File name: Pandora208s1_Windsor-West_20250910_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20250911T054216.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20250910_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20250910 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250910T121226.1Z 9384.508635 236 1 17.34 2 78.84 93.79 65.91 264.49 0.00 1 0.00 1 0 33 5.600e-01 1.721e-02 3.483e-01 1.245e-02 6.325315e-01 7.001847e-03 7.778896e-03 -6.000000e+00 3.366255e-01 229.55 -2.00 3.53 -2.00 321.17 0.00e+00 5.122918e-03 3.346312e-03 4.594480e-03 -6.000000e+00 1.587884e-02 286.40 -2.00 20.00 -2.00 320.57 0.00e+00 4.983 0.002 302.00 328.00 3 3.5808e+00 2.4030e-02 6.2733e-02 -6.0000e+00 8.4177e-01 1.9015e-01 3.1972e-02 4.2581e-02 -6.0000e+00 9.1372e-01 -2.5557e-01 3.0131e-02 2.1397e-02 -6.0000e+00 5.3955e-01 1.0646e-01 1.4473e-02 6.0042e-03 -6.0000e+00 2.2833e-01 5.5571e-05 -3.9367e-04 3.7553e-04 1.2411e-04 -6.0000e+00 1.6341e-02 -2.5215e-03 -7.5167e-06 12 9 9 12 1 1 98.46 19.31 0.79 -0.00252 -0.00548 11 9 1 5 0 1444.580 22.71 15.01 19.31 22.27 23.3 958.54 -166531 -222932 -168519 900000 -180358 900000 900000 -143433 -87159 900000 43731 -122403 -31424 126688 58 -62000 900000 -62485 900000 136080 900000 16390 8679 73549 73795 21438 -31087 153770 -23904 46602 33362 351655 36166 -24042 -8474 448 -21684 -18562 14388 22401 20436 -1517 11864 900000 -16226 -7213 25583 11421 19196 9342 14134 24101 17429 -5553 14448 4389 -469 -2004 8593 5139 11093 -957 9670 -1039 10089 8412 -873 5064 3288 3269 3763 7073 731 1259 -711 -5194 -8000 -5421 145 -3462 -2121 -5874 301 -559 -1995 75 625 -460 334 2259 1616 -2401 -2166 -2910 -215 -2334 -832 1412 -122 72 -1512 -3148 -936 -969 -770 -652 -2302 -1366 691 525 1476 1900 -77 -329 -467 -343 712 619 -123 692 -1363 1107 2447 833 -356 -307 1284 -149 638 806 -582 -242 -120 31 -63 -423 86 317 -316 -227 205 -668 -2896 -7753 -3552 900000 -3875 900000 900000 -2528 -1056 900000 530 -2495 -381 1535 1 -1639 900000 -2031 900000 1649 900000 284 170 891 894 433 -1058 1864 -745 807 789 4262 1106 -1374 -396 20 -1339 -1328 897 1500 1533 -151 1075 900000 -2023 -841 2200 1173 1916 1116 1794 3060 2575 -1109 2468 856 -97 -414 1557 970 2100 -229 2361 -309 2713 2238 -256 1479 1104 1243 1529 2828 301 479 -249 -1729 -2650 -1858 54 -1592 -1111 -3417 177 -352 -1365 54 459 -347 245 1536 1077 -1574 -1404 -2046 -160 -2064 -835 1548 -141 80 -1567 -3002 -839 -914 -775 -691 -2644 -1681 925 783 2251 2948 -119 -485 -683 -494 1049 964 -195 1099 -2154 1720 3623 1202 -500 -415 1723 -222 1065 1419 -1118 -488 -254 71 -146 -1007 207 767 -748 -531 450 -1412 SS 20250910T121714.1Z 9384.511969 239 1 11.56 2 77.95 94.61 66.76 265.32 0.00 1 0.00 1 0 17 3.739e-01 8.780e-03 3.070e-01 6.766e-03 5.914572e-01 3.688001e-03 6.818880e-03 -6.000000e+00 2.220426e-01 229.55 -2.00 3.53 -2.00 320.88 0.00e+00 3.615648e-03 1.640347e-03 1.023316e-03 -6.000000e+00 9.870153e-03 286.40 -2.00 20.00 -2.00 320.26 0.00e+00 4.645 0.002 302.00 328.00 3 2.7936e+00 1.2101e-02 5.5428e-02 -6.0000e+00 5.5393e-01 3.7746e-02 1.6116e-02 3.2095e-02 -6.0000e+00 5.9969e-01 -2.8879e-02 1.5566e-02 1.7629e-02 -6.0000e+00 3.5478e-01 -2.3605e-03 7.5660e-03 7.0268e-03 -6.0000e+00 