File name: Pandora208s1_Windsor-West_20240801_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20240802T054511.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20240801_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20240801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240801T111320.6Z 8979.467599 159 1 46.15 2 82.63 72.58 49.82 86.36 0.00 1 0.00 1 0 25 6.615e-01 6.683e-02 5.468e-01 5.755e-02 8.429754e-01 3.518324e-02 9.384427e-03 -6.000000e+00 4.186381e-01 232.28 -2.00 3.53 -2.00 321.81 0.00e+00 -3.015770e-02 1.572745e-02 1.208744e-02 -6.000000e+00 1.995917e-02 288.19 -2.00 20.00 -2.00 321.18 0.00e+00 7.199 0.007 302.00 328.00 3 3.4221e+00 1.2697e-01 1.2835e-01 -6.0000e+00 1.0552e+00 1.2426e+00 1.5636e-01 1.5122e-01 -6.0000e+00 1.1489e+00 -1.6240e+00 9.4667e-02 2.9821e-02 -6.0000e+00 6.7793e-01 6.4554e-01 4.7975e-02 3.0971e-02 -6.0000e+00 2.8460e-01 6.0259e-06 -2.2308e-03 1.7088e-03 2.4038e-04 -6.0000e+00 2.0308e-02 -4.8295e-03 1.0251e-05 12 9 8 11 8 0 87.79 19.61 1.19 -0.00483 -0.02159 13 4 1 5 0 3550.020 23.01 15.00 19.61 29.55 18.7 1023.30 900000 41864 37058 53411 -33585 900000 -16570 900000 169543 28670 900000 50315 101752 -95281 -18263 900000 66015 900000 900000 900000 900000 -7025 -39861 120158 108586 104859 172569 900000 -81401 416 171136 900000 -9161 900000 47298 -11576 900000 4085 147503 -28734 8575 91852 -7160 105105 900000 83412 28268 900000 -25109 316633 96523 128371 37790 39400 60574 171635 138343 90543 115743 167489 900000 69587 50438 65381 15645 32296 77889 51925 -3755 83391 18233 31884 -9005 -13814 16131 59449 -24249 162327 38336 30705 36389 17546 -4232 -1301 -2005 4795 4113 20133 -313 6374 -1106 -33145 3681 -18437 17940 -10675 -6895 -10488 -1901 2602 -11135 -11525 3325 9552 1104 2759 2883 -6768 -2169 -5466 2346 343 -386 7405 -7390 -4352 5374 5002 -507 4748 9037 2599 2534 419 6018 889 -302 -2619 -7244 3786 1137 901 -359 1716 2136 408 -2258 1134 -63 -4641 1161 -225 900000 2341 2073 2987 -1960 900000 -927 900000 9482 1603 900000 2814 5691 -18767 -1811 900000 3692 900000 900000 900000 900000 -536 -4661 6720 6073 5865 9652 900000 -12830 28 9571 900000 -815 900000 2645 -987 900000 403 8250 -5552 1302 6116 -1220 5878 900000 4665 2484 900000 -3812 17709 5398 7180 4328 4827 6453 9599 7737 7475 6782 9367 900000 6116 5911 7139 2833 4817 7841 6915 -990 10960 4710 7303 -2974 -4378 3518 7481 -6394 9079 6754 6869 8955 5937 -1849 -589 -977 2299 2151 9008 -167 2995 -523 -20762 1616 -11033 8579 -7881 -5650 -10030 -1754 2234 -10120 -9475 2232 6277 846 2191 2443 -6890 -2377 -7062 3116 490 -559 9649 -10726 -6024 6928 6797 -763 6824 12029 3533 3338 545 7169 1081 -375 -3699 -12338 6522 2210 1883 -812 4092 5417 1089 -6276 3052 -167 -11940 2613 -484 SS 20240801T112543.3Z 8979.476196 162 1 47.20 2 80.44 74.57 47.59 88.27 0.00 1 0.00 1 0 17 5.461e-01 1.150e-02 4.215e-01 9.876e-03 7.623350e-01 5.866642e-03 8.525075e-03 -6.000000e+00 3.262978e-01 232.28 -2.00 3.53 -2.00 321.90 0.00e+00 1.555725e-03 3.518607e-03 1.756764e-03 -6.000000e+00 1.702921e-02 288.19 -2.00 20.00 -2.00 321.37 0.00e+00 5.732 0.003 302.00 328.00 3 2.6431e+00 2.3767e-02 7.0844e-02 -6.0000e+00 8.1940e-01 1.3009e-01 3.5593e-02 4.4611e-02 -6.0000e+00 