File name: Pandora208s1_Windsor-West_20231226_L2Fit_fwvt1c4d20220407p1-8.txt File generation date: 20240113T075005.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20231226_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20231226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1623 1772 Nominal wavelengths inside fitting window [nm]: 492.0606 492.1820 492.3034 492.4247 492.5461 492.6674 492.7888 492.9101 493.0314 493.1527 493.2739 493.3952 493.5164 493.6376 493.7588 493.8800 494.0011 494.1223 494.2434 494.3645 494.4856 494.6067 494.7277 494.8488 494.9698 495.0908 495.2118 495.3328 495.4537 495.5747 495.6956 495.8165 495.9374 496.0583 496.1791 496.3000 496.4208 496.5416 496.6624 496.7832 496.9039 497.0247 497.1454 497.2661 497.3868 497.5075 497.6282 497.7488 497.8694 497.9900 498.1106 498.2312 498.3518 498.4723 498.5928 498.7133 498.8338 498.9543 499.0748 499.1952 499.3156 499.4360 499.5564 499.6768 499.7972 499.9175 500.0378 500.1581 500.2784 500.3987 500.5190 500.6392 500.7594 500.8796 500.9998 501.1200 501.2402 501.3603 501.4804 501.6005 501.7206 501.8407 501.9607 502.0808 502.2008 502.3208 502.4408 502.5608 502.6807 502.8007 502.9206 503.0405 503.1604 503.2802 503.4001 503.5199 503.6398 503.7596 503.8793 503.9991 504.1189 504.2386 504.3583 504.4780 504.5977 504.7174 504.8370 504.9567 505.0763 505.1959 505.3155 505.4350 505.5546 505.6741 505.7936 505.9131 506.0326 506.1521 506.2715 506.3909 506.5104 506.6297 506.7491 506.8685 506.9878 507.1072 507.2265 507.3458 507.4650 507.5843 507.7035 507.8228 507.9420 508.0612 508.1804 508.2995 508.4187 508.5378 508.6569 508.7760 508.8950 509.0141 509.1331 509.2522 509.3712 509.4902 509.6091 509.7281 509.8470 509.9659 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231226T173736.6Z 8760.734451 429 1 48.32 2 65.66 181.20 110.31 4.53 0.00 1 0.00 1 0 15 3.359e-03 3.370e-03 1.753e-03 1.744e-03 2.445521e+03 1.059510e+02 1.774001e+02 -6.000000e+00 1.849322e+02 274.32 -2.00 20.00 -2.00 505.24 0.00e+00 4.040877e-04 4.725655e-05 2.529259e-05 -6.000000e+00 9.327824e-05 274.32 -2.00 20.00 -2.00 500.23 0.00e+00 1.319498e-01 3.510306e-02 1.969476e-02 -6.000000e+00 6.717171e-02 222.84 -2.00 3.53 -2.00 501.86 0.00e+00 2.410 0.000 489.00 513.00 1 7.0781e+00 2.6847e-03 3.8051e-03 -6.0000e+00 5.1468e-03 1.5700e-02 6.8900e-04 4.9876e-04 -6.0000e+00 1.3216e-03 1.1601e-03 1.4241e-04 1.8374e-04 2.3325e-05 -6.0000e+00 3.6755e-04 -6.7248e-04 -1.3535e-06 10 0 0 10 0 0 93.25 19.34 1.47 -0.00067 0.00032 13 4 1 4 0 3715.850 22.71 15.00 19.34 18.27 15.2 1003.33 -403 -652 -53 -195 398 276 636 137 677 -4 -39 74 -485 -157 -228 5 -294 248 31 142 251 248 449 441 143 -152 395 -100 -99 -210 -501 -628 -303 669 27 -93 -183 97 -274 -97 189 100 110 254 531 567 -91 208 -193 -333 -524 -867 -864 -867 -466 -328 7 -5 16 385 75 792 221 136 730 375 427 108 -66 -189 293 -215 -285 -562 -66 -26 -370 -584 -369 -200 -335 -247 -474 -1 110 108 -373 102 111 264 122 -53 485 272 11 -55 -49 -14 -74 27 -687 -373 -254 -30 -22 -142 -439 -389 -386 -228 139 138 287 55 -13 500 537 632 430 273 263 320 41 319 84 22 -342 228 -157 -194 59 -261 346 -303 -83 -197 285 -49 121 48 252 241 37 -29 511 -238 -193 -95 -312 -324 -401 -658 -54 -199 415 295 687 150 735 -4 -42 78 -505 -160 -233 5 -306 262 33 155 276 273 494 486 159 -168 434 -108 -105 -216 -511 -645 -317 713 28 -98 -193 101 -295 -104 201 107 114 266 558 596 -95 214 -196 -344 -528 -858 -849 -862 -472 -327 7 -5 16 392 77 806 226 140 736 374 420 104 -64 -180 288 -204 -274 -548 -64 -25 -353 -550 -344 -185 -313 -232 -451 -1 106 105 -365 99 108 258 121 -53 488 274 11 -54 -47 -13 -68 24 -627 -346 -243 -30 -22 -142 -435 -382 -378 -225 138 134 281 54 -13 496 534 625 422 264 251 302 39 301 80 21 -326 216 -148 -183 55 -240 324 -285 -78 -181 266 -46 117 46 246 236 37 -29 499 -231 -183 -89 -288 -299 SQ 20231226T174605.2Z 8760.740338 435 1 6.20 2 65.72 183.33 