File name: Pandora208s1_Windsor-West_20231220_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20240202T190934.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20231220_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20231220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231220T133229.5Z 8754.564230 80 1 47.58 2 85.49 127.66 132.44 28.03 0.00 1 0.00 1 0 41 7.621e-01 1.305e-01 5.818e-01 1.122e-01 1.073846e+00 6.557645e-02 1.264600e-02 -6.000000e+00 4.509085e-01 222.62 -2.00 3.53 -2.00 320.91 0.00e+00 -1.539589e-03 1.516843e-02 3.975550e-03 -6.000000e+00 1.999647e-02 274.70 -2.00 20.00 -2.00 320.35 0.00e+00 10.594 0.022 302.00 328.00 3 -9.1252e-02 1.8783e-01 1.1827e-01 -6.0000e+00 1.1113e+00 2.9930e+00 2.1503e-01 5.4745e-02 -6.0000e+00 1.2139e+00 -2.5164e+00 1.2049e-01 2.5895e-02 -6.0000e+00 7.2065e-01 7.3476e-01 6.6291e-02 7.8335e-03 -6.0000e+00 3.0711e-01 3.6691e-06 3.2108e-03 2.8204e-03 1.2441e-04 -6.0000e+00 2.2413e-02 -4.6344e-03 1.0707e-04 12 8 8 10 0 0 -1.27 19.25 1.63 -0.00463 0.01949 24 6 1 5 0 1982.160 22.71 15.01 19.25 4.49 14.0 880.08 374666 900000 161793 112771 -37132 89448 -84802 900000 32429 75620 87567 900000 115721 165128 900000 462 50271 71649 46391 11305 -25538 140196 51154 51471 13399 69630 -613 -8115 -18811 -1586 -3687 25707 900000 -50484 85064 -19868 900000 -7859 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6694 18462 4682 9245 4856 7478 -9255 900000 2231 -18225 12617 13854 17815 -1769 13991 -4242 -6297 8007 15805 -10138 -3890 14724 10401 2954 152 1495 2553 -3429 164 13955 8277 20022 11805 3388 7653 -20345 11998 -50938 7303 1345 -6162 -11496 6317 13128 20040 17739 2707 -4924 -6592 7670 -2468 -18097 6456 -8088 6159 2414 5792 1262 9992 -4361 9108 -7073 5379 -15637 10976 -294 10589 6133 -28230 -7453 2136 10528 -6998 8887 1253 7765 SS 20231220T134419.8Z 8754.572452 83 1 47.27 2 83.78 129.78 131.35 31.54 0.00 1 0.00 1 0 25 5.358e-01 2.594e-02 4.865e-01 1.977e-02 9.994974e-01 1.218129e-02 1.100446e-02 -6.000000e+00 3.199201e-01 222.62 -2.00 3.53 -2.00 322.50 0.00e+00 9.523701e-03 7.078372e-03 1.877660e-03 -6.000000e+00 1.445371e-02 274.70 -2.00 20.00 -2.00 322.12 0.00e+00 8.309 0.011 302.00 328.00 3 6.1791e-01 4.8067e-02 9.8976e-02 -6.0000e+00 7.9315e-01 1.3143e+00 6.4448e-02 6.0256e-02 -6.0000e+00 8.6940e-01 -1.7158e+00 5.9281e-02 3.0853e-02 -6.0000e+00 5.1047e-01 6.8792e-01 2.8040e-02 1.3708e-02 -6.0000e+00 2.1649e-01 3.0189e-05 -1.4506e-03 5.8099e-04 2.3088e-04 -6.0000e+00 1.5888e-02 -2.4405e-03 4.1779e-05 12 8 8 10 0 0 22.09 19.22 0.81 -0.00244 -0.01334 97 26 1 5 0 487.250 22.61 15.00 19.22 4.89 14.0 883.64 32709 -48520 -11671 -67207 -146869 900000 -176770 900000 -135452 900000 -90737 -23877 20876 98153 68552 -19732 900000 17634 900000 45374 900000 -76910 900000 3861 -24270 -41763 -6990 147347 -95526 900000 25555 900000 7611 900000 -2431 161221 -69 26109 900000 22422 83743 55926 148794 43405 900000 13028 80910 900000 15810 61758 40115 261885 53718 129216 35907 84932 16208 18274 35169 3168 119949 -546 51184 26940 51685 11773 53584 31712 32042 14482 17769 22170 26033 45208 4702 23836 -8231 40731 196 3138 16491 -2596 4883 -1062 13 -2957 12962 993 7047 -3673 4714 2706 -9160 -4951 -4432 1171 -4583 -183 -3694 -1974 -357 -1442 -4252 -6274 -1546 -6965 92 -6382 1394 -891 -1210 -2086 -490 -585 -3003 -318 -713 3504 -368 4031 873 4062 2999 2011 2411 -1811 894 -1086 2338 -460 1827 -449 560 -570 -632 1025 -157 1084 -616 -502 -1217 -1022 629 -1017 -224 -1409 -5647 900000 -7723 900000 -3787 900000 -1744 -459 401 1887 1318 -483 900000 339 900000 872 900000 -3091 900000 74 -551 -1095 -134 2832 -3840 900000 491 900000 213 900000 -68 3099 -2 703 900000 819 1771 1613 2860 1418 900000 576 1866 900000 790 2137 1928 5034 2685 3229 2347 3429 1277 1335 2028 244 2998 -51 3345 2538 3974 1358 4223 3353 3819 2311 2903 3452 3653 4693 642 2428 -1155 3915 34 652 3551 -773 1464 -357 5 -1120 4311 374 2438 -1334 1477 843 -3346 -1970 -2104 635 -3136 -138 -3061 -1564 -253 -909 -2550 -3944 -987 -4968 66 -5496 1292 -988 -1524 -2828 -664 -779 -3983 -410 -957 4756 -539 5586 1185 5052 3643 2393 2785 -2138 1064 -1516 3744 -874 3789 -1035 1376 -1526 -1796 2943 -459 3129 -1736 -1306 -2922 -2291 SS 20231220T135516.5Z 8754.580053 86 1 47.29 2 82.25 131.78 130.25 34.68 0.00 1 0.00 1 0 25 5.697e-01 1.814e-02 3.443e-01 7.270e-03 8.844294e-01 4.190864e-03 9.801058e-03 -6.000000e+00 3.266548e-01 222.62 -2.00 3.53 -2.00 322.16 0.00e+00 1.450843e-02 2.361521e-03 2.685965e-03 -6.000000e+00 1.455329e-02 274.70 -2.00 20.00 -2.00 321.75 0.00e+00 6.910 0.006 302.00 328.00 3 6.7207e-01 1.5658e-02 8.8108e-02 -6.0000e+00 8.0624e-01 7.2774e-01 2.3067e-02 6.8936e-02 -6.0000e+00 8.7884e-01 -9.6587e-01 2.4503e-02 2.8363e-02 -6.0000e+00 5.2093e-01 3.8994e-01 1.1243e-02 1.7869e-02 -6.0000e+00 2.2318e-01 1.2545e-04 -5.1128e-04 2.0683e-04 2.3062e-04 -6.0000e+00 1.6090e-02 -2.4992e-03 2.7665e-05 12 8 8 10 0 0 39.65 19.24 0.38 -0.00250 -0.00634 205 55 1 5 0 230.640 22.71 15.00 19.24 5.39 14.0 887.24 -247748 46077 -178415 -45393 -153246 -193809 -12501 -129154 900000 -217462 -27362 -209477 -21790 -108403 82423 -63740 -47373 27098 -58602 900000 -15360 900000 -84980 100185 -42829 -50803 46715 -74491 10458 -40084 60661 -56260 117875 -32115 -8684 -9325 30834 1155 47645 147611 6262 153950 11057 52932 12283 63845 10132 42629 42960 20640 73647 31063 61841 12476 41716 12958 32233 17698 15228 20302 15224 29541 10000 25478 13730 24560 14215 13012 9067 8478 13884 8552 17851 2054 8687 -1757 3173 -4184 3137 -2518 3383 679 -1073 121 49 2888 -2197 2337 35 2738 -577 -895 -2263 -2902 -1224 -3853 128 -2971 -234 -1050 -1102 -57 -2781 -2217 -4164 73 -3763 -125 -2679 431 -907 -891 -180 -912 -39 -553 420 -225 886 -100 2045 913 1909 1684 649 1971 945 1162 232 945 -69 638 71 21 110 -106 477 -267 77 -605 -91 -1590 -7979 326 -3333 -322 -1777 -3121 -89 -1081 900000 -4482 -194 -5127 -154 -1815 584 -1067 -763 250 -1208 900000 -218 900000 -2080 710 -759 -972 331 -1742 111 -852 602 -2192 919 -1138 -228 -244 590 34 1046 1360 257 1527 478 1538 548 1764 503 1631 1765 1170 2765 1981 3155 1114 2867 1203 2444 1492 1262 1597 1348 2595 1247 3069 1936 3115 2065 2056 1690 1790 2951 1921 3453 422 1483 -304 522 -824 693 -715 1066 250 -433 51 22 1322 -1094 1123 17 1210 -247 -371 -978 -1417 -697 -2697 102 -2781 -224 -980 -936 -42 -1990 -1633 -3331 59 -3423 -121 -3071 551 -1308 -1348 -271 -1342 -54 -779 607 -346 1400 -159 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