File name: Pandora208s1_Windsor-West_20240429_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20240430T053631.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20240429_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20240429 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240429T112426.0Z 8885.475301 197 1 47.33 2 81.11 78.18 73.45 198.34 0.00 1 0.00 1 0 17 5.152e-01 2.860e-02 4.609e-01 2.249e-02 7.233334e-01 1.274700e-02 8.607083e-03 -6.000000e+00 3.031725e-01 229.63 -2.00 3.53 -2.00 321.77 0.00e+00 1.885514e-02 6.590020e-03 1.210563e-03 -6.000000e+00 1.420856e-02 280.12 -2.00 20.00 -2.00 321.27 0.00e+00 6.124 0.004 302.00 328.00 3 3.1665e+00 4.5870e-02 7.3226e-02 -6.0000e+00 7.5933e-01 6.7073e-01 5.9244e-02 4.8476e-02 -6.0000e+00 8.2333e-01 -8.3209e-01 5.2422e-02 2.3522e-02 -6.0000e+00 4.8654e-01 3.3249e-01 2.4862e-02 2.0693e-02 -6.0000e+00 2.0687e-01 2.3407e-05 -6.7959e-04 6.7011e-04 2.8632e-04 -6.0000e+00 1.4651e-02 -3.6997e-04 -3.8854e-05 12 8 8 10 0 0 99.78 19.35 0.69 -0.00037 -0.00548 35 9 1 5 0 1351.970 22.71 15.01 19.35 22.47 16.6 1065.91 -48512 227195 -131875 -36643 -77412 -188377 -176524 -108263 900000 -137502 900000 -62655 -51075 -37112 152769 44307 -2786 148133 -8618 900000 -81162 900000 89283 -23194 14818 -23619 11678 -68580 1893 -52955 16921 15598 60731 53274 14593 104228 88810 66970 -6358 14736 44417 43338 33152 5190 35645 144066 58900 4392 90343 45985 88226 -2308 74761 30264 7764 -12612 36328 2513 7893 7789 28179 14492 -8131 29691 7225 30564 -9650 20183 6094 20025 16086 4815 -4689 4387 18840 -10604 -9254 -16327 4522 -11176 -285 -1003 -5168 3069 -1894 3948 463 3181 -2821 6823 821 2018 -281 -5213 -3274 -7359 2338 -1094 589 -2843 4104 -3757 -2245 20 -4516 -1545 -1494 722 -2177 -87 -1697 1614 -820 637 -2088 -1297 1695 -2711 1939 365 1562 1399 4307 -525 960 -944 1778 3199 -416 1943 -2535 575 249 522 1862 318 60 -1048 8 -2119 1314 -1509 -1063 4979 -4649 -803 -1696 -8436 -6728 -2373 900000 -3561 900000 -1373 -1119 -813 3348 971 -69 3246 -258 900000 -4851 900000 1957 -693 325 -715 256 -3006 45 -2597 512 570 1584 1501 563 2284 1946 1887 -431 907 2178 2261 2007 428 2232 3157 3135 422 3865 3311 4603 -325 5227 3474 1134 -2264 3943 370 1071 1073 3411 2284 -1841 5081 1576 5167 -2457 4023 1571 5036 4465 1502 -1532 1199 3991 -2744 -2318 -4771 1269 -4385 -116 -461 -2653 1534 -1059 2196 277 1876 -1734 3596 427 985 -141 -3003 -2153 -5944 2003 -1095 605 -2914 3584 -3183 -1783 16 -4095 -1436 -1490 770 -2692 -118 -2566 2433 -1248 915 -2951 -1804 2379 -4212 3020 581 2380 2048 6215 -764 1331 -1293 2413 4771 -700 3572 -5293 1235 568 1270 4733 846 162 -2880 22 -5364 3011 -3551 SS 20240429T113714.2Z 8885.484192 202 1 47.32 2 78.78 80.25 74.21 201.07 0.00 1 0.00 1 0 17 3.590e-01 7.048e-03 2.515e-01 4.419e-03 6.368969e-01 2.420239e-03 7.281206e-03 -6.000000e+00 2.106321e-01 229.63 -2.00 3.53 -2.00 321.30 0.00e+00 2.697967e-03 1.171099e-03 2.375628e-03 -6.000000e+00 9.115251e-03 280.12 -2.00 20.00 -2.00 320.78 0.00e+00 4.963 0.002 302.00 328.00 3 2.2389e+00 8.2504e-03 6.0402e-02 -6.0000e+00 5.2603e-01 6.0701e-02 1.1523e-02 3.7167e-02 -6.0000e+00 5.6943e-01 -8.9008e-02 1.1999e-02 2.1049e-02 -6.0000e+00 3.3812e-01 2.5550e-02 