1.5042e-01 1.8053e-04 3.2957e-05 2.0141e-04 8.1953e-05 -6.0000e+00 1.0722e-02 -2.8594e-03 -1.0432e-04 12 9 1 12 1 1 98.80 19.32 0.38 -0.00286 -0.00261 20 23 1 5 0 550.440 22.71 14.99 19.32 22.64 23.2 961.83 -76535 -74504 -93610 -84123 -191703 900000 -67946 900000 -31653 22323 -62660 -49943 711 -30694 138537 -53217 264275 -58883 22816 -18855 25262 48208 -1998 42029 -35799 23190 -25335 20977 -39231 31130 -17912 -887 5522 -2954 19616 -10959 17110 -10762 -6669 -7951 2626 -429 -903 185 -2945 9881 -1701 7057 -5419 16015 -1301 7751 -1462 3172 -234 -1130 3060 -3123 4071 -414 3688 -939 6040 544 2875 3620 -2544 2424 -880 3156 2182 465 -43 -476 1495 -1942 -947 -3373 -739 -2128 -810 -2665 306 -1041 -1301 43 -9 1830 215 1366 -1009 740 -492 -504 -356 767 1013 -766 659 -787 -9 -1448 696 -1551 -107 -1036 -746 389 212 228 -423 817 365 285 -614 146 314 181 380 -1067 -158 -9 817 59 603 198 732 -72 364 384 -352 -598 -5 112 -450 47 737 -37 188 -371 -199 -217 -505 -491 -747 -584 -3660 900000 -448 900000 -209 147 -574 -476 5 -394 914 -1248 1743 -1812 334 -442 389 601 -44 647 -1285 484 -863 438 -1524 673 -755 -37 245 -146 747 -590 796 -800 -582 -821 269 -48 -107 22 -373 1129 -224 882 -806 2089 -225 1357 -290 647 -52 -262 691 -740 880 -95 865 -259 1755 182 943 1143 -857 823 -350 1364 1022 226 -20 -210 587 -719 -335 -1296 -319 -1096 -474 -1772 212 -777 -992 34 -8 1513 177 1050 -777 528 -351 -386 -294 723 1092 -934 780 -952 -10 -1470 670 -1613 -117 -1207 -922 488 295 350 -701 1357 592 439 -902 209 466 284 629 -1814 -260 -14 1243 86 847 282 1047 -108 611 675 -668 -1193 -11 239 -1024 109 1744 -90 439 -826 -439 -459 SS 20250910T122219.5Z 9384.515504 242 1 11.69 2 77.01 95.49 67.66 266.19 0.00 1 0.00 1 0 17 3.655e-01 1.843e-02 2.863e-01 1.325e-02 5.539546e-01 7.101944e-03 6.469006e-03 -6.000000e+00 2.157683e-01 229.55 -2.00 3.53 -2.00 320.64 0.00e+00 4.731380e-03 2.861956e-03 1.236280e-03 -6.000000e+00 9.631451e-03 286.40 -2.00 20.00 -2.00 319.97 0.00e+00 4.334 0.001 302.00 328.00 3 4.1443e+00 2.2361e-02 5.1719e-02 -6.0000e+00 5.3716e-01 1.6550e-01 2.8252e-02 2.9711e-02 -6.0000e+00 5.8099e-01 -2.1152e-01 2.4407e-02 1.6315e-02 -6.0000e+00 3.4543e-01 8.8476e-02 1.2110e-02 6.8503e-03 -6.0000e+00 1.4708e-01 6.2936e-05 -3.5960e-04 3.9534e-04 8.3916e-05 -6.0000e+00 1.0340e-02 -2.1740e-03 -1.9832e-05 12 9 9 12 1 1 91.50 19.32 0.57 -0.00217 -0.00488 5 6 1 5 0 1948.360 22.71 14.99 19.32 23.08 23.3 965.31 -74788 6249 -128935 173715 -151059 900000 -136370 30384 -24318 -73194 -41763 -101856 -70724 -102118 15667 -70831 69508 16128 143293 10760 57808 -61637 13045 -11896 31130 -13231 9862 -4946 -4791 47121 7670 44141 14061 14363 19878 22242 42635 -8475 -1865 -8808 15707 16345 27686 13868 -7297 -1546 -7238 26500 10524 10903 4612 9266 4652 3374 13730 2588 5565 1576 8555 -5888 8896 2672 6089 3011 3015 6494 -1339 5661 -4620 5226 1265 4361 -4811 -1665 -4700 962 -5051 -6752 1130 -76 -1036 -4330 -739 -1927 -189 -1798 -327 262 -223 1891 439 -1752 -3048 2406 1258 -2382 -1486 -2250 35 75 -128 -901 2345 1291 29 -649 -1528 -851 244 2081 -341 569 122 819 -2237 733 749 -282 -74 -344 1425 147 1175 -508 38 -432 1688 -363 1460 902 549 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