8.8639e-01 -2.2154e-01 3.6268e-02 2.4386e-02 -6.0000e+00 5.2395e-01 8.2113e-02 1.6318e-02 7.9755e-03 -6.0000e+00 2.2738e-01 6.4877e-05 2.7383e-04 2.9881e-04 1.0947e-04 -6.0000e+00 1.5800e-02 -5.6531e-03 2.9837e-05 12 8 8 10 0 0 10.61 19.63 0.71 -0.00565 -0.00360 70 19 1 5 0 674.240 23.01 14.99 19.63 30.17 18.7 1027.96 900000 -201075 900000 -259437 -204995 900000 -320987 -107492 -123599 900000 900000 900000 -60039 900000 60004 -72021 -33540 -22231 -90355 75952 118459 -73939 37152 -21796 147422 -8065 -47916 -97433 -16567 7373 64103 -40271 14504 -3988 -78864 900000 1192 724 -6747 4962 8392 -29108 2215 2256 21728 9306 -3784 9017 2500 28640 2958 -7108 9439 16105 5424 8331 9549 -2920 9594 -40 6240 1664 6900 4188 7591 -1361 13068 4282 -1755 2300 6153 359 4004 1830 5777 782 -3268 -1729 981 -49 -905 -766 -1327 -1866 903 83 1590 552 3292 900 1931 1174 254 -3165 -2205 -570 211 1068 764 -862 -1693 -2230 -282 -1705 -1192 -1859 -1805 -1360 -661 -538 -372 88 359 -252 718 -94 -107 819 -316 156 14 646 977 425 1146 -636 1392 893 684 1038 -82 -343 -178 -539 529 111 -260 227 -462 176 -287 -382 900000 -1933 900000 -2494 -1971 900000 -6172 -1033 -1188 900000 900000 900000 -577 900000 577 -692 -322 -214 -1303 730 1139 -995 357 -210 1417 -78 -691 -2248 -175 71 616 -929 223 -77 -3109 900000 25 19 -234 181 331 -1791 104 108 877 438 -211 468 149 1459 222 -663 826 1440 574 897 1037 -354 996 -5 714 226 1022 709 1277 -249 2123 819 -408 586 1627 103 1063 459 1255 163 -697 -394 257 -15 -338 -323 -610 -920 465 46 894 318 1810 479 952 559 123 -1746 -1399 -418 178 1010 756 -837 -1519 -1810 -214 -1377 -1023 -1696 -1765 -1448 -787 -723 -546 133 536 -363 982 -129 -151 1212 -496 245 21 933 1361 572 1481 -811 1771 1272 1119 1895 -165 -736 -407 -1324 1367 296 -712 621 -1233 438 -675 -857 SS 20240801T113628.0Z 8979.483658 167 1 47.67 2 78.51 76.28 45.66 89.98 0.00 1 0.00 1 0 17 4.375e-01 1.204e-02 3.149e-01 7.881e-03 6.518713e-01 4.414836e-03 8.096574e-03 -6.000000e+00 2.594219e-01 232.28 -2.00 3.53 -2.00 321.39 0.00e+00 5.607955e-03 2.268638e-03 5.392718e-03 -6.000000e+00 1.192664e-02 288.19 -2.00 20.00 -2.00 320.79 0.00e+00 4.853 0.002 302.00 328.00 3 3.3186e+00 1.5894e-02 6.4114e-02 -6.0000e+00 6.5119e-01 1.2914e-01 2.1569e-02 4.6654e-02 -6.0000e+00 7.0278e-01 -1.6286e-01 2.0608e-02 2.3234e-02 -6.0000e+00 4.1760e-01 5.5683e-02 9.7619e-03 6.4113e-03 -6.0000e+00 1.7797e-01 7.9981e-05 3.5931e-04 2.3409e-04 1.3965e-04 -6.0000e+00 1.2388e-02 -5.1396e-03 -3.2358e-06 12 9 8 11 8 0 91.55 19.62 0.53 -0.00514 -0.00244 46 12 1 5 0 1025.070 23.01 14.99 19.62 30.66 18.7 1031.50 -169233 -154992 114472 -146687 -227023 -136577 111534 53725 -5439 900000 -93789 2516 -74512 -93688 -105204 -88113 -37078 -59023 77192 -81295 -22092 -68692 -38719 -34798 -52473 38256 -24232 -44722 -16882 29937 -27413 -25341 -16379 5345 -9501 -43880 605 -2028 44788 -12056 14224 5336 15320 3788 2511 14803 -12703 14419 -12600 -2526 3680 10926 -757 15096 5066 9034 4879 610 6564 2012 16635 3692 5821 -1253 6658 5852 4582 2924 489 7310 -1327 5057 1937 4813 560 -373 -6169 -3901 4344 -4484 1178 -2373 1498 -1510 -1433 -1459 -504 578 -1057 1588 -31 -1423 -1768 -762 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