File name: Pandora208s1_Windsor-West_20240320_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20240321T054555.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20240320_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20240320 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240320T132237.6Z 8845.557380 238 1 46.87 2 71.13 107.86 114.07 343.29 0.00 1 0.00 1 0 17 2.463e-01 1.563e-02 2.121e-01 1.064e-02 5.089817e-01 5.613852e-03 6.036320e-03 -6.000000e+00 1.430495e-01 226.38 -2.00 3.53 -2.00 320.26 0.00e+00 1.520272e-03 1.877405e-03 1.532608e-03 -6.000000e+00 6.306307e-03 275.67 -2.00 20.00 -2.00 319.73 0.00e+00 3.055 0.000 302.00 328.00 3 5.5625e+00 1.6427e-02 4.0522e-02 -6.0000e+00 3.5471e-01 1.1983e-01 2.0061e-02 2.7690e-02 -6.0000e+00 3.8552e-01 -7.1389e-02 1.8043e-02 1.4408e-02 -6.0000e+00 2.2857e-01 2.4941e-02 9.2702e-03 4.3928e-03 -6.0000e+00 9.7917e-02 5.1379e-05 -4.4959e-04 3.2220e-04 5.9339e-05 -6.0000e+00 6.9980e-03 -1.7074e-03 -2.4051e-04 12 9 8 11 8 0 99.90 19.16 0.56 -0.00171 -0.00509 25 7 1 5 0 1874.470 22.61 15.00 19.16 4.70 15.0 921.69 900000 -28323 -38059 -70547 900000 -137475 46158 -55861 138388 -56732 -811 -63345 -11281 30074 -37591 30585 3165 9510 -54120 -16519 -13777 64138 -25711 -1431 22559 8412 21939 -40991 65592 9796 4184 -231 41339 28607 1972 16616 -10639 6635 -6154 9697 -4008 -910 -5106 7280 9508 4644 15820 -6731 -545 -3928 8994 -1866 6923 873 1292 5523 -4486 4217 -417 3810 -490 7657 -372 1274 6060 1511 -1424 -679 2848 -1948 4559 -86 189 -1291 2296 -2667 -998 -2117 2382 2217 -5329 -1303 -5159 704 -3058 1045 -424 -97 3466 -1365 1825 -1413 518 -2267 226 274 1152 488 -195 -941 -444 -601 -2615 -322 -3813 326 -1728 1093 1816 427 534 290 1792 -1397 -42 -351 845 140 591 -1100 317 1348 -229 1333 -1011 1309 -7 451 -1054 -1 742 -728 386 -362 557 -395 530 -631 497 -703 64 -312 900000 -400 -610 -1463 900000 -5183 479 -1158 1435 -1456 -12 -1970 -267 579 -1630 800 119 362 -3928 -897 -735 1583 -1650 -78 1025 457 1029 -3440 1878 532 277 -18 2388 1893 163 1222 -1166 734 -936 1455 -752 -174 -1054 1341 1728 894 2742 -1486 -116 -927 2052 -518 1897 271 414 1751 -1588 1343 -136 1194 -170 2707 -159 571 2561 638 -611 -302 1373 -1107 2593 -52 110 -712 1104 -1219 -428 -954 1166 1260 -3715 -964 -4223 576 -2778 963 -411 -95 3196 -1241 1484 -1108 388 -1845 201 278 1313 616 -254 -1180 -508 -627 -2706 -344 -4504 387 -2217 1456 2621 683 902 493 2889 -2181 -61 -499 1220 214 952 -1833 510 2075 -345 1979 -1470 1781 -10 667 -1667 -2 1328 -1372 752 -753 1212 -892 1208 -1462 1107 -1507 129 -606 SS 20240320T132819.5Z 8845.561337 241 1 47.22 2 70.13 108.93 114.37 344.64 0.00 1 0.00 1 0 25 1.333e-01 6.142e-03 1.041e-01 3.100e-03 4.906582e-01 1.627163e-03 5.715084e-03 -6.000000e+00 7.720089e-02 226.38 -2.00 3.53 -2.00 320.20 0.00e+00 2.077289e-03 5.424749e-04 4.838734e-04 -6.000000e+00 3.322378e-03 275.67 -2.00 20.00 -2.00 319.67 0.00e+00 2.911 0.000 302.00 328.00 3 3.6018e+00 4.7487e-03 3.8423e-02 -6.0000e+00 1.9162e-01 5.3747e-02 5.7930e-03 2.5713e-02 -6.0000e+00 2.0811e-01 -3.0447e-03 5.2615e-03 1.3540e-02 -6.0000e+00 1.2357e-01 -9.8017e-03 2.7124e-03 4.7592e-03 -6.0000e+00 5.2575e-02 4.3589e-04 -3.1940e-04 9.3545e-05 5.4593e-05 -6.0000e+00 3.7592e-03 -3.1549e-03 -1.6951e-04 10 0 0 10 0 0 99.91 19.14 0.29 -0.00315 -0.00556 250 68 1 5 0 188.860 22.61 15.00 19.14 4.94 15.0 924.01 45866 29354 -27830 63593 -55910 53950 -62359 8162 -54625 13752 -24626 -6369 1568 -15577 18084 -19259 5144 -16902 3135 -13221 2141 -2847 -1981 -181 -1848 8696 -13057 1208 -15770 5767 -10523 4565 -2450 -1324 -5067 -5609 3863 -5871 -1529 -6343 2158 -2466 443 191 1139 2347 519 3105 -2583 1584 -196 1131 406 1780 1014 274 1330 -244 2249 355 3080 722 2777 549 1892 -313 -138 1132 644 676 10 1290 -147 398 -881 -356 -511 -938 -497 -1655 -679 -1904 -298 -1993 -565 -533 711 929 766 1283 531 480 -704 143 -922 852 714 456 -162 -482 -634 -938 -182 -1445 -874 -1530 -206 -410 384 692 100 285 21 10 -345 628 -109 524 21 -393 274 67 626 -60 246 -151 1000 274 139 -24 -177 -9 -72 30 -111 224 -56 77 -187 -45 -138 -219 270 229 -378 344 -879 300 -1159 90 -1189 168 -462 -113 32 -461 460 -774 187 -787 127 -659 98 -138 -101 -10 -108 476 -883 68 -1041 333 -824 351 -225 -122 -463 -532 378 -759 -218 -1099 375 -474 86 38 225 463 105 623 -564 354 -49 304 119 547 327 92 445 -82 719 123 1096 277 1159 251 844 -136 -62 523 318 376 6 777 -87 231 -468 -170 -233 -444 -265 -1036 -478 -1427 -234 -1686 -505 -504 689 909 735 1153 467 393 -567 120 -877 860 818 576 -212 -604 -730 -1040 -195 -1654 -1009 -1865 -263 -558 564 1104 169 484 35 15 -500 880 -158 799 34 -652 443 106 940 -91 357 -210 1371 408 218 -41 -319 -16 -140 61 -243 503 -129 177 -422 -97 -281 -430 SS 20240320T133814.1Z 8845.568219 244 1 2.62 2 68.40 110.83 114.83 347.00 0.00 1 0.00 1 0 17 3.038e-01 1.569e-02 1.641e-01 1.188e-02 4.495233e-01 6.107585e-03 5.331739e-03 -6.000000e+00 1.761466e-01 226.38 -2.00 3.53 -2.00 319.00 0.00e+00 6.042511e-04 1.445959e-03 5.843072e-04 -6.000000e+00 7.618584e-03 275.67 -2.00 20.00 -2.00 318.44 0.00e+00 2.693 0.000 302.00 328.00 3 4.3690e+00 1.6715e-02 3.5277e-02 -6.0000e+00 4.3720e-01 4.1852e-02 1.9310e-02 2.3284e-02 -6.0000e+00 4.7478e-01 -3.6948e-03 1.4789e-02 1.1805e-02 -6.0000e+00 2.8195e-01 -1.5127e-03 7.8594e-03 3.5405e-03 -6.0000e+00 1.2096e-01 2.6374e-04 3.9901e-04 3.4567e-04 3.9018e-05 -6.0000e+00 8.6067e-03 -6.9283e-03 -2.3407e-05 12 9 9 12 1 1 999.00 19.13 0.31 -0.00693 -0.00393 1 10 1 5 0 1297.190 22.61 15.00 19.13 5.37 15.0 926.65 900000 203864 247447 -91179 -4640 -59720 -19271 9500 -42147 26285 -52690 -16337 -17678 -3391 -19621 -12531 657 -1864 9456 8628 8803 1564 17193 -10720 11729 -10144 -1986 15482 -3737 -295 -9415 4321 12128 -6633 -3501 886 -8843 -3356 3661 -1013 -546 -4853 474 1568 9883 -1407 5022 984 2360 5504 3041 6469 -2771 -1457 -5208 425 512 5781 4161 1601 1423 -5166 5947 -3049 3070 -1166 2957 -628 -951 321 -544 -1567 3934 866 -1433 373 -974 176 -1168 160 -1244 -234 676 -3945 -566 -308 610 45 1756 1377 2441 -2860 -1406 -2227 -14 2869 168 1387 -30 -1142 -2950 -1356 -1930 239 -2429 -1397 194 -1109 1146 -516 420 147 855 228 -672 1927 421 -468 942 289 215 173 47 883 364 1650 840 -5 630 -48 -68 -18 186 -902 858 -212 566 -423 -1637 662 -209 -608 900000 2361 2866 -5097 -105 -2256 -558 235 -1868 650 -2839 -714 -940 -189 -1463 -985 49 -153 733 704 760 140 1457 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