File name: Pandora208s1_Windsor-West_20250901_L2Fit_fout2c4d20220407p1-8.txt
File generation date: 20250902T054329.4Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 208
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora208_OF_v4d20211014.txt
Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt
Level 1 file used: Pandora208s1_Windsor-West_20250901_L1_smca1c4d20220407p1-8.txt
Full location name: Ontario Ministry of the Environment, Windsor West
Short location name: Windsor-West
Country of location: Canada
Location latitude [deg]: 42.2929
Location longitude [deg]: -83.0731
Location altitude [m]: 180
Local noon date: 20250901
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 206 347
Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250901T120426.2Z 9375.503081 68 1 63.46 2 78.64 89.38 166.20 348.44 0.00 1 0.00 1 0 17 4.036e-01 5.399e-03 1.024e-01 1.793e-03 6.631327e-01 9.917417e-04 7.634112e-03 -6.000000e+00 2.376755e-01 230.34 -2.00 3.53 -2.00 321.29 0.00e+00 4.067366e-03 5.063567e-04 2.591968e-03 -6.000000e+00 1.055482e-02 287.13 -2.00 20.00 -2.00 320.70 0.00e+00 4.902 0.002 302.00 328.00 3 6.7354e-01 3.4941e-03 6.0605e-02 -6.0000e+00 5.9316e-01 5.0279e-02 4.9486e-03 3.8308e-02 -6.0000e+00 6.4079e-01 -4.3746e-02 5.0270e-03 2.2030e-02 -6.0000e+00 3.8191e-01 4.1741e-03 2.3646e-03 8.0146e-03 -6.0000e+00 1.6307e-01 1.0864e-03 5.4434e-04 5.2395e-05 1.0566e-04 -6.0000e+00 1.1398e-02 -6.2077e-03 2.3150e-05 10 0 0 10 0 0 14.05 19.48 0.34 -0.00621 -0.00212 633 171 1 5 0 74.560 22.90 15.00 19.48 21.37 23.2 948.66 -172159 -143447 -166224 -110484 -127341 -106123 -139157 -117258 -111007 -108496 -86488 -115493 -63273 -71305 -42436 -28036 -38426 -33965 -34399 -2993 -30975 -16870 -42350 -10623 -29651 -22572 -32686 -18759 -25755 -25140 -15465 -22916 -980 -14959 -6286 -16544 -8094 -8686 -6324 -702 -2350 1772 -3996 2359 -2132 1592 -1886 358 -816 1674 2314 1859 3337 1363 2667 793 1614 1223 711 1305 1479 2818 2279 2695 1292 2144 653 1733 1186 1606 2048 1294 1582 398 907 -1588 -728 -2077 -451 -950 -882 -1117 -1806 -1052 -496 -34 239 920 798 999 863 61 -401 -645 39 -44 845 25 -6 -375 -631 -525 -653 -1072 -1601 -913 -857 -336 313 315 389 91 144 -157 106 27 394 97 12 -328 389 478 368 394 -102 88 502 539 26 57 -28 -392 -6 -131 -32 40 232 68 -88 -192 -167 -65 -1204 -878 -1366 -502 -646 -445 -900 -697 -699 -721 -499 -1070 -453 -723 -408 -279 -484 -457 -505 -34 -477 -230 -800 -160 -581 -434 -703 -344 -522 -580 -395 -753 -30 -539 -201 -610 -314 -411 -359 -44 -168 130 -328 186 -181 134 -170 33 -81 178 276 248 482 218 443 140 287 216 123 227 275 582 540 700 346 559 175 489 383 586 801 519 612 145 297 -486 -215 -664 -165 -415 -446 -636 -1114 -686 -344 -25 181 704 600 707 570 38 -253 -442 30 -40 878 29 -7 -440 -680 -511 -611 -1060 -1699 -1013 -1015 -429 402 451 602 145 224 -233 149 42 564 148 19 -530 605 715 585 602 -150 125 718 851 42 103 -55 -809 -12 -305 -79 102 600 177 -223 -460 -379 -140
SS 20250901T121100.3Z 9375.507642 71 1 53.78 2 77.42 90.49 166.38 354.18 0.00 1 0.00 1 0 17 3.059e-01 5.315e-03 6.048e-02 1.249e-03 6.119644e-01 6.929996e-04 7.101381e-03 -6.000000e+00 1.800983e-01 230.34 -2.00 3.53 -2.00 321.04 0.00e+00 2.606594e-03 3.192226e-04 2.016563e-03 -6.000000e+00 7.998353e-03 287.13 -2.00 20.00 -2.00 320.40 0.00e+00 4.464 0.002 302.00 328.00 3 5.8798e-01 2.3505e-03 5.5371e-02 -6.0000e+00 4.4947e-01 3.4389e-02 3.1493e-03 3.4820e-02 -6.0000e+00 4.8557e-01 -1.9638e-02 3.0400e-03 1.8743e-02 -6.0000e+00 2.8940e-01 -6.3413e-03 1.4645e-03 6.1166e-03 -6.0000e+00 1.2356e-01 1.8777e-03 5.1531e-04 3.7449e-05 8.3974e-05 -6.0000e+00 8.6372e-03 -6.3504e-03 7.7293e-06 10 0 0 10 0 0 15.93 19.49 0.30 -0.00635 -0.00248 855 231 1 5 0 55.210 22.90 14.99 19.49 22.10 23.2 955.53 -61441 -116436 -100653 -102897 -110860 -105030 -120924 -75029 -117996 -64145 -82862 -60799 -60107 -44946 -29830 -27265 -16267 64174 -7488 -30681 -3246 -24069 -15261 -15008 -19908 -14240 -20396 -9539 -21589 -8187 -14698 -5585 -6687 -6997 -9292 -11294 -3882 -7111 -1899 -3661 -997 -2147 648 -1869 -475 671 -509 -74 -1069 2505 306 2436 1074 2627 1316 1583 1262 605 1070 641 2423 2124 3397 1918 1859 1207 753 1289 1111 1535 596 1462 532 856 -524 -435 -1598 -1002 -1204 -1085 -585 -1722 -1327 -1480 -402 -222 530 581 932 942 560 415 -334 98 -370 391 423 393 -142 -351 -677 -964 -363 -1333 -1272 -1338 -667 -264 313 478 303 259 13 -213 1 368 344 304 -85 -281 266 157 426 233 261 107 786 264 167 2 -108 -243 -183 -115 -152 154 258 118 -109 -107 -188 -135 -239 -907 -711 -714 -783 -716 -1075 -484 -1322 -453 -757 -526 -659 -542 -385 -405 -244 477 -123 -673 -55 -516 -322 -345 -519 -369 -566 -231 -599 -223 -512 -209 -288 -312 -410 -528 -193 -442 -138 -317 -93 -217 67 -202 -52 74 -58 -9 -134 331 46 400 196 509 272 339 276 131 226 137 543 535 957 599 586 373 235 423 414 646 272 675 240 359 -202 -152 -546 -360 -501 -531 -329 -1094 -902 -1072 -309 -180 445 449 775 739 410 287 -230 72 -312 377 426 441 -165 -395 -700 -997 -360 -1406 -1303 -1444 -762 -324 422 713 486 424 21 -323 1 517 500 467 -138 -462 426 243 633 333 358 142 1040 383 273 3 -209 -495 -394 -264 -370 386 657 302 -274 -254 -424 -291
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