File name: Pandora208s1_Windsor-West_20240629_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20240711T144754.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20240629_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20240629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240629T133359.5Z 8946.565272 270 1 46.56 2 53.14 90.98 41.42 216.76 0.00 1 0.00 1 0 17 4.443e-01 9.490e-03 8.776e-02 5.082e-03 2.397988e-01 2.639774e-03 2.854169e-03 -6.000000e+00 2.637223e-01 232.88 -2.00 3.53 -2.00 317.60 0.00e+00 3.062404e-04 4.058832e-04 1.234557e-04 -6.000000e+00 1.158109e-02 286.39 -2.00 20.00 -2.00 316.77 0.00e+00 1.663 0.000 302.00 328.00 3 6.3715e+00 7.0730e-03 2.0800e-02 -6.0000e+00 6.6248e-01 5.5794e-02 7.9529e-03 1.2678e-02 -6.0000e+00 7.1471e-01 5.2285e-03 4.8361e-03 6.1321e-03 -6.0000e+00 4.2482e-01 -7.6614e-03 2.3821e-03 1.6876e-03 -6.0000e+00 1.8005e-01 1.2921e-04 2.1009e-04 1.5392e-04 1.9429e-05 -6.0000e+00 1.2556e-02 -6.5241e-04 -8.3192e-05 12 8 8 10 0 0 98.90 19.56 0.48 -0.00065 0.00093 18 5 1 5 0 2586.590 22.90 14.99 19.56 26.96 18.0 1032.49 8424 4426 8420 1740 -1922 -14805 11420 -8213 2753 -11875 -916 -3889 -1573 490 8110 3659 -2682 515140 -3970 4270 -1579 1461 -616 3806 848 2097 798 -2661 1784 -4825 340 368 430 -2147 -2001 -14 -4524 471 -1031 2078 -2742 1003 -1051 -599 -1200 -12 -852 -1066 334 -1697 1899 489 254 303 -572 679 444 1107 -387 1320 478 2011 631 1380 252 -279 -992 209 994 110 2848 47 1958 932 66 -488 -1780 -2052 -1553 -1372 -2575 -925 -1715 -1551 -313 115 93 705 1410 699 1058 -728 -1019 -1500 34 -116 1921 877 -139 53 -1136 -1267 -1196 381 -1366 -602 -580 -568 730 300 755 239 590 -1150 -181 -1070 -360 -224 699 406 463 507 -163 775 -6 -234 37 123 553 619 416 -933 316 -429 206 390 194 336 410 -274 -956 -633 818 477 868 175 -181 -1566 1004 -985 323 -1656 -113 -521 -232 81 1388 704 -568 2553 -915 983 -388 347 -155 964 231 577 217 -695 421 -1226 87 102 126 -636 -557 -4 -1484 174 -459 1017 -1503 548 -598 -340 -682 -7 -465 -567 172 -914 1049 291 159 198 -385 461 304 743 -259 879 337 1510 516 1153 203 -207 -701 148 766 96 2568 44 1782 812 53 -353 -1200 -1374 -1127 -1117 -2356 -902 -1773 -1694 -363 141 113 864 1772 830 1146 -729 -958 -1437 34 -132 2361 1177 -191 70 -1392 -1449 -1359 456 -1783 -816 -822 -841 1128 467 1201 374 909 -1657 -240 -1386 -476 -315 1042 632 721 771 -241 1074 -8 -295 46 158 756 893 621 -1438 495 -712 359 701 358 627 752 -490 -1658 -1065 SS 20240629T135546.4Z 8946.580398 282 1 47.41 2 49.12 94.81 43.88 223.69 0.00 1 0.00 1 0 17 1.320e-02 8.104e-03 1.092e-02 3.951e-03 2.170036e-01 2.049021e-03 2.586436e-03 -6.000000e+00 7.831974e-03 232.88 -2.00 3.53 -2.00 317.18 0.00e+00 1.236372e-03 2.825945e-04 1.388665e-04 -6.000000e+00 3.440012e-04 286.40 -2.00 20.00 -2.00 316.37 0.00e+00 1.525 0.000 302.00 328.00 3 6.2267e+00 5.4465e-03 1.8948e-02 -6.0000e+00 1.9674e-02 5.3662e-02 6.0986e-03 1.1457e-02 -6.0000e+00 2.1227e-02 9.8454e-04 3.5917e-03 5.5457e-03 -6.0000e+00 1.2617e-02 -4.4206e-03 1.7264e-03 1.7114e-03 -6.0000e+00 5.3459e-03 1.7804e-04 3.9442e-04 1.1881e-04 1.8297e-05 -6.0000e+00 3.7305e-04 1.0353e-04 -1.2525e-04 11 8 0 10 0 0 98.82 19.57 0.57 0.00010 0.00307 21 6 1 5 0 2256.670 