5.6819e-03 7.4253e-03 -6.0000e+00 1.4350e-01 2.2489e-04 5.8558e-04 1.3239e-04 1.0815e-04 -6.0000e+00 1.0134e-02 -1.7793e-03 1.2287e-05 11 8 0 10 0 0 90.65 19.34 0.45 -0.00178 0.00262 153 41 1 5 0 309.230 22.71 15.00 19.34 23.16 16.7 1072.02 31590 -149149 -152897 -132971 -90084 -206295 -16635 -94778 26791 -113980 -5561 -93824 -54900 -48160 -37913 24912 -41049 -9801 -47175 43482 -55796 -35959 -39156 -32121 -35752 -39104 -26976 -29700 -27633 -15160 -6844 -13061 24231 -3945 -4910 8285 -16777 -127 -2106 4340 -3917 -1610 -3165 938 2050 -3456 -2030 -529 2498 3248 6579 477 6274 3633 3032 2807 2589 129 222 1570 3700 1839 2236 4408 2636 3539 1142 444 1606 2716 1908 291 2433 1791 1 -969 -1905 -3827 -2830 -1852 -1226 -1641 -2715 -818 -575 218 258 1404 1423 -263 672 -338 -153 315 -1022 461 785 971 -199 -518 -667 -1290 -1036 -1050 -1560 -1276 -702 -373 335 729 422 51 108 -118 -148 -299 165 -338 608 -79 88 468 540 306 213 382 280 312 -109 210 -154 -34 -234 -97 -135 -12 402 85 -16 -28 -289 -228 136 -1227 -1377 -938 -427 -2909 -72 -613 115 -1080 -24 -930 -473 -498 -441 182 -654 -127 -955 375 -1322 -713 -860 -720 -893 -1061 -651 -717 -667 -366 -183 -439 637 -141 -171 264 -788 -6 -127 288 -312 -134 -280 81 179 -328 -195 -52 253 357 785 67 914 587 519 501 471 24 40 280 690 393 540 1139 701 910 304 127 515 977 743 117 927 638 0 -293 -565 -1235 -1051 -804 -611 -920 -1653 -521 -392 156 192 1046 1039 -185 435 -209 -94 208 -785 404 790 1087 -233 -584 -691 -1218 -943 -1010 -1611 -1384 -808 -463 459 1107 692 85 176 -184 -220 -439 249 -543 1018 -135 146 743 828 452 303 523 389 478 -189 401 -317 -74 -487 -217 -318 -29 992 212 -38 -64 -690 -523 SS 20240429T114317.0Z 8885.488391 205 1 47.33 2 77.68 81.23 74.61 202.35 0.00 1 0.00 1 0 17 3.127e-01 7.629e-03 1.379e-01 3.014e-03 5.898062e-01 1.625762e-03 6.713530e-03 -6.000000e+00 1.834898e-01 229.63 -2.00 3.53 -2.00 320.99 0.00e+00 2.532271e-03 7.188108e-04 2.080144e-03 -6.000000e+00 7.940573e-03 280.12 -2.00 20.00 -2.00 320.45 0.00e+00 4.551 0.002 302.00 328.00 3 2.0999e+00 5.2513e-03 5.5120e-02 -6.0000e+00 4.5825e-01 4.9605e-02 7.0249e-03 3.3311e-02 -6.0000e+00 4.9605e-01 -6.6571e-02 7.0472e-03 1.8647e-02 -6.0000e+00 2.9455e-01 1.6425e-02 3.4222e-03 6.5771e-03 -6.0000e+00 1.2501e-01 3.9624e-04 5.7666e-04 9.0045e-05 8.3350e-05 -6.0000e+00 8.8281e-03 -2.1151e-03 4.2489e-06 11 8 0 10 0 0 64.85 19.34 0.28 -0.00212 0.00222 207 56 1 5 0 228.620 22.71 15.01 19.34 23.51 16.6 1075.13 -118131 47017 -100125 -88102 -123605 -106685 -66649 -106182 -92161 -116653 -19659 -116664 -19080 -76811 -24199 -45820 -30731 10034 -45163 14823 -39345 5007 -41542 -9285 -25070 -13690 168 -26235 -6266 -24173 15691 -18217 16003 -12835 -3149 -18068 -9364 -6379 -2839 266 -251 1095 -4023 9870 -2968 4032 -370 -590 731 2505 1813 3954 5499 985 4457 2477 4078 -596 1524 1624 1369 3420 2885 4407 118 2906 -134 2628 2163 2433 1954 726 1857 -586 2195 -3158 -155 -2966 -675 -2391 -813 -1643 -1828 -1035 -1614 571 615 981 204 1189 -241 356 -490 -916 58 -313 639 106 382 -688 -513 -1012 -331 -1069 -1562 -1060 -971 -10 -22 506 381 216 3 -705 -65 -43 493 42 364 -297 618 376 714 535 335 -156 674 543 -178 319 -224 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