File name: Pandora208s1_Windsor-West_20250403_L2Fit_fout2c4d20220407p1-8.txt
File generation date: 20250404T054119.0Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 208
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora208_OF_v4d20211014.txt
Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt
Level 1 file used: Pandora208s1_Windsor-West_20250403_L1_smca1c4d20220407p1-8.txt
Full location name: Ontario Ministry of the Environment, Windsor West
Short location name: Windsor-West
Country of location: Canada
Location latitude [deg]: 42.2929
Location longitude [deg]: -83.0731
Location altitude [m]: 180
Local noon date: 20250403
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 206 347
Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250403T124237.5Z 9224.529600 89 1 47.14 2 73.90 97.30 102.59 32.10 0.00 1 0.00 1 0 17 3.878e-01 1.244e-02 2.356e-01 8.971e-03 4.760974e-01 4.722302e-03 5.649924e-03 -6.000000e+00 2.255740e-01 227.39 -2.00 3.53 -2.00 320.31 0.00e+00 4.752067e-04 1.638772e-03 1.883846e-03 -6.000000e+00 9.827885e-03 277.10 -2.00 20.00 -2.00 319.76 0.00e+00 3.545 0.001 302.00 328.00 3 5.0230e+00 1.4029e-02 4.3529e-02 -6.0000e+00 5.6093e-01 3.6099e-02 1.7224e-02 2.7297e-02 -6.0000e+00 6.0855e-01 1.3671e-02 1.5553e-02 1.3615e-02 -6.0000e+00 3.6159e-01 -1.3953e-02 7.9266e-03 3.8536e-03 -6.0000e+00 1.5462e-01 6.0641e-05 1.0253e-04 2.7534e-04 5.3630e-05 -6.0000e+00 1.0940e-02 -4.3385e-03 -9.1189e-05 12 8 8 10 0 0 98.49 19.42 0.45 -0.00434 -0.00357 20 5 1 5 0 2343.290 22.80 14.99 19.42 19.59 21.1 1064.02 32849 900000 -96116 -70302 -107679 10921 -76780 93831 -16921 42464 -57988 3066 378039 -6194 -14333 1486 -32196 -26113 -8591 -15243 -14369 -13697 -24247 2875 -5043 -21986 -12115 -15430 -33679 -8264 -9916 13449 18671 -1691 -14345 -908 -13239 -6136 5806 -4687 -451 -2141 1595 68276 1746 5276 -2245 1979 443 -363 -1992 5321 1896 3502 6692 -3646 -848 3602 382 1321 4068 3588 3724 -500 2083 1323 1893 545 3521 -175 1111 2740 -1419 -336 1644 -1963 -1458 -656 -1851 -67 66 -2416 -870 -2860 429 -1083 -341 -841 1933 -486 323 1097 -22 476 -1002 -992 1563 1026 -314 -252 -2070 617 -1471 -1383 -1192 -1505 -502 354 -938 649 845 81 -751 -702 398 353 161 -246 1183 547 884 510 818 746 -437 244 1053 -139 308 326 -267 -1013 -258 -199 -286 280 1198 -161 382 -579 -209 -831 287 900000 -2254 -1259 -2601 96 -1535 821 -240 371 -1377 45 3306 -147 -442 45 -1475 -1218 -358 -711 -676 -650 -1363 134 -273 -1474 -732 -919 -2370 -485 -677 829 1213 -137 -1261 -72 -1356 -705 721 -752 -76 -387 288 6717 321 947 -437 374 87 -77 -472 1281 510 990 1912 -1195 -274 1099 118 427 1354 1263 1526 -218 917 559 782 238 1674 -93 623 1620 -850 -186 812 -910 -638 -294 -949 -39 44 -1815 -686 -2442 380 -984 -335 -804 1851 -449 274 858 -17 382 -912 -1026 1785 1235 -392 -317 -2440 648 -1537 -1531 -1408 -1872 -654 487 -1355 1005 1381 135 -1204 -1107 582 505 238 -387 1937 921 1461 820 1266 1103 -626 333 1417 -203 495 568 -496 -1968 -495 -406 -616 619 2677 -368 847 -1236 -444 -1714
SS 20250403T125410.6Z 9224.537622 92 1 29.76 2 71.78 99.34 101.46 34.29 0.00 1 0.00 1 0 25 4.314e-02 5.348e-03 1.836e-02 1.340e-03 4.329057e-01 6.947802e-04 5.103479e-03 -6.000000e+00 2.509153e-02 227.39 -2.00 3.53 -2.00 319.47 0.00e+00 1.452172e-03 1.856188e-04 4.614025e-04 -6.000000e+00 1.081848e-03 277.10 -2.00 20.00 -2.00 318.89 0.00e+00 3.157 0.001 302.00 328.00 3 2.0304e+00 1.9485e-03 3.8336e-02 -6.0000e+00 6.2394e-02 2.8482e-02 2.2767e-03 2.2665e-02 -6.0000e+00 6.7695e-02 -4.5946e-03 1.8229e-03 1.1590e-02 -6.0000e+00 4.0196e-02 -7.2692e-03 9.6020e-04 3.7505e-03 -6.0000e+00 1.7092e-02 1.8512e-03 -8.7284e-05 4.0095e-05 4.2973e-05 -6.0000e+00 1.2171e-03 -3.9728e-03 -1.3539e-04 12 1 1 12 1 1 99.73 19.40 0.24 -0.00397 -0.00463 148 98 1 5 0 130.520 22.80 15.00 19.40 19.52 21.2 1064.32 -11792 -11861 -9605 -21797 -6258 -19438 -8343 -14440 -8420 -13966 -13879 -11350 -12194 -4079 -7972 -880 -206 -884 -1587 20 -533 -448 1532 -1127 -466 -4683 -1607 -3353 -2603 -2086 -945 -328 -631 -1632 -3865 -3085 -3021 -1021 -1177 -770 -1490 -1147 -1304 -1043 -32 -162 649 75 403 100 1144 1262 1328 955 777 1144 293 452 538 1368 1421 1808 2073 1269 738 27 28 -143 1066 473 852 672 602 561 -130 -611 -1505 -810 -1334 -887 -1275 -1711 -1778 -1111 -486 -228 324 572 1026 494 581 270 109 242 -339 451 586 457 -302 -324 -869 -786 -486 -1049 -1056 -973 -527 -370 391 393 472 95 -6 -321 6 86 225 362 147 -61 266 394 329 502 105 159 537 352 150 -76 -47 -489 91 -93 77 180 359 135 -177 -203 -464 -364 -234 -262 -213 -513 -116 -414 -174 -364 -222 -411 -421 -375 -489 -183 -441 -51 -13 -60 -114 1 -40 -34 121 -98 -43 -466 -153 -310 -234 -199 -101 -39 -84 -220 -510 -417 -462 -183 -256 -192 -409 -330 -389 -314 -9 -49 195 23 125 33 406 442 500 383 324 490 128 195 227 577 634 886 1119 734 421 15 15 -79 649 326 627 505 441 386 -82 -349 -820 -449 -836 -638 -1043 -1419 -1569 -1034 -482 -239 352 629 1103 502 544 235 100 212 -333 498 729 577 -393 -404 -1089 -903 -544 -1255 -1352 -1306 -687 -511 581 633 800 162 -10 -490 9 119 323 548 236 -100 434 623 502 731 147 230 769 499 234 -129 -84 -839 162 -176 153 370 753 286 -368 -405 -886 -670
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