File name: Pandora208s1_Windsor-West_20250606_L2Fit_fout2c4d20220407p1-8.txt
File generation date: 20250607T072500.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 208
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora208_OF_v4d20211014.txt
Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt
Level 1 file used: Pandora208s1_Windsor-West_20250606_L1_smca1c4d20220407p1-8.txt
Full location name: Ontario Ministry of the Environment, Windsor West
Short location name: Windsor-West
Country of location: Canada
Location latitude [deg]: 42.2929
Location longitude [deg]: -83.0731
Location altitude [m]: 180
Local noon date: 20250606
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 206 347
Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250606T152700.1Z 9288.643751 261 1 6.12 2 32.37 117.38 144.56 38.91 0.00 1 0.00 1 0 17 7.625e-03 6.039e-03 2.336e-03 1.580e-03 1.726716e-01 8.361816e-04 2.096319e-03 -6.000000e+00 4.517702e-03 232.30 -2.00 3.53 -2.00 314.99 0.00e+00 3.881373e-04 7.110636e-05 2.716569e-05 -6.000000e+00 1.968467e-04 284.09 -2.00 20.00 -2.00 314.38 0.00e+00 1.183 0.000 302.00 328.00 3 3.8149e+00 2.1611e-03 1.4825e-02 -6.0000e+00 1.1341e-02 4.1914e-02 2.3875e-03 9.0632e-03 -6.0000e+00 1.2244e-02 -5.6289e-04 1.3648e-03 4.3902e-03 -6.0000e+00 7.2713e-03 -5.1731e-03 6.0152e-04 1.2218e-03 -6.0000e+00 3.0802e-03 3.0466e-03 2.9720e-04 4.6168e-05 1.6411e-05 -6.0000e+00 2.1542e-04 -5.0559e-03 -1.3998e-04 12 1 1 12 1 1 56.41 19.44 0.38 -0.00506 -0.00282 18 42 1 5 0 305.940 22.80 14.99 19.44 27.69 22.2 1083.13 -366 9 -1181 -2049 -1166 -1887 -159 803 -225 -903 -706 -422 -900 9 333 -241 244 938 526 829 1303 1412 1096 242 899 840 161 80 138 969 1103 1473 587 -1616 -1979 -2093 -1482 -973 -802 -1112 -748 -902 -571 -521 -242 -435 -416 -731 -517 335 437 593 646 885 546 980 676 399 359 827 1166 1260 1483 535 228 -206 -576 63 742 352 591 377 553 297 -302 -436 -874 -515 -911 -1179 -1312 -1621 -1521 -1008 -693 -270 209 287 280 64 190 89 -25 208 -12 509 767 598 -299 -250 -670 -731 -161 -724 -629 -643 -516 -321 327 340 392 142 -33 -109 128 97 248 359 425 -257 187 201 509 374 641 186 913 414 337 245 -98 -441 12 111 58 135 249 31 -303 -242 -619 -731 -123 3 -415 -657 -331 -528 -47 261 -80 -329 -250 -154 -333 4 150 -116 119 464 268 433 678 728 582 125 478 455 85 42 68 470 557 783 331 -910 -1046 -1128 -818 -628 -567 -829 -590 -734 -471 -428 -197 -350 -323 -587 -402 261 358 477 543 769 484 877 610 357 316 733 1080 1173 1467 546 220 -194 -508 55 707 352 629 386 591 303 -283 -391 -769 -442 -788 -1140 -1315 -1758 -1626 -1133 -835 -325 261 365 349 75 216 97 -26 210 -13 569 943 749 -381 -304 -807 -823 -180 -873 -768 -821 -687 -419 446 486 571 201 -44 -139 160 118 307 447 570 -344 250 279 680 474 813 225 1066 503 433 312 -129 -590 17 150 83 200 377 45 -440 -359 -893 -1028
SS 20250606T153745.9Z 9288.651226 267 1 3.42 2 30.63 120.77 143.35 42.68 0.00 1 0.00 1 0 17 1.126e-02 7.886e-03 6.953e-03 4.725e-03 1.695896e-01 2.503341e-03 2.079748e-03 -6.000000e+00 6.673363e-03 232.31 -2.00 3.53 -2.00 314.96 0.00e+00 7.091828e-04 2.106615e-04 2.129375e-05 -6.000000e+00 2.907082e-04 284.09 -2.00 20.00 -2.00 314.34 0.00e+00 1.162 0.000 302.00 328.00 3 5.1190e+00 6.4756e-03 1.4592e-02 -6.0000e+00 1.6753e-02 4.9118e-02 7.1493e-03 8.9913e-03 -6.0000e+00 1.8086e-02 -2.1977e-03 4.0883e-03 4.3453e-03 -6.0000e+00 1.0740e-02 -3.2543e-03 1.7998e-03 1.2670e-03 -6.0000e+00 4.5506e-03 8.4654e-04 4.9822e-04 1.3825e-04 1.6498e-05 -6.0000e+00 3.1815e-04 -5.8757e-03 -1.1561e-04 12 9 1 12 1 1 999.00 19.43 0.26 -0.00588 -0.00213 2 11 1 5 0 1137.690 22.80 15.00 19.43 28.17 22.2 1086.67 1610 -138 -1393 -2476 -2113 -2727 -779 1303 -1185 -2736 -792 -2287 -515 -1564 1043 265 -219 1152 730 1681 -507 2489 2232 2049 607 2116 1212 378 1042 2546 2547 454 -382 -3779 -1456 -3029 -2319 -1550 -561 -1188 -705 -1318 -689 316 -748 -461 -1083 -123 -313 329 607 1283 753 512 587 1225 705 -109 281 536 1946 1369 1441 987 259 -219 -41 194 -195 575 683 757 -362 -468 -951 56 -1209 -1245 -997 -1421 -774 -2040 -988 -939 -359 -298 201 441 441 199 552 515 -614 -430 16 802 835 1009 333 -859 -800 -1293 -350 -971 -1125 -994 -205 -92 535 262 263 801 57 -54 -53 -342 269 -198 908 417 625 -92 89 1035 461 -82 489 370 435 61 -155 -225 602 -54 -174 277 -133 -67 -169 -591 -581 -322 536 -47 -470 -805 -611 -774 -232 421 -425 -1012 -279 -844 -196 -672 482 124 -105 559 365 854 -263 1244 1146 1098 341 1192 668 194 521 1241 1296 237 -211 -2115 -744 -1600 -1357 -1007 -407 -937 -564 -1092 -577 262 -622 -376 -859 -97 -239 253 489 1037 639 451 525 1103 617 -99 250 481 1734 1318 1421 999 249 -200 -36 171 -181 569 720 786 -387 -476 -925 50 -1042 -1049 -865 -1328 -793 -2198 -1064 -1069 -421 -359 252 560 551 242 632 553 -640 -448 17 903 1000 1255 421 -1049 -939 -1479 -395 -1144 -1423 -1270 -271 -122 740 369 378 1112 77 -69 -64 -418 324 -254 1203 562 847 -123 118 1338 568 -100 575 451 541 80 -202 -297 807 -74 -252 401 -198 -101 -253 -860 -846 -456
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