File name: Pandora208s1_Windsor-West_20250620_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20250621T054313.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20250620_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20250620 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250620T110750.2Z 9302.463775 188 1 47.77 2 79.03 68.21 39.60 137.08 0.00 1 0.00 1 0 17 4.929e-01 6.330e-03 2.430e-01 3.583e-03 6.938697e-01 2.004401e-03 8.013431e-03 -6.000000e+00 2.927956e-01 232.86 -2.00 3.53 -2.00 321.47 0.00e+00 4.988610e-03 1.067391e-03 3.358544e-03 -6.000000e+00 1.279662e-02 285.45 -2.00 20.00 -2.00 320.93 0.00e+00 5.062 0.002 302.00 328.00 3 1.6461e+00 7.3259e-03 6.4065e-02 -6.0000e+00 7.3574e-01 5.8779e-02 1.0690e-02 4.2358e-02 -6.0000e+00 7.9361e-01 -7.0212e-02 1.1119e-02 2.4998e-02 -6.0000e+00 4.7147e-01 1.5834e-02 5.1271e-03 9.3520e-03 -6.0000e+00 1.9987e-01 3.4260e-04 4.5055e-04 1.0429e-04 1.4302e-04 -6.0000e+00 1.3926e-02 -5.7485e-03 -1.1125e-05 10 0 0 10 0 0 92.63 19.35 0.40 -0.00575 -0.00236 254 69 1 5 0 185.860 22.71 15.00 19.35 23.82 22.3 1031.46 -143111 -181939 -110739 -172802 -207321 -200740 122831 -103874 -108896 -133558 -140596 -130270 -152744 -74857 -70177 -68001 -26683 -29867 -34246 12194 1730 -35422 -38699 -57521 -44635 -31248 -40144 -7514 -35759 -26752 -19788 333 -10287 -1425 -22907 -22068 -8392 -15534 -11123 -1561 2669 -1856 -5074 13180 -6151 5188 -3075 -2714 -2388 2209 3921 6429 4619 6193 712 -327 -1654 -1258 1413 2474 2183 5387 5907 1058 2496 1079 755 1243 3347 2006 2106 908 2026 960 1264 -1739 -1851 155 -98 -647 -396 -1754 -1244 -1287 151 -284 419 604 906 1003 1547 -97 187 -292 -29 -322 624 221 -159 -787 -1057 -564 -900 -684 -1486 -1531 -888 -615 121 452 260 -70 -129 -69 231 -21 383 541 -38 -92 438 188 577 404 45 95 959 190 -199 -43 76 -250 -66 -182 103 32 173 -99 61 -128 -94 -219 -500 -1098 -387 -1087 -1738 -1613 429 -399 -495 -840 -1032 -1047 -2028 -602 -686 -784 -233 -303 -395 94 15 -458 -554 -1085 -795 -513 -729 -97 -637 -505 -429 7 -280 -37 -712 -709 -270 -651 -548 -82 150 -117 -349 778 -453 353 -236 -219 -205 200 394 705 568 814 104 -50 -263 -197 210 368 349 945 1180 245 582 251 179 314 945 652 737 327 697 310 367 -476 -495 44 -32 -257 -182 -919 -699 -771 96 -191 291 425 624 652 932 -57 108 -185 -21 -275 611 244 -183 -876 -1081 -518 -796 -634 -1482 -1611 -992 -744 162 678 423 -118 -211 -108 345 -31 582 869 -64 -157 723 298 883 593 64 131 1323 292 -349 -84 159 -507 -142 -418 251 79 441 -255 153 -302 -209 -513 SS 20250620T111415.3Z 9302.468233 191 1 64.45 2 77.92 69.20 38.80 139.17 0.00 1 0.00 1 0 17 3.690e-01 6.004e-03 1.751e-01 2.443e-03 6.458419e-01 1.354943e-03 7.370250e-03 -6.000000e+00 2.191404e-01 232.86 -2.00 3.53 -2.00 321.22 0.00e+00 3.677955e-03 6.621178e-04 2.119858e-03 -6.000000e+00 9.581634e-03 285.46 -2.00 20.00 -2.00 320.63 0.00e+00 4.634 0.002 302.00 328.00 3 1.5160e+00 4.6542e-03 5.8052e-02 -6.0000e+00 5.5065e-01 3.7302e-02 6.4914e-03 3.6979e-02 -6.0000e+00 5.9405e-01 -3.6259e-02 6.5688e-03 2.0716e-02 -6.0000e+00 3.5291e-01 1.3891e-03 3.1086e-03 7.3641e-03 -6.0000e+00 1.4954e-01 6.0941e-04 -9.9323e-05 7.2052e-05 9.2981e-05 -6.0000e+00 1.0428e-02 -4.6795e-03 -8.2538e-05 10 0 0 10 0 0 99.35 19.35 0.30 -0.00468 -0.00543 340 92 1 5 0 138.900 22.80 15.01 19.35 24.40 22.2 1035.86 -164412 -22577 -162784 61291 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607 776 889 957 667 799 420 702 390 588 248 425 709 -50 288 -106 -189 -583 -488 -691 -127 -897 -952 -679 -412 306 190 804 808 674 522 143 -159 -240 -585 -355 799 377 -401 -604 -983 -1122 -695 -1219 -1546 -1065 -941 -44 -212 870 668 509 18 -261 449 387 838 130 200 -601 329 175 637 294 317 291 1074 532 84 197 -125 -715 53 -605 -147 142 743 -87 -47 -302 -282 -431 SS 20250620T112030.2Z 9302.472572 194 1 57.61 2 76.84 70.16 38.05 141.27 0.00 1 0.00 1 0 17 3.248e-01 9.092e-03 1.780e-01 3.748e-03 6.033110e-01 2.079751e-03 7.136860e-03 -6.000000e+00 1.929063e-01 232.86 -2.00 3.53 -2.00 321.07 0.00e+00 2.765007e-03 9.505825e-04 3.285146e-03 -6.000000e+00 8.553317e-03 285.46 -2.00 20.00 -2.00 320.45 0.00e+00 4.279 0.001 302.00 328.00 3 2.6739e+00 6.9766e-03 5.5286e-02 -6.0000e+00 4.8474e-01 5.7281e-02 9.3025e-03 3.8125e-02 -6.0000e+00 5.2290e-01 -7.6876e-02 8.9246e-03 1.9608e-02 -6.0000e+00 3.1084e-01 2.3794e-02 4.2958e-03 5.6034e-03 -6.0000e+00 1.3217e-01 2.7772e-04 5.0765e-05 1.1303e-04 8.8341e-05 -6.0000e+00 9.2085e-03 -4.4789e-03 -3.6219e-05 11 8 0 10 0 0 99.83 19.36 0.28 -0.00448 -0.00410 150 41 1 5 0 314.520 22.80 15.00 19.36 24.93 22.2 1040.19 10774 -96036 900000 -134286 2709 -182808 -35346 -129086 -106579 -89058 -88234 -59323 -102964 5733 -86005 5612 -52504 -1766 -33733 -8283 -20597 -17189 23347 -41203 20374 -34834 -7539 -44420 823 -40494 2848 1159 -5604 20016 -15234 5338 -13914 10831 -9015 1705 -2322 6076 3907 -369 8207 -2705 6324 -3620 8294 -3423 5213 4633 5533 6603 1333 5119 -1854 4730 -1413 7347 2513 2949 4630 3002 2973 -942 3434 -822 3584 346 2669 195 996 1378 -2369 1080 -4289 -610 -2889 -651 -1802 -977 -1343 -1593 110 -164 980 132 1640 -375 -101 -1211 138 -1044 -1008 175 -180 1285 -1284 96 -1253 -836 -1179 -1010 -1395 -1242 -331 -545 980 -108 1362 189 596 -281 -198 311 17 486 38 242 -135 773 510 513 -95 235 300 5 465 -392 274 -594 121 -651 -36 263 291 231 -371 123 -505 28 39 -739 900000 -1524 10 -3199 -165 -1755 -1298 -976 -1021 -602 -2048 49 -2150 69 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