File name: Pandora208s1_Windsor-West_20240217_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20240223T181604.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20240217_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20240217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240217T131923.1Z 8813.555129 131 1 46.88 2 81.64 114.75 110.97 15.72 0.00 1 0.00 1 0 25 7.186e-01 3.222e-02 4.436e-01 2.118e-02 1.254299e+00 1.444470e-02 1.337651e-02 -6.000000e+00 4.411674e-01 224.82 -2.00 3.53 -2.00 322.61 0.00e+00 -6.215956e-03 7.901000e-03 3.171068e-03 -6.000000e+00 2.592454e-02 273.24 -2.00 20.00 -2.00 322.24 0.00e+00 6.472 0.005 302.00 328.00 3 2.2763e+00 5.6168e-02 9.5760e-02 -6.0000e+00 1.1082e+00 1.8973e+00 7.8007e-02 7.5412e-02 -6.0000e+00 1.2226e+00 -2.3903e+00 7.5145e-02 4.3858e-02 -6.0000e+00 7.0725e-01 9.2790e-01 3.6270e-02 1.4995e-02 -6.0000e+00 3.0465e-01 2.0001e-05 -1.0243e-03 5.9733e-04 2.1851e-04 -6.0000e+00 2.3104e-02 -2.9791e-03 3.1684e-05 12 8 8 10 0 0 97.79 19.30 0.98 -0.00298 -0.01068 46 12 1 5 0 1019.080 22.71 15.00 19.30 0.47 14.3 882.98 900000 -6956 900000 900000 900000 -33494 900000 900000 100304 900000 900000 900000 -19873 900000 -39005 900000 37130 900000 900000 900000 900000 53507 900000 -83672 900000 -101871 257046 133859 900000 57099 42115 900000 -63588 900000 26902 900000 145595 900000 315455 900000 224932 46463 332025 -18293 139625 38479 900000 -24944 900000 35172 62638 900000 -3504 157726 23462 900000 -15092 900000 53927 106089 77792 -45378 63151 47230 135127 25229 89663 12522 60803 3880 39594 39506 56760 34491 12902 95523 1151 91374 20062 23930 1818 5517 6714 15858 17826 -3286 12251 -3069 18552 -12073 3132 -15648 -2928 3373 -10081 3358 -1510 1542 -3169 127 -9855 4497 -7758 -4175 -4915 -2895 2714 870 -1230 -4197 -19 -3831 1050 -3176 1888 -1297 2372 1095 1101 4732 -2737 4566 -1000 5107 620 1446 2234 -891 1035 -312 633 -1556 1768 -1565 967 -119 483 70 -212 793 -2527 -55 900000 -190 900000 900000 900000 -687 900000 900000 2059 900000 900000 900000 -519 900000 -1747 900000 901 900000 900000 900000 900000 1098 900000 -5308 900000 -7603 5276 2747 900000 1172 864 900000 -4390 900000 653 900000 2988 900000 6474 900000 4616 1560 6814 -1058 2866 1264 900000 -1489 900000 1516 2314 900000 -275 3237 1734 900000 -1642 900000 2435 2613 2555 -5681 3111 3102 3883 2227 4417 1465 4992 629 4713 4622 5126 3398 1350 3921 123 4501 2470 3487 395 1336 1750 3971 4573 -1072 3470 -1001 4683 -3865 810 -4849 -859 1087 -4531 1606 -908 1038 -2374 89 -6877 2344 -4140 -2176 -2724 -1658 1599 593 -1017 -4281 -21 -4898 1324 -4159 2302 -1629 2970 1447 1485 5944 -3432 4948 -1100 5125 635 1442 2320 -1125 1558 -559 1275 -3529 4223 -4178 2667 -339 1361 196 -559 1878 -5549 -108 SS 20240217T133418.1Z 8813.565488 136 1 47.25 2 79.16 117.47 110.15 19.04 0.00 1 0.00 1 0 17 8.059e-01 1.390e-02 4.871e-01 9.462e-03 1.039372e+00 5.530407e-03 1.116608e-02 -6.000000e+00 4.666929e-01 224.82 -2.00 3.53 -2.00 322.20 0.00e+00 9.292325e-03 3.091318e-03 2.337322e-03 -6.000000e+00 2.025843e-02 273.24 -2.00 20.00 -2.00 321.81 0.00e+00 5.125 0.002 302.00 328.00 3 2.5524e+00 2.0697e-02 7.9974e-02 -6.0000e+00 1.1568e+00 5.2641e-01 3.5514e-02 7.1522e-02 -6.0000e+00 1.2609e+00 -7.0168e-01 4.1577e-02 3.6901e-02 -6.0000e+00 7.4655e-01 2.7830e-01 1.8526e-02 1.6600e-02 -6.0000e+00 3.1833e-01 8.3563e-05 -1.5558e-04 2.4809e-04 2.2289e-04 -6.0000e+00 2.2723e-02 -1.9280e-03 5.7750e-05 12 8 8 10 0 0 97.10 19.32 0.52 -0.00193 -0.00310 151 41 1 5 0 312.880 22.71 15.00 19.32 0.67 14.3 884.99 -150711 900000 -316060 -285000 -74414 -284377 -71916 -320918 -276636 -189407 -270656 -193804 -88988 -123837 -25112 -170203 -133447 65954 -65748 6168 -87068 -162565 -166927 900000 -37343 -70129 -88318 90302 -131775 -98752 -1017 22139 900000 -38222 16968 27977 108488 -42469 86776 -33079 7179 -9659 27001 17473 -14121 14041 17393 75464 -2552 46456 24536 22927 52133 3614 35095 8291 30494 11164 42401 -5906 11912 12916 3985 23311 8223 5620 10644 14356 5834 8074 9681 13098 1312 7001 -1099 2576 983 -8144 4236 9 6389 -260 -1460 533 4319 3262 -1637 3467 -101 3684 -3640 3210 -2150 -111 -1404 -2415 -1009 -572 34 -1870 -715 -1793 612 -4039 -892 -2863 -984 -2530 -707 81 24 733 -65 -415 -662 -522 286 -188 64 216 973 1845 2395 -57 -233 -386 889 367 117 934 584 302 -237 -473 -336 387 228 278 -554 345 -402 -959 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273.24 -2.00 20.00 -2.00 321.62 0.00e+00 4.741 0.002 302.00 328.00 3 1.9969e+00 1.0028e-02 7.4584e-02 -6.0000e+00 1.2580e+00 2.8387e-01 1.7018e-02 6.6181e-02 -6.0000e+00 1.3682e+00 -3.8962e-01 2.0279e-02 3.3354e-02 -6.0000e+00 8.1234e-01 1.5397e-01 9.1412e-03 1.4864e-02 -6.0000e+00 3.4739e-01 2.3410e-04 -8.7989e-04 1.2805e-04 1.6509e-04 -6.0000e+00 2.5013e-02 -1.2671e-03 -1.2267e-04 12 8 8 10 0 0 99.98 19.32 0.31 -0.00127 -0.00788 281 76 1 5 0 167.810 22.71 14.97 19.32 0.87 14.3 886.57 -376069 -236998 -216208 -302657 -288692 -331159 -162837 -347121 -183119 -309468 900000 -206961 -194147 -50113 -79434 -67344 -153712 -101713 -87998 -58522 -112134 900000 -127416 -35809 -67681 -90695 -72027 -131131 -72754 -84043 1037 -76198 40146 282 -13342 -28135 -12857 -7023 -14187 10247 -25540 23303 -13639 1071 -8747 -2692 -928 19089 769 8528 22939 3616 20085 -1800 13357 2500 11270 10590 6657 5808 2317 14719 2690 16701 5346 11462 4040 6858 7043 6301 7590 5495 5673 13 4827 -2602 293 -189 783 1772 967 211 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