600 476 329 -209 -343 428 811 325 341 322 -14 -7 872 327 363 -294 243 -180 273 689 -14 2 52 -434 -1330 -262 -518 -373 673 -867 -380 -574 -98 -770 -643 -297 -528 -540 -538 756 -882 629 -662 922 -757 678 988 711 113 -85 815 -791 301 -20 133 277 146 5 -601 56 -539 -903 -813 373 -1055 20 196 -249 -628 61 564 21 462 -1044 278 304 933 646 325 1213 355 256 472 745 417 578 930 1241 1653 391 -59 -1027 286 344 610 -669 1029 33 458 477 -841 -575 -1360 46 -1420 -910 -1531 -2819 -1804 -1017 -916 -238 695 89 1353 309 949 -382 -212 24 -287 -310 1536 849 -1522 -287 -935 -966 -142 -684 -293 -1249 -580 -891 912 1405 892 937 -334 -39 329 -303 -795 663 494 -310 -512 658 1198 457 455 408 -17 -10 1189 472 540 -446 377 -296 470 1154 -23 4 90 -771 -2308 -437 SS 20231012T164140.0Z 8685.695602 268 1 48.37 2 50.49 168.03 40.20 197.10 0.00 1 0.00 1 0 17 1.150e-02 7.538e-03 9.066e-03 3.838e-03 1.972819e-01 1.955702e-03 2.400976e-03 -6.000000e+00 6.655126e-03 225.99 -2.00 3.53 -2.00 316.79 0.00e+00 6.994563e-04 2.466629e-04 1.126461e-04 -6.000000e+00 2.951230e-04 282.63 -2.00 20.00 -2.00 316.07 0.00e+00 1.569 0.000 302.00 328.00 3 6.2632e+00 5.1002e-03 1.8360e-02 -6.0000e+00 1.6464e-02 6.8357e-02 5.7189e-03 1.0106e-02 -6.0000e+00 1.7865e-02 -4.1341e-03 3.3440e-03 4.9903e-03 -6.0000e+00 1.0655e-02 -5.0397e-03 1.5934e-03 1.4750e-03 -6.0000e+00 4.5655e-03 1.7337e-04 3.0773e-04 1.1553e-04 1.7416e-05 -6.0000e+00 3.2450e-04 -9.9865e-04 -1.1328e-04 11 8 0 10 0 0 99.94 19.03 0.27 -0.00100 0.00131 18 5 1 5 0 2686.780 22.50 15.01 19.03 23.53 14.4 978.51 1189 276 -3207 -2578 -434 -1314 2980 327 178 -3582 -4084 -3305 -2177 -292 368 -301 402 -253 901 235 102 139 1997 271 1564 1537 1044 1177 199 -900 132 1141 448 -2209 -685 -2787 -1721 -1679 -145 -638 -135 -760 -1390 -388 -511 53 -257 1561 -593 567 766 255 236 722 435 726 442 841 169 809 1711 1088 1795 1116 451 517 -1584 380 1262 497 951 592 781 1 -1012 -526 -1620 -1903 -1664 -2329 -1080 -2501 -1423 -1041 -936 86 80 1271 685 586 156 -1017 -544 207 -308 421 1157 385 -471 -377 -473 -1384 -399 -496 -553 -834 -79 -519 330 592 914 612 -98 -347 -77 -558 303 -257 601 -329 448 674 857 513 -351 172 231 108 -62 92 -96 -805 90 237 155 595 321 543 -190 -344 -902 -728 203 50 -595 -431 -64 -191 445 56 33 -701 -787 -658 -478 -71 99 -87 118 -77 277 75 33 44 638 92 545 546 361 376 60 -276 42 384 160 -793 -227 -963 -658 -755 -76 -378 -84 -495 -927 -256 -336 34 -161 927 -352 338 481 170 165 520 320 541 332 620 123 594 1308 901 1577 1011 390 406 -1195 283 1022 451 916 584 755 1 -861 -399 -1221 -1416 -1337 -1969 -997 -2529 -1494 -1151 -1112 107 104 1659 882 709 173 -1034 -513 195 -315 471 1419 513 -638 -486 -567 -1564 -446 -595 -709 -1124 -111 -758 504 948 1491 973 -147 -478 -98 -691 383 -346 864 -497 675 993 1215 691 -454 209 294 134 -81 127 -138 -1174 133 369 256 1008 558 955 -331 -584 -1488 -1166 SS 20231012T165203.1Z 8685.702814 271 1 46.04 2 50.15 171.35 40.86 200.89 0.00 1 0.00 1 0 17 2.226e-02 9.981e-03 1.334e-02 5.463e-03 1.993473e-01 2.778730e-03 2.443879e-03 -6.000000e+00 1.288177e-02 225.99 -2.00 3.53 -2.00 316.90 0.00e+00 9.817727e-05 3.579426e-04 1.845284e-04 -6.000000e+00 5.711907e-04 282.63 -2.00 20.00 -2.00 316.17 0.00e+00 1.557 0.000 302.00 328.00 3 6.6025e+00 7.2633e-03 1.8353e-02 -6.0000e+00 3.1868e-02 7.3488e-02 8.1521e-03 1.0259e-02 -6.0000e+00 3.4578e-02 -3.6314e-03 4.7781e-03 5.0514e-03 -6.0000e+00 2.0623e-02 -3.8591e-03 2.2883e-03 1.4329e-03 -6.0000e+00 8.8376e-03 1.2419e-04 3.4579e-04 1.6405e-04 1.7815e-05 -6.0000e+00 6.2799e-04 -9.2628e-04 -8.1112e-05 12 8 8 10 0 0 99.87 19.05 0.11 -0.00093 0.00167 19 5 1 5 0 2422.860 22.50 14.99 19.05 23.91 14.4 981.78 -2390 2526 -2918 -3836 4661 -1152 7317 868 5496 -12166 1638 -3702 -2165 -840 1990 2599 -2074 6741 -460 4654 -2713 -717 518 1747 3710 -978 4069 -3762 1659 -880 940 3687 743 -2066 -6474 -2760 -5335 697 -2955 -1008 -1184 1148 -529 264 -1102 -1017 -267 -1972 370 -1272 725 466 1738 1652 603 1997 -1349 2255 481 2085 -698 2693 1121 947 -26 -964 277 30 3164 -791 1321 -466 740 113 359 -238 -2273 -513 -2668 -641 -1947 -926 -1704 -759 19 -435 280 391 920 229 1134 -1130 673 -850 -295 -314 841 1364 445 -121 -940 -1126 -1797 -76 -1183 -463 -1071 -471 1230 277 1019 -97 230 -956 -331 -1151 484 577 406 -17 481 517 857 759 -186 541 141 88 -124 -351 642 -953 413 -373 637 -83 426 132 -211 -83 -938 -191 -392 416 -501 -603 635 -163 1026 145 952 -2565 295 -731 -467 -201 515 710 -608 1862 -140 1386 -871 -224 165 577 1249 -352 1349 -1246 488 -264 292 1184 259 -726 -2227 -934 -2073 300 -1563 -590 -739 722 -344 170 -714 -649 -163 -1188 212 -755 446 303 1171 1157 434 1442 -1012 1609 344 1482 -535 2147 970 841 -22 -753 201 22 2459 -713 1242 -455 700 102 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