22.90 15.00 19.57 29.12 18.0 1050.17 1370 423 175 -1864 1382 -1456 3400 -2006 -1752 -3455 -3751 -6178 -1603 -2350 -2065 -292 -1082 532 215 -1355 1856 795 1333 587 -958 -28 -557 -1744 2016 -1869 954 4 1136 -273 -3351 -2084 -2339 -972 225 390 -250 25 -292 246 373 -505 321 -625 1704 -1155 1648 301 1929 1456 964 1580 391 212 -265 1725 659 1838 1023 304 825 -1055 -1283 -879 -58 -141 950 1126 1603 365 -813 -778 -2595 -1035 -2167 -1068 -1836 -1791 -1216 -1088 -708 156 791 545 644 326 1033 -940 -121 -798 -1287 162 1244 882 -676 -650 -1071 -1146 -964 -680 -927 -874 -140 -163 611 737 1008 379 -312 -367 102 -493 351 -193 945 117 -21 359 953 1122 40 -294 791 -301 391 182 226 -605 374 -335 179 448 520 290 -388 198 -947 -1148 179 59 24 -254 164 -175 418 -290 -274 -559 -599 -1062 -296 -496 -487 -72 -278 139 58 -383 510 220 377 175 -301 -9 -172 -507 534 -518 273 1 367 -88 -1043 -656 -828 -400 108 211 -145 15 -178 150 226 -306 187 -356 931 -663 974 191 1263 995 674 1116 281 150 -186 1205 490 1457 875 269 688 -819 -941 -648 -47 -127 899 1085 1506 329 -676 -580 -1812 -746 -1621 -887 -1701 -1793 -1271 -1202 -838 194 1020 677 829 394 1133 -955 -114 -765 -1341 184 1544 1185 -931 -853 -1309 -1309 -1097 -827 -1210 -1192 -198 -241 895 1137 1586 585 -479 -517 133 -626 454 -268 1390 181 -32 542 1380 1535 53 -368 958 -385 528 258 331 -909 573 -542 306 786 885 500 -701 343 -1610 -1902 SS 20240629T145626.7Z 8946.622532 310 1 47.09 2 38.12 107.31 52.30 240.00 0.00 1 0.00 1 0 17 3.071e-02 1.599e-02 1.547e-02 6.674e-03 1.922531e-01 3.464428e-03 2.280237e-03 -6.000000e+00 1.822522e-02 232.88 -2.00 3.53 -2.00 316.75 0.00e+00 1.581029e-03 4.276393e-04 1.932690e-04 -6.000000e+00 8.005959e-04 286.40 -2.00 20.00 -2.00 315.96 0.00e+00 1.270 0.000 302.00 328.00 3 7.1411e+00 9.1292e-03 1.6118e-02 -6.0000e+00 4.5782e-02 7.7983e-02 1.0183e-02 1.0047e-02 -6.0000e+00 4.9399e-02 -7.4412e-03 5.9021e-03 4.8445e-03 -6.0000e+00 2.9362e-02 8.2486e-04 2.7800e-03 1.5775e-03 -6.0000e+00 1.2439e-02 9.4686e-05 4.0832e-04 1.9847e-04 1.5505e-05 -6.0000e+00 8.6835e-04 7.1780e-05 -1.7825e-04 12 8 8 10 0 0 90.57 19.60 0.49 0.00007 0.00314 12 3 1 5 0 3871.460 22.90 14.99 19.60 31.30 18.1 1067.45 3634 7478 -850 -454 -507 1705 8088 4323 942 -532 1086 -7042 -305 3666 -1630 7888 130 -24378 1281 254 5295 4551 -1839 4712 -321 1550 -889 -1895 -2658 3805 -1393 5023 2609 1987 -3599 610 -4022 732 -1193 51 -393 -804 1651 261 19 -731 1318 132 3070 -2785 379 2508 715 554 2357 -817 177 -578 54 195 1108 2212 2072 992 2123 675 -1045 -3156 679 1258 2188 1384 1276 1005 -3379 -1360 -4680 -2894 -733 -3214 -2063 -1802 -465 -1790 -923 108 2708 2570 1791 400 673 -3277 -2116 -1661 -1056 304 400 207 -98 81 -640 -876 -1231 -874 -969 -1224 -274 -791 487 1388 769 923 951 -843 -819 -1023 -476 1141 953 362 502 855 1808 345 -494 -1604 1638 -836 1369 261 -231 -1615 246 -681 -53 1189 656 734 -293 364 -1229 -1597 619 1291 -157 -75 -80 257 1222 750 182 -106 207 -1522 -69 897 -467 2181 40 -9800 410 84 1667 1431 -632 1576 -117 561 -319 -636 -847 1139 -463 1663 932 695 -1248 208 -1604 327 -640 31 -249 -527 1074 172 13 -478 816 80 1761 -1720 239 1635 496 399 1690 -613 132 -427 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