File name: Pandora208s1_Windsor-West_20250823_L2Fit_fout2c4d20220407p1-8.txt
File generation date: 20250824T054455.0Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 208
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora208_OF_v4d20211014.txt
Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt
Level 1 file used: Pandora208s1_Windsor-West_20250823_L1_smca1c4d20220407p1-8.txt
Full location name: Ontario Ministry of the Environment, Windsor West
Short location name: Windsor-West
Country of location: Canada
Location latitude [deg]: 42.2929
Location longitude [deg]: -83.0731
Location altitude [m]: 180
Local noon date: 20250823
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 206 347
Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250823T125253.8Z 9366.536733 102 1 3.94 2 68.08 94.71 71.72 92.14 0.00 1 0.00 1 0 25 2.718e-02 7.369e-03 1.990e-02 3.754e-03 3.355035e-01 1.940332e-03 4.006260e-03 -6.000000e+00 1.604627e-02 231.12 -2.00 3.53 -2.00 318.17 0.00e+00 6.273182e-04 3.576653e-04 2.699128e-04 -6.000000e+00 7.130306e-04 287.86 -2.00 20.00 -2.00 317.34 0.00e+00 2.655 0.000 302.00 328.00 3 3.2951e+00 5.2502e-03 3.1541e-02 -6.0000e+00 4.0113e-02 1.3215e-02 5.9523e-03 1.7755e-02 -6.0000e+00 4.3309e-02 -5.2267e-03 3.8298e-03 8.6470e-03 -6.0000e+00 2.5806e-02 -5.0271e-03 1.9680e-03 2.4274e-03 -6.0000e+00 1.1004e-02 9.6912e-04 3.7982e-04 1.1161e-04 2.6846e-05 -6.0000e+00 7.6787e-04 -7.2337e-03 -1.1429e-04 12 9 1 12 1 1 39.40 19.48 0.38 -0.00723 -0.00438 10 36 1 5 0 357.980 22.90 14.99 19.48 28.59 23.6 1001.49 217 -14029 6934 -10384 162 -8876 -7702 418 -6009 1072 -11078 7041 -2897 -1376 -6159 5214 -5653 1707 -537 3498 2410 -971 1895 -1835 1563 -1055 -3095 -1204 -3915 857 -906 4281 -2486 391 -3030 -611 -4834 -428 -839 -25 -1074 -785 -109 84 1318 -363 1080 -1229 -191 376 -69 1278 176 1701 1113 978 135 706 165 653 744 1545 3048 1114 1213 146 -127 -105 1027 195 -291 538 450 -78 477 291 -1994 29 -1673 -1522 -1409 -2023 -1920 -881 -891 -43 925 123 608 645 956 638 -499 694 133 476 122 622 -528 -846 -1095 -1170 -833 -870 -1156 -1226 -120 -297 288 625 657 308 121 -401 353 436 364 412 -28 -194 -150 242 107 340 634 75 1445 274 502 -2 -6 -158 -24 273 216 45 356 276 -443 -209 -727 -721 12 -981 398 -657 8 -504 -471 27 -451 78 -920 528 -279 -153 -830 691 -883 262 -88 574 404 -169 336 -360 313 -224 -659 -237 -759 164 -194 957 -586 98 -748 -151 -1282 -129 -306 -10 -486 -370 -48 37 632 -177 512 -590 -91 185 -34 663 98 986 670 604 85 437 101 402 482 1084 2118 827 873 107 -90 -76 753 161 -260 487 399 -65 364 217 -1420 20 -1221 -1264 -1311 -1926 -1934 -932 -1013 -48 1069 146 704 754 1024 631 -474 669 141 565 152 841 -690 -1133 -1361 -1349 -1010 -1051 -1502 -1673 -159 -417 430 939 1027 479 190 -588 479 614 495 594 -43 -294 -239 375 161 486 918 104 1951 395 734 -3 -9 -251 -40 474 375 82 654 513 -816 -370 -1317 -1266
SS 20250823T153619.2Z 9366.650222 208 1 47.76 2 40.41 131.57 44.42 126.21 0.00 1 0.00 1 0 17 8.154e-03 5.982e-03 4.810e-03 2.402e-03 1.730209e-01 1.243981e-03 2.104330e-03 -6.000000e+00 4.811708e-03 231.11 -2.00 3.53 -2.00 316.29 0.00e+00 4.478297e-04 1.399079e-04 5.030424e-05 -6.000000e+00 2.138723e-04 287.85 -2.00 20.00 -2.00 315.49 0.00e+00 1.312 0.000 302.00 328.00 3 5.8637e+00 3.2531e-03 1.5802e-02 -6.0000e+00 1.2028e-02 3.2496e-02 3.6251e-03 9.1015e-03 -6.0000e+00 1.2988e-02 8.6167e-04 2.0900e-03 4.4147e-03 -6.0000e+00 7.7387e-03 -5.5772e-03 9.6761e-04 1.2385e-03 -6.0000e+00 3.2991e-03 3.4895e-04 1.9563e-04 7.1793e-05 1.5425e-05 -6.0000e+00 2.3034e-04 -5.6907e-03 -1.2888e-04 11 1 0 11 8 0 99.95 19.51 0.30 -0.00569 -0.00422 28 8 1 5 0 1705.570 22.90 14.99 19.51 30.04 23.8 1013.96 -331 -433 -1312 -2014 -846 -1023 -542 -930 -97 -2402 -1161 -30 -856 1647 -1251 -127 -299 861 1209 2189 97 1316 625 1336 345 -299 -91 -244 884 -305 567 857 -22 -1055 -1867 -2229 -1929 -534 -401 36 -835 -474 -468 -579 -351 -811 -25 -669 -182 -95 915 731 651 382 895 890 629 345 140 1420 927 1269 1556 559 468 -315 -843 -19 947 114 408 81 562 256 15 -392 -726 -713 -1414 -1289 -1537 -1860 -1557 -807 -491 -131 216 558 713 362 700 96 -158 -433 321 342 625 117 -199 -340 -764 -942 -250 -608 -911 -788 -544 -263 399 505 434 169 52 -149 -41 -74 490 499 443 -130 337 -164 169 512 -113 279 906 464 638 161 184 -501 146 -113 184 185 545 -46 -372 -341 -408 -670 -69 -95 -287 -402 -149 -188 -106 -203 -23 -589 -274 -7 -229 481 -390 -42 -100 291 418 822 37 496 243 539 146 -130 -38 -95 317 -110 211 336 -9 -434 -725 -884 -851 -273 -227 23 -569 -332 -333 -412 -247 -566 -17 -434 -114 -60 604 510 475 290 687 693 494 268 107 1090 749 1098 1431 531 421 -259 -652 -15 787 107 406 83 562 244 13 -329 -558 -535 -1150 -1095 -1446 -1896 -1660 -903 -588 -167 269 704 940 450 791 98 -151 -415 328 383 771 157 -270 -440 -925 -1069 -281 -736 -1186 -1072 -772 -364 576 763 671 254 74 -205 -52 -90 612 664 635 -196 511 -245 243 696 -146 341 1072 571 830 221 259 -721 214 -175 298 292 882 -76 -609 -543 -668 -1073
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