110.17 6.43 0.00 1 0.00 1 0 15 2.341e-03 2.350e-03 1.362e-04 1.358e-04 1.717817e+03 7.991637e+00 1.342578e+02 -6.000000e+00 1.289098e+02 274.32 -2.00 20.00 -2.00 505.26 0.00e+00 4.026727e-04 3.699244e-06 2.360837e-05 -6.000000e+00 6.502185e-05 274.32 -2.00 20.00 -2.00 500.35 0.00e+00 1.510730e-01 2.724638e-03 1.284598e-02 -6.000000e+00 4.682544e-02 222.84 -2.00 3.53 -2.00 501.96 0.00e+00 2.415 0.000 489.00 513.00 1 2.8425e-01 2.0870e-04 3.5972e-03 -6.0000e+00 3.5878e-03 7.5597e-03 5.3376e-05 3.6604e-04 -6.0000e+00 9.2133e-04 1.0345e+00 2.1563e-04 1.4410e-05 1.9761e-05 -6.0000e+00 2.5621e-04 -7.1088e-04 -5.0766e-06 10 0 0 10 0 0 96.91 19.34 1.50 -0.00071 0.00078 1207 327 1 4 0 4.820 22.71 15.00 19.34 18.73 15.2 1007.21 -448 -315 -217 4 193 356 443 374 358 292 134 -40 -110 -106 -166 -80 -25 66 172 206 243 291 295 308 360 267 4 -63 -100 -262 -333 -243 -117 -14 -35 -58 -53 -43 -121 -152 -67 -9 62 113 147 155 112 -76 -190 -385 -486 -544 -560 -538 -398 -295 -216 -49 85 256 352 427 356 366 336 308 80 -11 -61 -114 -169 -180 -196 -173 -182 -246 -287 -273 -185 -214 -284 -270 -142 -82 -96 -116 -45 3 8 95 135 162 175 198 230 113 -61 -128 -204 -344 -382 -335 -303 -272 -299 -316 -227 -166 -144 -107 -20 46 225 313 436 385 328 270 167 157 142 145 158 139 46 185 266 149 72 106 32 -43 -84 -137 -76 -11 -55 -46 91 233 243 295 274 157 0 -71 -141 -200 -268 -273 -441 -313 -222 4 200 377 477 407 388 314 143 -41 -114 -108 -168 -81 -26 70 179 216 257 308 312 327 382 284 5 -66 -102 -271 -338 -248 -122 -14 -37 -61 -57 -45 -125 -156 -69 -9 65 119 156 164 118 -79 -194 -384 -490 -538 -549 -533 -389 -296 -221 -50 87 262 361 440 368 377 342 310 80 -11 -60 -109 -162 -173 -190 -170 -179 -240 -276 -259 -174 -201 -268 -257 -137 -79 -94 -114 -44 3 8 94 135 158 173 195 224 113 -59 -122 -191 -318 -354 -317 -296 -263 -294 -310 -220 -160 -137 -103 -19 45 224 315 440 391 334 275 168 156 139 141 152 135 45 180 258 144 69 102 31 -41 -78 -126 -70 -10 -53 -45 90 231 243 296 267 153 0 -70 -137 -191 -253 -258 SQ 20231226T174611.8Z 8760.740414 435 2 6.41 2 65.72 183.36 110.17 6.46 0.00 1 0.00 1 0 15 2.331e-03 2.328e-03 1.663e-04 1.658e-04 1.734409e+03 9.717777e+00 1.354758e+02 -6.000000e+00 1.283521e+02 274.32 -2.00 20.00 -2.00 505.26 0.00e+00 4.118955e-04 4.504851e-06 2.406376e-05 -6.000000e+00 6.474054e-05 274.32 -2.00 20.00 -2.00 500.36 0.00e+00 1.515273e-01 3.321965e-03 1.300797e-02 -6.000000e+00 4.662279e-02 222.84 -2.00 3.53 -2.00 501.97 0.00e+00 2.415 0.000 489.00 513.00 1 5.9660e-01 2.5466e-04 3.6038e-03 -6.0000e+00 3.5723e-03 8.2153e-03 6.5257e-05 3.6916e-04 -6.0000e+00 9.1734e-04 7.5681e-01 2.1601e-04 1.7591e-05 1.9636e-05 -6.0000e+00 2.5510e-04 -1.0086e-03 -3.1390e-06 10 0 0 10 0 0 98.01 19.35 1.49 -0.00101 0.00049 1207 327 1 4 0 4.820 22.71 15.00 19.35 18.73 15.2 1007.21 -445 -317 -168 1 173 360 416 340 347 306 120 -38 -119 -127 -149 -90 -26 62 162 198 210 294 317 314 353 260 24 -84 -118 -264 -350 -248 -135 -11 -20 -83 -20 -19 -133 -115 -57 -16 122 122 152 191 120 -70 -189 -393 -495 -539 -543 -555 -391 -326 -208 -45 110 263 330 411 356 360 349 297 95 -11 -31 -79 -138 -180 -193 -182 -193 -244 -254 -234 -214 -213 -275 -271 -172 -84 -82 -117 -71 9 18 129 131 172 181 226 219 134 -108 -124 -241 -310 -379 -347 -299 -238 -305 -328 -220 -182 -129 -106 -15 51 212 325 414 418 352 273 171 141 147 167 161 144 68 189 266 144 112 119 41 -38 -71 -79 -35 -29 -65 -34 80 192 182 295 276 143 -9 -73 -158 -207 -250 -274 -430 -310 -169 1 176 375 439 362 369 322 125 -39 -121 -127 -155 -90 -26 65 171 212 226 316 341 339 381 281 26 -89 -122 -267 -349 -248 -138 -11 -22 -90 -21 -20 -140 -120 -59 -16 129 125 157 198 124 -74 -196 -398 -489 -522 -522 -539 -389 -333 -216 -45 111 263 331 414 359 362 347 304 96 -11 -31 -77 -134 -175 -190 -181 -193 -242 -249 -226 -204 -203 -265 -262 -168 -82 -78 -112 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