File name: Pandora208s1_Windsor-West_20250616_L2Fit_fout2c4d20220407p1-8.txt
File generation date: 20250617T054621.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 208
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora208_OF_v4d20211014.txt
Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt
Level 1 file used: Pandora208s1_Windsor-West_20250616_L1_smca1c4d20220407p1-8.txt
Full location name: Ontario Ministry of the Environment, Windsor West
Short location name: Windsor-West
Country of location: Canada
Location latitude [deg]: 42.2929
Location longitude [deg]: -83.0731
Location altitude [m]: 180
Local noon date: 20250616
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 206 347
Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250616T113202.4Z 9298.480583 209 1 19.32 2 74.71 72.12 62.62 208.29 0.00 1 0.00 1 0 17 2.663e-01 1.316e-02 2.276e-01 9.339e-03 4.834789e-01 5.023379e-03 5.842620e-03 -6.000000e+00 1.585895e-01 232.85 -2.00 3.53 -2.00 320.23 0.00e+00 2.130973e-03 1.742665e-03 2.530050e-03 -6.000000e+00 7.012943e-03 285.08 -2.00 20.00 -2.00 319.55 0.00e+00 3.721 0.001 302.00 328.00 3 4.5936e+00 1.5144e-02 4.5956e-02 -6.0000e+00 3.9947e-01 6.6319e-02 1.8554e-02 2.9312e-02 -6.0000e+00 4.3124e-01 -4.9271e-02 1.5615e-02 1.4737e-02 -6.0000e+00 2.5519e-01 1.1432e-02 7.9055e-03 4.1365e-03 -6.0000e+00 1.0797e-01 7.8055e-05 1.1376e-03 2.8417e-04 6.2517e-05 -6.0000e+00 7.5424e-03 -6.0275e-03 3.9748e-06 12 9 9 12 1 1 64.31 19.35 0.39 -0.00603 0.00252 7 5 1 5 0 2345.070 22.80 15.00 19.35 25.43 22.1 1049.80 -109298 -55122 -33075 30081 5999 -76391 85532 120403 900000 -80577 -15574 -90328 -49677 -59304 -39162 -16459 23664 17238 -15856 141804 -2426 8882 -6780 619 -16467 29727 8130 -23133 5347 -37793 22850 -31150 12484 -3440 -7339 -4877 -8219 21853 -509 7979 999 10027 -6212 1250 -2229 1392 6164 9056 10920 3849 7734 1011 5461 2127 3754 3105 -2105 3173 -2420 2822 -462 4859 -4205 2295 559 4433 1832 3487 2204 -9 3494 1576 2590 -2012 386 -2752 -1620 -1536 -3744 -265 -2450 -1298 -2986 226 -2596 -966 -284 1206 -311 -450 1317 -1630 -44 350 1195 -1573 1137 -1013 -366 -1438 -1747 97 -1172 1440 -924 183 -752 -195 -45 978 1497 23 1457 -769 274 -1342 368 128 788 402 553 1542 -434 522 -1031 163 -72 737 -1216 79 -640 431 592 -673 -393 365 399 375 -393 -165 -57 -505 -2985 -980 -488 274 55 -1523 779 1096 900000 -2445 -269 -3563 -1594 -2571 -1664 -667 700 588 -801 1549 -114 376 -355 32 -1087 1285 433 -1611 277 -3269 1238 -3304 949 -310 -658 -442 -875 2069 -73 1217 178 1725 -1304 247 -462 281 1195 1731 2108 850 1806 276 1536 659 1191 1023 -741 1044 -826 924 -166 1831 -1836 1003 245 1873 782 1529 1047 -5 1979 928 1467 -1117 199 -1329 -736 -723 -2041 -162 -1656 -959 -2391 187 -2363 -917 -279 1184 -304 -414 1103 -1310 -34 282 1070 -1650 1317 -1261 -464 -1765 -2074 104 -1239 1576 -1107 228 -955 -263 -66 1548 2491 39 2340 -1184 393 -1919 535 197 1279 670 905 2424 -672 764 -1468 230 -102 1064 -1977 138 -1189 787 1130 -1382 -851 812 905 858 -885 -353 -116 -998
SS 20250616T120232.6Z 9298.501766 225 1 50.61 2 69.28 76.76 65.42 215.66 0.00 1 0.00 1 0 25 2.756e-02 5.063e-03 8.422e-03 8.599e-04 3.720575e-01 4.490512e-04 4.350138e-03 -6.000000e+00 1.636142e-02 232.85 -2.00 3.53 -2.00 319.22 0.00e+00 9.903573e-04 1.109213e-04 3.296978e-04 -6.000000e+00 7.144783e-04 285.09 -2.00 20.00 -2.00 318.46 0.00e+00 2.798 0.000 302.00 328.00 3 2.1686e+00 1.2594e-03 3.3949e-02 -6.0000e+00 4.1116e-02 7.9072e-03 1.4594e-03 1.9845e-02 -6.0000e+00 4.4364e-02 3.1343e-03 1.0662e-03 9.7768e-03 -6.0000e+00 2.6349e-02 -8.9315e-03 5.5744e-04 2.8739e-03 -6.0000e+00 1.1159e-02 2.4634e-03 -3.8790e-05 2.6238e-05 3.0614e-05 -6.0000e+00 7.7876e-04 -4.4776e-03 -1.2766e-04 10 0 0 10 0 0 99.32 19.36 0.28 -0.00448 -0.00477 384 104 1 5 0 122.820 22.80 14.99 19.36 26.16 22.2 1056.37 -6602 -12558 -3082 -13513 -5784 -10608 -5580 -6521 -7002 -8512 -8077 -6830 -7239 -1288 -3608 -716 -3117 -419 1183 -342 -117 -738 138 -2216 253 -1378 -1126 -2690 -503 -777 -193 990 -654 -2023 -3217 -2711 -3053 -1211 -1667 -1303 -938 -973 -603 814 328 -441 234 -608 -173 150 717 765 960 837 701 760 432 707 182 1099 1242 1670 1853 1170 932 113 392 312 958 334 629 425 520 279 -89 -256 -1146 -732 -1094 -1085 -1168 -1784 -1568 -1053 -742 -358 317 438 871 549 753 72 179 211 -63 522 410 429 -502 -335 -821 -680 -401 -836 -996 -922 -553 -340 372 315 472 96 108 -124 -28 136 256 341 66 -194 -44 233 235 408 312 243 802 460 280 -52 37 -293 145 26 74 129 220 44 -271 -240 -363 -348 -193 -427 -97 -442 -161 -309 -169 -226 -271 -350 -337 -308 -386 -77 -257 -55 -263 -37 107 -33 -11 -72 14 -248 29 -168 -135 -310 -55 -89 -24 138 -101 -317 -486 -420 -537 -249 -415 -372 -289 -315 -201 269 110 -149 78 -203 -58 52 271 312 418 386 335 373 215 347 88 534 637 933 1132 689 536 67 226 185 628 225 453 314 375 190 -61 -159 -671 -432 -721 -744 -903 -1524 -1417 -1005 -759 -388 356 499 971 578 728 65 154 186 -62 570 504 576 -696 -444 -1012 -773 -447 -997 -1274 -1238 -779 -463 540 492 770 155 167 -180 -41 195 377 488 102 -307 -69 356 348 624 457 340 1102 673 447 -81 62 -500 256 49 146 264 460 94 -566 -482 -699 -648
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